Esterification of glycerol from biodiesel production to glycerol carbonate in non-catalytic supercritical dimethyl carbonate. [PDF]
Conversion of glycerol from biodiesel production to glycerol carbonate was studied by esterification with dimethyl carbonate in a non-catalytic supercritical condition. It was found that in a non-catalytic supercritical condition, glycerol at higher purity gave higher yield of glycerol carbonate at 98 wt% after reaction at 300 °C/20-40 MPa/15 min.
Ilham Z, Saka S.
europepmc +11 more sources
Synthesis of glycerol carbonate from dimethyl carbonate and glycerol using CaO derived from eggshells [PDF]
Waste eggshell is proposed as a highly active catalyst for glycerol carbonate production from dimethyl carbonate (DMC) and glycerol. The effect of reaction temperature, reaction time and catalyst loading on the reaction performance were investigated in ...
Praikaew Wanichaya +8 more
doaj +7 more sources
Biodiesel is nowadays added in 5–10% v/v to diesel, and its production involves the parallel creation of a vast glycerol amount as a by-product. Despite its many applications, there is a surplus of glycerol (Gly) that has boosted the search for new ...
Yosra Snoussi +5 more
doaj +2 more sources
Synthesis of glycerol carbonate from glycerol and dimethyl carbonate in basic ionic liquids
Glycerol carbonate is a key multifunctional compound used as solvent, additive, and building block in alternative chlorine-free processes. Here, we report the synthesis of glycerol carbonate from renewable materials (glycerol and dimethyl carbonate, DMC) using basic ionic liquids (ILs) as catalysts.
CHIAPPE, CINZIA, Rajamani S.
openaire +3 more sources
Esters of oligo-(glycerol carbonate-glycerol): New biobased oligomeric surfactants [PDF]
Glycerol carbonate is one of the most potentially multifunction glycerol-derived compounds. Glycerol is an important by-product of the oleochemical industry. The oligomerization of glycerol carbonate, assisted by the glycerol, results in the production of polyhydroxylated oligomers rich in linear carbonate groups. The polar moieties of these oligomers (
Holmière, Sébastien +3 more
openaire +6 more sources
Fabrication of novel buckypaper metal oxide nano-catalysis glycerol carbonate/MWCNTs membrane for efficient removal of heavy metals [PDF]
This study describes the fabrication of novel buckypaper membranes through the dispersion of multi-walled carbon nanotubes (MWCNTs) in the presence of surfactants metal oxide nano-catalysis Zinc oxide and magnesium oxide (ZnO and MgO) glycerol carbonate ...
Seham S. Alterary +2 more
doaj +2 more sources
Research on the direct synthesis of glycerol carbonate from carbon dioxide and glycerol
Using biodiesel-based glycerol as raw material to directly synthesize glycerol carbonate with CO2 can not only promote the benign development of biodiesel industry, but also have positive significance for carbon reduction.
Dan Yang +8 more
doaj +2 more sources
Comparative study of conventional and process intensification by reactive distillation designs for glycerol carbonate production from glycerol and diethyl carbonate [PDF]
Glycerol carbonate (GC) can be produced from glycerol (GL), a low-value byproduct in the biodiesel industry. In this work, continuous processes of GC production via transesterification from crude GL and diethyl carbonate (DEC) were developed using Aspen ...
Bushra Chalermthai +6 more
doaj +2 more sources
In this article, a CaO-based catalyst was prepared by impregnating chloride salts on CaO to develop a highly efficient heterogeneous catalyst for the synthesis of glycerol carbonate (GC) from glycerol and dimethyl carbonate.
Ying Tang +5 more
doaj +2 more sources
K2CO3-Modified Smectites as Basic Catalysts for Glycerol Transcarbonation to Glycerol Carbonate. [PDF]
A novel and cost-effective heterogeneous catalyst for glycerol carbonate production through transesterification was developed by impregnating smectite clay with K2CO3. Comprehensive structural and chemical analyses, including X-ray diffraction Analysis (XRD), Scanning Electron Microscopy (SEM)-Electron Dispersion Spectroscopy (EDS), Fourier Transform ...
Snoussi Y +5 more
europepmc +3 more sources

