Designing hollow nano gold golf balls. [PDF]
Hollow/porous nanoparticles, including nanocarriers, nanoshells, and mesoporous materials have applications in catalysis, photonics, biosensing, and delivery of theranostic agents.
Anzenberg, Paula +11 more
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Formation of rectifier with gold nanoclusters [PDF]
Gold nanoclusters encapsulated with organic molecules are of great interest for its possible applications in the fields of molecular electronics, catalysis and medical science.
John, Neena S. +3 more
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A dual catalytic strategy for carbon-phosphorus cross-coupling via gold and photoredox catalysis. [PDF]
A new method for the P-arylation of aryldiazonium salts with H-phosphonates via dual gold and photoredox catalysis is described. The reaction proceeds smoothly at room temperature in the absence of base and/or additives, and offers an efficient approach ...
He, Ying, TOSTE, F. Dean, Wu, Hongmiao
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Plasma-enhanced atomic layer deposition of nanostructured gold near room temperature [PDF]
A plasma-enhanced atomic layer deposition (PE-ALD) process to deposit metallic gold is reported, using the previously reported Me3Au(PMe3) precursor with H-2 plasma as the reactant.
Baets, Roel +11 more
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Identification of single-site gold catalysis in acetylene hydrochlorination [PDF]
There remains considerable debate over the active form of gold under operating conditions of a recently validated gold catalyst for acetylene hydrochlorination.
Catlow, C. Richard A. +14 more
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Comparing Protonolysis and Transmetalation Reactions: Microcalorimetric Studies of C–AuI Bonds in [AuRL] Complexes [PDF]
Producción CientíficaThe protonolysis of C–Au bonds in [AuRL] organometallic complexes has been studied by calorimetry for twelve R groups. The experimental data have been combined with DFT calculations to obtain Bond Dissociation Energy values (BDE).
Casares González, Juan Ángel +2 more
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An element through the looking glass: Exploring the Au-C, Au-H and Au-O energy landscape [PDF]
Gold, the archetypal “noble metal”, used to be considered of little interest in catalysis. It is now clear that this was a misconception, and a multitude of gold-catalysed transformations has been reported.
Bochmann, Manfred +2 more
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The Success Story of Gold-Based Catalysts for Gas- and Liquid-Phase Reactions: A Brief Perspective and Beyond [PDF]
Gold has long held the fascination of mankind. For millennia it has found use in art, cosmetic metallurgy and architecture; this element is seen as the ultimate statement of prosperity and beauty.
Ivanova, Svetlana +4 more
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Peptide-Gold Nanoparticle Conjugates as Artificial Carbonic Anhydrase Mimics [PDF]
We herein describe the design and synthesis of a catalytically active peptide–gold nanoparticle conjugate (Pep-Au-NP) that binds Zn(II) within its peptide monolayer and develops carbonic anhydrase activity. Specifically, a modified variant of the β-sheet
Koksch, Beate, Mikolajczak, Dorian J.
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Deactivation of gold(I) catalysts in the presence of thiols and amines – characterisation and catalysis [PDF]
Thiols and amines, which are common heteroatom nucleophiles in gold-catalysed reactions, are known to dampen the reactivity of gold catalysts. In this article, the identity and activity of gold(I) catalysts in the presence of thiols and amines is ...
Green, Samantha L J +3 more
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