Results 41 to 50 of about 917,598 (194)

Reactant-induced photoactivation of in situ generated organogold intermediates leading to alkynylated indoles via Csp 2-Csp cross-coupling

open access: yesNature Communications, 2022
Dual photo- and metal-catalysis is generally not well-understood when the metal catalyst is a gold complex. Here the authors show that a variation of a known metallaphotoredox annulation is possible without an added photocatalyst, proceeding putatively ...
Fen Zhao   +14 more
doaj   +1 more source

Supramolecular Ligands in Gold(I) Catalysis

open access: yes, 2013
A supramolecular ligand-template strategy is applied to gold(I) catalysis. The supramolecular ligands, formed from a phosphoramidite backbone and two templates, display different regioselectivity in the hydroalkoxylation of allenes compared to non ...
Reek, J.N.H.   +3 more
core   +1 more source

Special Issue: Gold Nanoparticles for Catalytic Applications

open access: yesApplied Sciences, 2019
Catalysis by gold nanoparticles is a topic of increasing interest [...]
Sónia A. C. Carabineiro
doaj   +1 more source

New Endeavors in Gold Catalysis-Size Matters

open access: yes, 2013
International audienceGolden times: Recent breakthroughs in gold-catalyzed transformations using nanosized homogeneous gold catalysts are highlighted.
Gramage-Doria, Rafael   +3 more
core   +1 more source

Gold(I)-catalyzed domino cyclization for the synthesis of polyaromatic heterocycles

open access: yesBeilstein Journal of Organic Chemistry, 2013
Gold(I) complexes have emerged as powerful and useful catalysts for the formation of new C–C, C–O and C–N bonds. Taking advantage of the specificity of [IPrAuNCMe][SbF6] complexes to favor the 5-exo-dig cyclization over the 6-endo-dig pathway, we report ...
Mathieu Morin   +2 more
doaj   +1 more source

Catalysis by Gold: Why Size Matters

open access: yesCHIMIA, 2009
Bulk gold is the most inert metal of all, however, when gold is finely dispersed on a support, it can be a very active catalyst for oxidation and hydrogenation reactions.
Jeroen A. van Bokhoven
doaj   +1 more source

Electrochemical gold redox catalysis for selective oxidative arylation

open access: yesGreen Synthesis and Catalysis, 2021
The combination of ArB(OH)2 transmetallation with cationic gold(I) [LAu]+ and electrochemical anodic oxidation (EAO) approach was successfully developed for the preparation of AuIII-Ar intermediate for the first time.
Shuyao Zhang   +4 more
doaj   +1 more source

Chiral N-heterocyclic Carbene Gold Complexes: Synthesis and Applications in Catalysis

open access: yes, 2019
N-Heterocyclic carbenes have found many applications in modern metal catalysis, due to the formation of stable metal complexes, and organocatalysis. Among a myriad of N-heterocyclic carbene metal complexes, gold complexes have gained a lot of attention ...
Michalak, Kośnik
core   +1 more source

Gold-catalyzed Dearomatization Reactions

open access: yesCHIMIA, 2018
The advent of homogenous gold catalysis has revolutionized the way of approaching organic synthesis providing new and desirable solutions for challenging chemical manipulations of unactivated unsaturated hydrocarbons.
Juzeng An, Marco Bandini
doaj   +1 more source

Unlocking the Chain-Walking Process in Gold Catalysis [PDF]

open access: yes, 2023
The successful realization of gold-catalyzed chain-walking reactions, facilitated by ligand-enabled Au(I)/Au(III) redox catalysis, has been reported for the first time. This breakthrough has led to the development of gold-catalyzed annulation reaction of
Vincent , Gandon   +3 more
core   +2 more sources

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