Results 41 to 50 of about 55,092 (217)

Closing the gap between 19F and 18F chemistry

open access: yesEJNMMI Radiopharmacy and Chemistry, 2021
Positron emission tomography (PET) has become an invaluable tool for drug discovery and diagnosis. The positron-emitting radionuclide fluorine-18 is frequently used in PET radiopharmaceuticals due to its advantageous characteristics; hence, methods ...
Javier Ajenjo   +3 more
doaj   +1 more source

Synthetic Strategies to Access Fluorinated Azoles

open access: yesEuropean Journal of Organic Chemistry, Volume 28, Issue 47, December 15, 2025.
This review highlights recent synthetic strategies for introducing fluorine groups (mono‐, di‐, and trifluoromethylation) into 11 major azole classes, identifying research gaps to inform future innovations in materials science, medicinal chemistry, and biomedical research.
Mohammed K. Abd El‐Gaber   +4 more
wiley   +1 more source

A General Hydrotrifluoromethylation of Unactivated Olefins Enabled by Voltage‐Gated Electrosynthesis

open access: yesAngewandte Chemie, Volume 137, Issue 4, January 21, 2025.
This work presents the discovery and development of a regioselective hydrotrifluoromethylation of olefins under electrochemical conditions. Guided by mechanistic studies, a voltage‐gated electrolysis was designed by integrating two redox processes operating within a narrow potential window.
Eva M. Alvarez   +2 more
wiley   +2 more sources

Green Ceramic Machining: Influence of the Cutting Speed and the Binder Percentage on the Y-TZP Behavior

open access: yesJournal of Manufacturing and Materials Processing, 2020
The demand for inert bioceramics is always increasing in the dental field. Yttrium oxide tetragonal zirconia polycrystals (Y-TZP) are oxide ceramics which are currently used because of their interesting mechanical properties due to a toughening ...
Anthonin Demarbaix   +4 more
doaj   +1 more source

The mango tree in central and northern Benin: damage caused by fruit flies (Diptera Tephritidae) and computation of economic injury level [PDF]

open access: yes, 2009
Introduction. Dans la zone soudanienne méridionale du Bénin les mouches des fruits constituent la contrainte phytosanitaire majeure pour le manguier et sont responsables de pertes de production considérables.
Arinloye, Djalal   +5 more
core   +1 more source

Ball‐Milling Assisted Iron‐Catalyzed Difluoromethylation Toward the Synthesis of Valuable Oxindoles

open access: yesChemSusChem, Volume 18, Issue 24, December 13, 2025.
An iron‐catalyzed difluoroalkylation of acrylamides under ball‐milling conditions affords oxindoles in up to 85% yield. Analytical studies reveal that the apparent piezoelectric activity originates from iron leaching caused by milling assembly abrasion during the reaction process. The iron‐catalyzed process proves to be efficient with a broad substrate
Vitalii Solomin   +4 more
wiley   +1 more source

Exploiting Sodium Ascorbate as an Underutilized and Sustainable Sacrificial Reductant for Net Reductive Pinacol Coupling Reactions via Mechanophotocatalysis

open access: yesHelvetica Chimica Acta, Volume 108, Issue 12, December 2025.
Sodium ascorbate is a safe and sustainable electron donor, yet its use in solution‐state photocatalysis reactions is often limited by its poor solubility in organic solvents. In this study, typical electron donors used for net reductive pinacol coupling reactions, such as DIPEA and the Hantzsch ester, are replaced with the more benign sodium ascorbate,
Francis Millward, Eli Zysman‐Colman
wiley   +1 more source

Théâtre et exil entre le Río de la Plata et le Pacifique (1835-1855)

open access: yesAmérica, 2021
L’importance de la sphère publique habermassienne pour les jeunes romantiques du Río de la Plata et des pays voisins a reçu une attention particulière depuis quelques décennies.
Edward Blumenthal
doaj   +1 more source

Een blauwdruk van het Bourgondische beleid in het graafschap Vlaanderen: de regentschapsinstructie van 1387 [PDF]

open access: yes, 2011
Preoccupied with the politics at the royal court of Charles VI of France, Philip the Bold, Duke of Burgundy and count of Flanders, appointed his nephew William of Namur, lord of Bethune, as Governor of Flanders, Antwerp and Mechelen with a special ...
Verwerft, Bert
core   +2 more sources

Mechanochemische Methoden mit Anwendung in der Late‐Stage Modifizierung Pharmazeutisch Wirksamer Verbindungen

open access: yesAngewandte Chemie, Volume 137, Issue 41, October 6, 2025.
Dieser Review diskutiert mechanochemische Strategien zur späten Modifizierung bioaktiver Wirkstoffe und bietet zugleich eine wertvolle Übersicht zur Auswahl geeigneter Substrate, um das pharmazeutische Potenzial neuer und bestehender (mechano)chemischer Verfahren zu evaluieren.
Johanna Templ, Lars Borchardt
wiley   +1 more source

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