Results 171 to 180 of about 88,308 (209)

The Promise and Challenges of Ammonia Electrosynthesis From Dinitrogen and Water Using an Electrochemical Palladium Membrane

open access: yesAngewandte Chemie, EarlyView.
Electrosynthesis of ammonia from nitrogen gas and water at ambient temperature is demonstrated using a device equipped with an electrochemical palladium membrane, which provides exclusive selectivity for the transfer of protons between the aqueous water oxidation and non‐aqueous nitrogen reduction compartments.
Ngoc‐Trung Nguyen   +11 more
wiley   +1 more source

Controlled Hydrogen Delivery by Single‐Atom Ru Accelerates Electrocatalytic Ammonia Synthesis

open access: yesAngewandte Chemie, EarlyView.
Single Ru atoms anchored on Co3O4 guide reactants along a hydrogen‐rich surface pathway, enabling efficient and selective conversion of NO to NH3. By linking atomic design to catalytic performance, this strategy clarifies the reaction mechanism and offers a versatile platform for engineering oxide catalysts for electrochemical ammonia synthesis ...
Zheng Liu   +15 more
wiley   +1 more source

Photoswitchable Ambiphilicity: Light‐Gated Frustrated Lewis Pair Reactivity and Z‐Type Interaction

open access: yesAngewandte Chemie, EarlyView.
Light‐controlled ambiphilicity is realized in photoswitchable intramolecular phosphorus/boron Lewis pairs. Reversible switching modulates both the thermodynamics and kinetics of frustrated Lewis‐pair reactivity, enabling light‐gated CO2 binding and release.
Lennart Stoess   +3 more
wiley   +1 more source

Engineering Atomically Precise Cu4I4 Nanoclusters With Integrated Adsorption and Hydrogenation Functions for Efficient Photocatalytic Nitrate‐to‐Ammonia Conversion

open access: yesAngewandte Chemie, EarlyView.
Efficient photocatalytic nitrate‐to‐ammonia conversion is achieved over an atomically precise Cu4I4 motif through dual‐site cooperation. Lewis‐acidic Cu centers promote nitrate adsorption and activation, while adjacent I sites facilitate active hydrogen generation for stepwise hydrogenation.
Wanting Zhang   +13 more
wiley   +1 more source

Coordinating Mesopore Geometry and Interfacial Water Dynamics for Iron‐Site Evolution in Nitrate Electroreduction

open access: yesAngewandte Chemie, EarlyView.
Mesopore geometry programs the working‐state interface of Fe single sites during nitrate electroreduction. Hexagonal channels reorganize interfacial water and accompany the reversible evolution of isolated Fe─O4‐like sites toward Fe─O─Fe‐like motifs, promoting successive hydrogenation toward NH3 with a Faradaic efficiency of 99.1%.
Xiangyang Liu   +8 more
wiley   +1 more source

Evidence of biological nitrification inhibition in barley to support sustainable nitrogen management. [PDF]

open access: yesSustain Microbiol
Henderson J   +5 more
europepmc   +1 more source

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