Results 211 to 220 of about 744,099 (279)

Evaluation of Azobenzene Ethers Carrying a Perhalogenated Moiety as Halogen Bond Donors by Cocrystallization with Nitrogen-Containing Acceptors. [PDF]

Cryst Growth Des
Kučas F, Posavec L, Bedeković N, Nemec V, Cinčić D.   +4 more
europepmc   +1 more source

Iron‐Photocatalyzed Alkene Chloroaminoxylation: A Platform for Orthogonally Activatable Building Blocks

Angewandte Chemie, EarlyView.
An iron‐photocatalyzed unsymmetrical 1,2‐hetero(atom)difunctionalization of alkenes enables to install orthogonal C–Cl and C–O (alkoxyamine) handles which provides access to diverse nucleophiles via complementary reactivity (SN and photoredox) at two distinct sites. Detailed mechanistic studies elucidate interesting features of the iron catalytic cycle.
Amrita Chaudhuri, Meghana Aladahalli Shekar, Mohammad Zafar, Marianne Engeser, Gregor Schnakenburg, Ala Bunescu   +5 more
wiley   +2 more sources

Stabilisation of Bromenium Ions in Macrocyclic Halogen Bond Complexes. [PDF]

Angew Chem Int Ed Engl
Docker A, Kuhn H, Beer PD.
europepmc   +1 more source

Halogen-Bond-Mediated ¹³C Overhauser Dynamic Nuclear Polarization at 9.4 T. [PDF]

J Phys Chem Lett
Yang L, Orlando T, Bennati M.
europepmc   +1 more source

Crystallographic Evidence for Bi(I) as the Heaviest Halogen Bond Acceptor. [PDF]

J Am Chem Soc
Griffin LP, Streit TN, Sievers R, Aldridge S, Gomila RM, Frontera A, Malischewski M.   +6 more
europepmc   +1 more source

The Halogen Bond to Ethers - Prototypic Molecules and Experimental Electron Density. [PDF]

ACS Omega
Schmidt A, Krupp A, Kleinheider J, Binnenbrinkmann TML, Wang R, Englert U, Strohmann C.   +6 more
europepmc   +1 more source

Short Sb···Sb Contacts in Polymorphic Tris(p‐Tolyl)Antimony: A Hallmark of Organoantimony(III) Solid‐State Chemistry?

Angewandte Chemie, EarlyView.
Discovery of polymorphism in solid tris(p‐tolyl)antimony(III) highlighted short, direct antimony‐antimony contacts, with interatomic separation shorter than the sum of the van der Waals radii, and calculated interaction energy of ca. 26 kJ mol−1 that includes a significant dispersion component.
Imogen Suh, Michael Ferguson, Filip Topić, Fu‐Qiang Gong, Mihails Arhangelskis, Hatem M. Titi, D. Scott Bohle, Vinko Nemec, Levente Kiss, Andrew J. Morris, Cristian Silvestru, Dominik Cinčić, Tomislav Friščić   +12 more
wiley   +1 more source

Unprecedented carbonic anhydrase inhibition mechanism: Targeting histidine 64 side chain through a halogen bond. [PDF]

Arch Pharm (Weinheim)
Paciotti R, Carradori S, Angeli A, D'Agostino I, Ferraroni M, Coletti C, Supuran CT.   +6 more
europepmc   +1 more source

Ambiphilic Ligand Stabilization of Aluminum(I) Fragments: Halides, Cations, and a Hydride

Angewandte Chemie, EarlyView.
Stabilization of elusive aluminum(I) halides in the framework of an ambiphilic ligand is reported. The unique bonding situation at the trigonal‐bipyramidal aluminum center is analyzed, and the coordination chemistry and Al(I)Br transfer reactivity of the complexes are presented.
Charlotte S. V. Weiß, Philipp Dabringhaus   +1 more
wiley   +1 more source

Tailoring Photochromism Beyond Human Eye Visibility: On/Off Switchable NIR Absorption in an Aluminosilicate

Angewandte Chemie, EarlyView.
A new photochromic material was developed. Its on/off‐switchable absorption band is situated completely outside the human eye's visibility, in the near‐infrared (NIR) region, a feature never reported before. The photochromism mechanism in this aluminosilicate is elucidated by combining experimental as well as computational results, and the material's ...
Bettiina Muurinen, Hannah Byron, Teppo Kreivilä, Roosa Vastamäki, Sami Vuori, Tomasz Galica, Ian P. Machado, Sari Granroth, Basit Ali, Maarit Karppinen, Ivo Heinmaa, Milica Todorović, Raphael Rullan, Stephan Steinmann, Tangui Le Bahers, Mika Lastusaari   +15 more
wiley   +1 more source