Results 111 to 120 of about 744,099 (279)
Crystals, 2017 In order to explore the use of non-covalent interactions in the deliberate assembly of metal-supramolecular architectures, a series of β-diketone based ligands capable of simultaneously acting as halogen-bond donors and chelating ligands were synthesized.
Janaka C. Gamekkanda +4 more
doaj +1 more source
Turning Water Into a Tool: From Degradation Pathways to Functional Engineering in Halide Perovskites
Advanced Materials Technologies, EarlyView.Water exhibits a threshold‐dependent dual role in lead halide perovskites, acting either as a degradation trigger or as a powerful tool for defect passivation, recrystallization, and structural engineering. This review discusses how controlled water‐mediated interactions govern stability, dimensionality, and optoelectronic performance, providing ...
Raphaella T. S. Gonçalves +4 more
wiley +1 more source
NX⋯Y halogen bonds. Comparison with NH⋯Y H-bonds and CX⋯Y halogen bonds
Physical Chemistry Chemical Physics, 2016 Quantum calculations examine how the NH⋯Y H-bond compares to the equivalent NX⋯Y halogen bond, as well as to comparable CH/CX donors.
Nepal, Binod, Scheiner, Steve
openaire +4 more sources
Advanced Materials Technologies, EarlyView.Extrusion‐based bioprinting (EBB) has emerged as a versatile biofabrication platform capable of precisely depositing bioinks composed of biomaterials, cells, and bioactive agents to generate patient‐specific, biomimetic skin constructs. This paper presents a state‐of‐the‐art and forward‐looking overview of EBB for wound healing, encompassing printing ...
Hien‐Phuong Le +4 more
wiley +1 more source
Cyanometallates as Halogen Bond Acceptors
, 2016 Two families of halopyridnium hexacyanometallate salts, (3-XpyMe)3[M(CN)6] and (3,5-X2pyMe)3[M(CN)6] (X = I, Br; 3-XpyMe = N-methyl-3-halopyridinium; 3,5-XpyMe = N-methyl-3,5-dihalopyridinium; M = Cr, Fe, Co), have been synthesized and characterized by
Lee Brammer (1306188) +2 more
core +1 more source
Advanced Optical Materials, EarlyView.Tailored amine substitution in fluorene and dibenzothiophene derivatives enables systematic control of excited‐state properties and triplet population. Combined photophysical studies, TD‐DFT calculations and time‐resolved EPR reveal how charge‐transfer character, sulfur‐induced spin–orbit coupling and triplet manifold engineering cooperate to promote ...
Francesco Ruighi +10 more
wiley +1 more source
Enhancement of Circular Dichroism in Chiral Dielectric Metasurfaces by Ion Beam Irradiation
Advanced Optical Materials, EarlyView.Ion beam irradiation enables post fabrication tuning of dissipative losses in chiral dielectric metasurfaces composed of C4 symmetric silicon nanostructures. By tailoring the absorption toward critical coupling condition, circular dichroism is enhanced from 0.70 to 0.85, demonstrating a versatile route for maximizing optical chirality and polarization ...
Anna Fitriana +6 more
wiley +1 more source
Degradable Magnetic Composites from Recycled NdFeB Magnets for Soft Actuation and Sensing
Advanced Robotics Research, EarlyView.This work presents a degradable soft magnetic composite made from recycled NdFeB particles embedded in a gelatin‐based organogel. The material is processed into magnetic sensors and soft robotic components, which can later be dissolved in a green solvent to recover NdFeB magnetic particles.
Muhammad Bilal Khan +14 more
wiley +1 more source
Multidentate Iodoalkyne Receptors as Halogen Bond Donors [PDF]
, 2015 Halogen bonding is an expanding area in supramolecular chemistry. Previously, the Taylor group has reported a series of multidentate iodoperfluoroarene based receptors that displayed strong halogen bonding with anions in solution.
Takasaki, Harumi
core +2 more sources
Machine Learning for Green Solvents: Assessment, Selection and Substitution
Advanced Science, EarlyView.Environmental regulations have intensified demand for green solvents, but discovery is limited by Solvent Selection Guides (SSGs) that quantify solvent sustainability. Training a machine learning model on GlaxoSmithKline SSG, a database of sustainability metrics for 10,189 solvents, GreenSolventDB is developed. Integrated with Hansen solubility metrics,
Rohan Datta +4 more
wiley +1 more source