Results 11 to 20 of about 85,379 (320)
Chemical Reviews, 2016 The halogen bond occurs when there is evidence of a net attractive interaction between an electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic region in another, or the same, molecular entity.
Cavallo, Gabriella +6 more
core +11 more sources
Activation of a Metal-Halogen Bond by Halogen Bonding. [PDF]
Angew Chem Int Ed Engl, 2020 Abstract In recent years, the non‐covalent interaction of halogen bonding (XB) has found increasing application in organocatalysis. However, reports of the activation of metal‐ligand bonds by XB have so far been limited to a few reactions with elemental iodine or bromine. Herein, we present the activation of metal‐halogen bonds by two
Wolf J +7 more
europepmc +8 more sources
The Halogen Bond in the Design of Functional Supramolecular Materials: Recent Advances [PDF]
Accounts of Chemical Research, 2013 Halogen bonding is an emerging noncovalent interaction for constructing supramolecular assemblies. Though similar to the more familiar hydrogen bonding, four primary differences between these two interactions make halogen bonding a unique tool for ...
A. Priimagi +3 more
core +3 more sources
Halogen-bonded shape memory polymers
Nature Communications, 2022 Halogen bonding is widely adopted in organic synthesis and supramolecular crystal engineering but application of halogen bonding in the design of stimuli-responsive materials is challenging.
Hongshuang Guo +6 more
doaj +5 more sources
“Anti-Electrostatic” Halogen Bonding [PDF]
Angewandte Chemie International Edition, 2020 Halogen bonding (XB) is often described as being driven predominantly by electrostatics, and thus adducts between anionic XB donors (halogen-based Lewis acids) and anions seem counterintuitive. Such “anti-electrostatic” XBs have been predicted theoretically, but there are currently no experimental examples based on organic XB donors. Herein, we report
Jana M. Holthoff +3 more
openalex +5 more sources
Principles and Applications of CF2X Moieties as Unconventional Halogen Bond Donors in Medicinal Chemistry, Chemical Biology, and Drug Discovery. [PDF]
J Med Chem, 2023 Vaas S +11 more
europepmc +3 more sources
Halogen-Bonded Driven Tetra-Substituted Benzene Dimers and Trimers: Potential Hosts for Metal Ions
Sci, 2022 Cyclic dimers and trimers of tetra-substituted benzenes, ((HOOC)2-C6H2-(NHI)2), are selected as convenient model systems for investigating NI…O=C halogen bond strength and cooperativity. The four substituents in benzene are chosen so that two of them act
Rubén D. Parra
doaj +1 more source
Molecules, 2022 The halogen bond has been widely used as an important supramolecular tool in various research areas. However, there are relatively few studies on halogen bonding related to molecular chirality. 3-(2-Halophenyl)quinazoline-4-thione derivatives have stable
Ryosuke Matsui +7 more
doaj +1 more source
Crystals, 2021 In order to study the proclivity of primary amine groups to act as halogen bond acceptors, three aromatic diamines (p-phenylenediamine (pphda), benzidine (bnzd) and o-tolidine (otol)) were cocrystallised with three perfluorinated iodobenzenes (1,4 ...
Erik Uran +4 more
doaj +1 more source
Molecules, 2021 The formation of a pair of extended networks sustained by halogen bonds based upon two regioisomers of a photoproduct, namely rctt-1,3-bis(4-pyridyl)-2,4-bis(phenyl)cyclobutane (ht-PP) and rctt-1,2-bis(4-pyridyl)-3,4-bis(phenyl)cyclobutane (hh-PP), that ...
Taylor J. Dunning +3 more
doaj +1 more source