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Angewandte Chemie International Edition, EarlyView.Merging silylium‐ion and palladium catalysis provides a mechanistically distinct route to allylsilanes by formal C–H/Si–H metathesis. Using allylsilanes as silicon proelectrophiles, various allylarenes undergo migrative silylation, selectively yielding (E)‐allylsilanes.
Longhui Duan +5 more
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Halogen bond-induced electrophilic aromatic halogenations
Organic & Biomolecular Chemistry, 2021This review highlights the recent development of halogen bond-induced activations of N -halosuccinimides and N , N -dihalodimethylhydantoins in electrophilic aromatic halogenations.
Wanutcha Lorpaiboon, Pakorn Bovonsombat
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Chemical Society Reviews, 2012
Halogen bonding is the electron density donation based weak interaction of halogens with Lewis bases. Its applicability for molecular recognition processes long remained unappreciated and has so far mostly been studied in silico and in solid state.
Erdelyi, M.
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Halogen bonding is the electron density donation based weak interaction of halogens with Lewis bases. Its applicability for molecular recognition processes long remained unappreciated and has so far mostly been studied in silico and in solid state.
Erdelyi, M.
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On The Nature of the Halogen Bond
Journal of Chemical Theory and Computation, 2014The wide-ranging applications of the halogen bond (X-bond), notably in self-assembling materials and medicinal chemistry, have placed this weak intermolecular interaction in a center of great deal of attention. There is a need to elucidate the physical nature of the halogen bond for better understanding of its similarity and differences vis-à-vis other
Changwei, Wang +3 more
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On the directionality of halogen bonding
Physical Chemistry Chemical Physics, 2013The origin of the high directionality of halogen bonding was investigated quantum chemically by a detailed comparison of typical adducts in two different orientations: linear (most stable) and perpendicular. Energy decomposition analyses revealed that the synergy between charge-transfer interactions and Pauli repulsion are the driving forces for the ...
Stefan M, Huber +4 more
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An overview of halogen bonding
Journal of Molecular Modeling, 2006Halogen bonding (XB) is a type of noncovalent interaction between a halogen atom X in one molecule and a negative site in another. X can be chlorine, bromine or iodine.
Peter, Politzer +4 more
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Halogen Bonding Molecular Capsules
Angewandte Chemie International Edition, 2015AbstractMolecular capsules based solely on the interaction of halogen bonding (XB) are presented along with their host–guest binding properties in solution. The first example of a well‐defined four‐point XB supramolecular system is realized by decorating resorcin[4]arene cavitands with polarized halogen atoms for dimerization with tetra(4‐pyridyl ...
Dumele O, Trapp N, Diederich F
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Clˉ as the halogen bond acceptor: studies on strong halogen bonds
Structural Chemistry, 2017The Clˉ anion as the halogen bond acceptor, the diiodotetrafluoroethane I(CF2)2I and its derivatives I(MF2)nI (M = C, Si, Ge, Sn) as the halogen bond donor, and the strong halogen bonds could be formed. The halogen bonds between I(MF2)nI and Clˉ have been designed and investigated by Moller–Plesset perturbation/aug-cc-pVDZ calculations together with ...
Jiaojiao Wang +3 more
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Halogen Bonding in Supramolecular Chemistry
Angewandte Chemie International Edition, 2008AbstractHalogen bonding is the noncovalent interaction where halogen atoms function as electrophilic species. The energetic and geometrical features of the interaction are described along with the atomic characteristics that confer molecules with the specific ability to interact through this interaction.
METRANGOLO, PIERANGELO +4 more
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2014
Halogens are atypical elements in biology, but are common as substituents in ligands, including thyroid hormones and inhibitors, which bind specifically to proteins and nucleic acids. The short-range, stabilizing interactions of halogens - now seen as relatively common in biology - conform generally to halogen bonds characterized in small molecule ...
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Halogens are atypical elements in biology, but are common as substituents in ligands, including thyroid hormones and inhibitors, which bind specifically to proteins and nucleic acids. The short-range, stabilizing interactions of halogens - now seen as relatively common in biology - conform generally to halogen bonds characterized in small molecule ...
openaire +2 more sources