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Syntheses, X‐ray Crystal Structures, and Raman Spectra of Self‐Assembled XeO3 Chain and Network Complexes of Polytopic sp2‐ and sp3‐Nitrogen Bases

Angewandte Chemie, EarlyView.
Supramolecular 1‐D, 2‐D, and 3‐D networks comprised of ‐(‐O═Xe(O2)‐‐)‐∞ and ‐(‐Xe(O2)O‐‐‐HO(H)‐‐)‐∞ chains coordinated to polytopic N‐base ligands were synthesized and structurally characterized by X‐ray crystallography. Their Xe‐‐‐N and Xe‐‐‐O bonds are characteristic of σ–hole bonds in which the nucleophilic Lewis base sites of the N‐ligands, H2O ...
James T. Goettel +2 more
wiley +1 more source

Photoelectrochemical nitrate reduction to ammonia on CuFeO2 photocathodes modified with metallic cocatalysts. [PDF]

RSC Adv
El Idrissi M +6 more
europepmc +1 more source

Gain‐of‐Function Engineering of the NifEN Scaffold Into a Self‐Assembling Nitrogenase

Angewandte Chemie, EarlyView.
From scaffold to enzyme: Systematic engineering of the cofactor maturation scaffold NifEN reconstructs the P→M electron relay along with cofactor coordination and proton gating at the S2B site, converting NifEN into a functional nitrogenase capable of ATP‐dependent N2 reduction both in vitro and in vivo.
Yimo Yang +4 more
wiley +1 more source

Gills are not the primary site of gas exchange in the suspension-feeding hemichordate Protoglossus graveolens. [PDF]

J Exp Biol
Sackville MA, Cameron CB, Brauner CJ.
europepmc +1 more source

Bottlebrush anthocyanin-mediated green synthesis of ZnO nanoparticles and their integration into functional paper for multifunctional ammonia sensing and food quality monitoring. [PDF]