Results 101 to 110 of about 62,611 (245)

Copper Complexes with Arylated Triethylenetetramine Ligands: Reactivity Toward Dioxygen and Peroxides

European Journal of Inorganic Chemistry, EarlyView.
Here, we describe new Cu(I)/Cu(II) complexes based on arylated tren ligands and investigate their reactivity toward O2 and peroxides. Low‐temperature–stopped flow studies revealed the formation of transient copper–oxygen species, including superoxido, hydroperoxido, and alkylperoxido intermediates.
Chiara Eleonora Campi, Christian Würtele, Siegfried Schindler   +2 more
wiley   +1 more source

Fluorine Chemistry. [PDF]

ACS Org Inorg Au
Poisson T, Dichiarante V.
europepmc   +1 more source

Emerging Trends in Organic Photoreactions Utilizing Disulfides

European Journal of Organic Chemistry, EarlyView.
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar, Bolormaa Bayarkhuu, Hong Y. Cho, Jeehye Byun   +3 more
wiley   +1 more source

Mannich reaction with organozinc reagents in continuous flow: experimental and computational studies. [PDF]

RSC Adv
Fraile-González L, Sánchez-González Á, Peña LF, López E.   +3 more
europepmc   +1 more source

Preparation of α‐Mono‐Fluoromethyl Silanes via Nucleophilic Displacement on Chlorosilanes With LiCH2F

European Journal of Organic Chemistry, EarlyView.
The SiCl bond acts as a versatile platform for undergoing a formal nucleophilic substitution promoted by LiCH2F en route to extremely rare α‐monofluoromethyl‐silanes. Though surprising – when compared with well‐established poly‐fluoromethyl silanes (e.g., Ruppert‐Prakash reagent, TMSCF3) – α‐mono‐fluoromethyl silanes are underrepresented motifs in ...
Alberto Nardi, Davide Castiglione, Margherita Miele, Laura Castoldi, Vittorio Pace   +4 more
wiley   +1 more source

On-complex three-component cascade reactions involving phosphorescent cyclometalated Ir(iii) chloro-isocyanide complexes, nitriles, and propylamine. [PDF]

Chem Sci
Phan SNT, Dang VQ, Teets TS.
europepmc   +1 more source

Unlocking the Functionalization and Reactivity of Ethylene Bridges in [2.2]Paracyclophanes: Strategies and Challenges

European Journal of Organic Chemistry, EarlyView.
Bridging the gap. Beyond deck functionalization, the ethylene bridges of [2.2]paracyclophanes offer a largely unexploited reactivity landscape. This review showcases strategies to functionalize these bridges and leverage them to build novel cyclophane architectures.
Rongyu Sun, Tamara Ye, Laurent Micouin, Erica Benedetti   +3 more
wiley   +1 more source

Diiron(I) Bis(cyclopentadienyl) Complexes with Bridging Iminium Ligands: From Foundational Organometallic Chemistry to Unique Reactivity and Biological Potential. [PDF]

Acc Chem Res
Benetti S, Cinci A, Zappelli C, Marchetti F.   +3 more
europepmc   +1 more source

Remarkable Formation of Indene Derivatives Upon Friedel–Crafts Acylation Reactions

European Journal of Organic Chemistry, EarlyView.
This shows indene derivatives. Under the reaction conditions of a Friedel–Crafts acylation, alkyl benzenes underwent an unprecedented cyclopentannulation furnishing indene derivatives. Alkylbenzene derivatives react with two equivalents of pivaloyl chloride (PivCl) in the presence of aluminum trichloride under formation of indene derivatives with up to
Leah Bantel, Neels Kruse, Marc Schmidtmann, Jens Christoffers   +3 more
wiley   +1 more source

Cobalt-Catalyzed Three-Component Reductive Coupling of Aldehydes, Allenes, and Aryl Halides. [PDF]

Org Lett
Sieber JD, Togoh M, Azad S, McHenry T, Sanders M.   +4 more
europepmc   +1 more source