Results 11 to 20 of about 265,039 (161)
Green Production Technology of the Monomer of Nylon-6: Caprolactam
After two decades’ endeavor, the Research Institute of Petroleum Processing (RIPP) has successfully developed a green caprolactam (CPL) production technology. This technology is based on the integration of titanium silicate (TS)-1 zeolite with the slurry-
Baoning Zong +7 more
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Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles
The investigation of reactivity of β,γ-unsaturated carbonyl compounds is of great synthetic value, especially in asymmetric transformations. Here, the authors report a catalytic asymmetric tandem isomerization/α-Michael addition of β,γ-unsaturated 2-acyl
Tengfei Kang +5 more
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Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO2
Compounds bearing a carbonyl group, such as aldehydes and ketones, are important industrial chemicals and widespread in pharmaceuticals and natural products.
Guang-Mei Cao +7 more
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Breaking through water-splitting bottlenecks over carbon nitride with fluorination
Graphitic carbon nitride has long been considered a poor oxygen evolution catalyst. Here, the authors report a simple fluorination strategy to prevent the accumulation of inert C=O on carbon nitride to break through this bottleneck.
Ji Wu +8 more
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The precise and efficient construction of axially chiral scaffolds, particularly toward the aryl-alkene atropoisomers with impeccably full enantiocontrol and highly structural diversity, remains greatly challenging. Herein, we disclose an organocatalytic
Fengyuan Guo +4 more
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A series of bimetel organic framework MnxCu1−x-MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy
Fei Wang +5 more
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Stereodivergent construction of adjacent quaternary-quaternary stereocenters remains a formidable synthetic challenge. Here, the authors report a nickel-catalyzed enantioselective dearomatization Claisen rearrangement leading to vicinal all-carbon ...
Haifeng Zheng +6 more
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Modern catalysis in the synthesis of some pharmaceuticals and fine chemicals [PDF]
Catalysis in the synthesis of Pharmaceuticals and line chemicals nowadays becomes more and more important. Synthesis that minimizes wastes is important from the economical aspect, as well as from the environmental aspect.
Petrović Slobodan D. +2 more
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Opportunities and perspectives for green chemistry in semiconductor technologies [PDF]
Semiconductor technologies offer a plethora of technological challenges and opportunities for a more extensive implementation of green chemistry principles.
Francesca Iacopi, Monique McIntosh
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Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CO2
Electrochemistry is a promising approach to make existing chemical protocols milder, but many simple transformations of feedstocks are still out of reach.
Guo-Quan Sun +7 more
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