Results 91 to 100 of about 62,611 (245)
ChemSusChem, Volume 18, Issue 6, March 15, 2025.Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
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ChemSusChem, Volume 18, Issue 6, March 15, 2025.we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
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, 1978 Molecular weight measurements and microwave titrations indicate that no interaction occurs between tetrameric 2-Me{2}NCH{2}C{6}H{4}Cu (Ar{4}Cu{4}) and the monodentate ligands PPh{3}, CH{3}CN or pyridine. However, the tetrameric structure Ar{4}Cu{4} breaks down upon interaction (1/1 molar ratio ArCu/L) with the bidentate ligands (L) Diphos or cis-DPPEE ...
Koten, G. van, Noltes, J.G., Spek, A.L.
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ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.2D MXene (Ti3C2Tx)‐based electrode setup for hybrid photo‐electro‐Fenton degradation of antibiotic (tetracycline). The persistence of antibiotics such as tetracycline in aquatic systems poses severe environmental and health risks by potential antimicrobial resistance.
Durga Sankar Vavilapalli +8 more
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, 1978 The 1/1 reaction of (2-Me{2}NCH{2}C{6}H{4}){4}M{2}Li{2} (M = Cu or Au) with (CO){2}ClRh-dimer affords (2-Me{2}NCH{2}C{6}H{4}M){n} and the novel 2-Me{2}NCH{2}C{6}H{4}Rh(CO){2}. In contrast, the reaction of (x-tolyl){4}M{2}Li{2} (x = 2, M = Cu or Au) under a CO atmosphere results in the formation of ditolyl ketone bitolyl in 69, 92 and 31, 4% yield ...
Koten, G. van +2 more
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Metal complexes of weakly coordinating anions. Precursors of strong cationic organometallic Lewis acids [PDF]
, 1988 Beck, Wolfgang, Sünkel, Karlheinz
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European Journal of Inorganic Chemistry, EarlyView.The concept of scorpionate ligands has evolved significantly since the introduction of tris(pyrazolyl)borate. By integrating a biological supramolecular ligand scaffold with the classic scorpionate architecture, researchers have made notable strides in mimicking the active sites of nitrogenase and advancing homogeneous catalysis.
Austin Winfield Medley +1 more
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A Geologic Si‐O‐C Pathway to Incorporate Carbon in Silicates
Geophysical Monograph Series, Page 47-54., 2020 This book is Open Access. A digital copy can be downloaded for free from Wiley Online Library.
Explores the behavior of carbon in minerals, melts, and fluids under extreme conditions
Carbon trapped in diamonds and carbonate-bearing rocks in subduction zones are examples of the continuing exchange of substantial carbon ...
Alexandra Navrotsky +2 more
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European Journal of Inorganic Chemistry, EarlyView.A modular library of structurally robust palladacyclopentadienyl Pd(II) complexes bearing achiral and chiral diphosphines was developed, revealing a strong influence of diphosphine design and ligand chirality on cytotoxicity and selectivity against ovarian cancer cells, including platinum‐resistant models.
Stefania Mautone +7 more
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European Journal of Inorganic Chemistry, EarlyView.The first low‐oxidation (I/III) state chromium‐complex bearing a O‐chelating NHC ligand has been synthesized and structurally characterized by single‐crystal X‐ray analysis. The formation of the mixed‐valence species was further supported by SQUID magnetometry and high‐field electron paramagnetic resonance (EPR) spectroscopy.
Somnath Bhattacharya +4 more
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