Role of Halogen Substituents on Halogen Bonding in 4,5-DiBromohexahydro-3a,6-Epoxyisoindol-1(4H)-ones [PDF]
Crystals, 2021 A series of 4,5-dibromo-2-(4-substituted phenyl)hexahydro-3a,6-epoxyisoindol-1(4H)-ones were synthesized by reaction of the corresponding 2-(4-substituted phenyl)-2,3,7,7a-tetrahydro-3a,6-epoxyisoindol-1(6H)-ones with [(Me2NCOMe)2H]Br3 in dry chloroform ...
Atash V. Gurbanov +9 more
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Preorganization: A Powerful Tool in Intermolecular Halogen Bonding in Solution
ChemistryOpen, 2020 Preorganization is a powerful tool in supramolecular chemistry which has been utilized successfully in intra‐ and intermolecular halogen bonding. In previous work, we had developed a bidentate bis(iodobenzimidazolium)‐based halogen bond donor which ...
Martin H. H. Voelkel +2 more
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Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control [PDF]
Beilstein Journal of Organic Chemistry, 2023 Halogen bonding is commonly found with iodine-containing molecules, and it arises when Lewis bases interact with iodine’s σ-holes. Halogen bonding and σ-holes have been encountered in numerous monovalent and hypervalent iodine-containing compounds, and ...
Carlee A. Montgomery, Graham K. Murphy
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Enhanced enantioselectivity in halogen-bonding catalysis [PDF]
Communications Chemistry, 2023 Chiral halogen-bonding catalysts have emerged as a new approach towards asymmetric catalysis, but enantioselectivities have thus far remained low. Now, fine-tuning the substrate–catalyst halogen–halogen interactions is shown to significantly enhance ...
Victoria Richards
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Interplay of halogen bonding and solvation in protein–ligand binding [PDF]
iScienceSummary: Halogen bonding is increasingly utilized in efforts to achieve high affinity and selectivity of molecules designed to bind proteins, making it paramount to understand the relationship between structure, dynamics, and thermodynamic driving forces.
Maria Luisa Verteramo +13 more
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Investigation of the Effect of Solvents on the Synthesis of Aza-flavanone from Aminochalcone Facilitated by Halogen Bonding. [PDF]
ACS Omega, 2023 Maharana RR, Bhanja R, Mal P, Samanta K.
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Amphoteric chalcogen-bonding and halogen-bonding rotaxanes for anion or cation recognition. [PDF]
Nat ChemTse YC +4 more
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Molecules, 2022 This study expands and combines concepts from two of our earlier studies. One study reported the complementary halogen bonding and π-π charge transfer complexation observed between isomeric electron rich 4-N,N-dimethylaminophenylethynylpyridines and the ...
Erin D. Speetzen +3 more
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Molecules, 2023 Charge-shift (CS) bonding is a new bonding paradigm in the field of chemical bonds. Our recent study has revealed that certain Cu/Ag/Au-bonds display both CS bonding and ω-bonding characters. In this investigation, we extend our study to halogen bonding.
Junjie Song +6 more
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Engineered Binding Microenvironments in Halogen Bonding Polymers for Enhanced Anion Sensing. [PDF]
Angew Chem Int Ed Engl, 2023 Bąk KM +4 more
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