Results 71 to 80 of about 15,945 (209)

Phosphoramidate and Silyl Amine Mediated Synthesis of Isocyanide Cyclopentadienone Iron Complexes

Helvetica Chimica Acta, EarlyView.
Carbonyl ligands in cyclopentadienone iron complexes are replaced by isocyanide ligands without using free, malodorous isocyanides. The reaction takes place via an Aza‐Wittig‐type reaction starting from primary amines, employing either phosphoramidates or silyl amines as intermediate reagents.
André Bütikofer, Daniel Svoboda, Joël Landis, Peter Chen   +3 more
wiley   +1 more source

Toward photodynamic detection and photodynamic therapy of tumours over-expressing carbonic anhydrase IX with a phosphorescent organometallic iridium(iii) antibody conjugate. [PDF]

Chem Sci
McGowan ER, Rudd SE, Morgan KA, Smith TA, Donnelly PS.   +4 more
europepmc   +1 more source

Organic field‐effect transistors: Materials design, device physics, and contact engineering for high‐performance flexible electronics

Information &Functional Materials, EarlyView.
This review bridges molecular design with device engineering to address key challenges in organic transistors. By integrating materials chemistry with contact optimization, it provides pathways toward stable, high‐performance flexible electronics. Abstract Organic field‐effect transistors are widely recognized as key enabling components for low‐cost ...
Fenglan Kuang, Fei Wang, Dawei Duan, Yicong Ma, Xiaokang Sun, Soumitra Satapathi, Annie Ng, Haoran Lin, Zheng Li, Yufei Zhong, Hanlin Hu   +10 more
wiley   +1 more source

Controlling Reductive Elimination Pathways in Ti(IV) Pincer Complexes: Concerted versus Radical Mechanisms via Ligand Design. [PDF]

J Am Chem Soc
Fritsche P, Czernetzki C, Heldner ML, Hörlin L, Krummenacher I, Hierlmeier G.   +5 more
europepmc   +1 more source

Total X‐Ray Illumination for Absolute Quantification of Crystalline Phases and Amorphous Content in PVDF and P(VDF‐TrFE)

Macromolecular Materials and Engineering, EarlyView.
A rigorous method, Total Illumination by X‐rays (TIX), is presented to quantify crystalline and amorphous phases in organic materials. Mitigating challenges such as low microabsorption and high amorphous content, an improved, general framework is established, applicable to polymers, MOFs, biological materials, etc.
Shaashwat Saraff, Giulio Isacco Lampronti, Sohini Kar‐Narayan   +2 more
wiley   +1 more source

On-surface synthesis platform for highly branched oligomers based on sequential C-C coupling and C-H activation of carbenes. [PDF]

Nat Commun
Cao Y, Mieres-Perez J, Rowen JF, Raut AH, Schweer P, Bao A, Sander W, Sanchez-Garcia E, Morgenstern K.   +8 more
europepmc   +1 more source

From Molecule to Material: How Support Changes Heterobimetallic Catalysts in Lactide Polymerization

Macromolecular Rapid Communications, EarlyView.
Silica‐supported heterobimetallic alkoxide complexes were developed as catalysts for lactide ring‐opening polymerization. Grafting iron‐based ate complexes onto SiO2‐700 produced well‐defined active sites, enabling controlled polymerization with predictable molar masses, narrow dispersities, and recyclability.
Fan Yang, Yahaya Nasiru, Abdulrahman Adamu Isah, Aimery de Mallmann, Mostafa Taoufik, Régis M. Gauvin, Christophe M. Thomas   +6 more
wiley   +1 more source

Ligand assisted Co(ii) catalyzed direct C-H alkylation of aryl ketones with diverse alkyl halides. [PDF]

Chem Sci
Nigade A, Parmar SV, Avasare V.
europepmc   +1 more source

Unprecedented Formation of a Formally Cu(III) Trifluoromethyl Hydroxide Tetramer. [PDF]

Chemistry
Novel high‐valent Cu(III) trifluoromethyl hydroxide scaffold with an unprecedented heterocubane structure was synthesized. Its neutralization reactions with acids afford a broad variety of Cu(III) complexes with two trifluoromethyl groups. Synthetic relevance of this compound for C─CF3 bond formation was demonstrated.
Motornov V, Limberg N.
europepmc   +2 more sources

Cold EI—The Way to Improve GC‐MS and Increase Its Range of Applications

Mass Spectrometry Reviews, EarlyView.
ABSTRACT Gas chromatography‐mass spectrometry (GC‐MS) with Cold electron ionization (EI) is based on interfacing the GC and MS with a supersonic molecular beam (SMB) along with electron ionization of vibrationally cold sample compounds in the SMB in a contact‐free fly‐through ion source (hence the name Cold EI).
Aviv Amirav, Benny Neumark, Oneg Elkabets, Alex Yakovchuk   +3 more
wiley   +1 more source