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Halogen Bonding in Two‐Dimensional Crystal Engineering
ChemistryOpen, 2020 Halogen bonds, which provide an intermolecular interaction with moderate strength and high directionality, have emerged as a promising tool in the repertoire of non‐covalent interactions.
Dr. Joan Teyssandier +2 more
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Combining high-resolution scanning tunnelling microscopy and first-principles simulations to identify halogen bonding [PDF]
Nature Communications, 2020 Scanning tunnelling microscopy (STM) is commonly used to identify on-surface molecular self-assembled structures. However, its limited ability to reveal only the overall shape of molecules and their relative positions is not always enough to fully solve ...
Bonifazi, Davide +5 more
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Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control [PDF]
Beilstein Journal of Organic Chemistry, 2023 Halogen bonding is commonly found with iodine-containing molecules, and it arises when Lewis bases interact with iodine’s σ-holes. Halogen bonding and σ-holes have been encountered in numerous monovalent and hypervalent iodine-containing compounds, and ...
Carlee A. Montgomery, Graham K. Murphy
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Site Selectivity of Halogen Oxygen Bonding in 5- and 6-Haloderivatives of Uracil [PDF]
Crystals, 2019 Seven 5-and 6-halogenated derivatives of uracil or 1-methyluracil (halogen = Cl, Br, I) were studied by single crystal X-ray diffraction. In contrast with pure 5-halouracils, where the presence of N-H⋯O and C-H⋯O hydrogen bonds prevents the formation of ...
Gustavo Portalone
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Enhanced enantioselectivity in halogen-bonding catalysis [PDF]
Communications Chemistry, 2023 Chiral halogen-bonding catalysts have emerged as a new approach towards asymmetric catalysis, but enantioselectivities have thus far remained low. Now, fine-tuning the substrate–catalyst halogen–halogen interactions is shown to significantly enhance ...
Victoria Richards
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Crystals, 2021 This manuscript reports the synthesis and X-ray characterization of two octahydro-1H-4,6-epoxycyclopenta[c]pyridin-1-one derivatives that contain the four most abundant halogen atoms (Ha) in the structure with the aim of studying the formation of Ha···Ha
Dmitriy F. Mertsalov +6 more
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Halogen Bonding: A Halogen-Centered Noncovalent Interaction Yet to Be Understood
Inorganics, 2019 In addition to the underlying basic concepts and early recognition of halogen bonding, this paper reviews the conflicting views that consistently appear in the area of noncovalent interactions and the ability of covalently bonded halogen atoms in ...
Pradeep R. Varadwaj +2 more
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Interplay of halogen bonding and solvation in protein–ligand binding [PDF]
iScienceSummary: Halogen bonding is increasingly utilized in efforts to achieve high affinity and selectivity of molecules designed to bind proteins, making it paramount to understand the relationship between structure, dynamics, and thermodynamic driving forces.
Maria Luisa Verteramo +13 more
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Molecules, 2022 This study expands and combines concepts from two of our earlier studies. One study reported the complementary halogen bonding and π-π charge transfer complexation observed between isomeric electron rich 4-N,N-dimethylaminophenylethynylpyridines and the ...
Erin D. Speetzen +3 more
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Molecules, 2023 Charge-shift (CS) bonding is a new bonding paradigm in the field of chemical bonds. Our recent study has revealed that certain Cu/Ag/Au-bonds display both CS bonding and ω-bonding characters. In this investigation, we extend our study to halogen bonding.
Junjie Song +6 more
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