Results 101 to 110 of about 19,455 (274)
The X40x10 Halogen Bonding Benchmark Revisited: Surprising Importance of (n-1)d Subvalence Correlation [PDF]
, 2018 We have re-evaluated the X40x10 benchmark for halogen bonding using conventional and explicitly correlated coupled cluster methods. For the aromatic dimers at small separation, improved CCSD(T)–MP2 “high-level corrections” (HLCs) cause substantial ...
Nitai, Sylvetsky +3 more
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Halogen Bonding in Crystal Engineering
, 2012 The structural features of a molecule are determined by the covalent bonds within the molecule. Modification of the structure requires the breaking and creation of covalent bonds. Similarly, the intrinsic reactivity of a molecule arises from the covalently bonded functional groups and active sites on a molecule.
Haukka Matti, Tuikka Matti, Ding Xin
openaire +2 more sources
Advanced Materials Technologies, EarlyView.ABSTRACT Molybdenum disulfide (MoS2) has attracted attention as a promising material due to the growing demand for environmentally friendly, cost‐effective, and efficient water treatment techniques. With its physicochemical characteristics, this stratified bidimensional material allows it to be highly effective in adsorption and catalytic performance ...
Pariksha Bishnoi +4 more
wiley +1 more source
The study of halogen bonding induced reaction [PDF]
, 2016 As a classic non-covalent bond interaction, halogen bonding is well studied in material sciences and crystal engineering, and its application in catalysis has attracted research attention in these years.
He, Wei
core +1 more source
Advanced Materials Technologies, EarlyView.This work highlights the impact of incorporating graphene nanoflakes into precursor inks of MAPbBr3 for inkjet‐printed optoelectronic device applications. A substantial modification of the crystallization dynamics is reported despite miniscule concentrations.
Kenneth Lobo +12 more
wiley +1 more source
Turning Water Into a Tool: From Degradation Pathways to Functional Engineering in Halide Perovskites
Advanced Materials Technologies, EarlyView.Water exhibits a threshold‐dependent dual role in lead halide perovskites, acting either as a degradation trigger or as a powerful tool for defect passivation, recrystallization, and structural engineering. This review discusses how controlled water‐mediated interactions govern stability, dimensionality, and optoelectronic performance, providing ...
Raphaella T. S. Gonçalves +4 more
wiley +1 more source
Fluorinated azobenzenes as supramolecular halogen-bonding building blocks
Beilstein Journal of Organic Chemistry, 2019 ortho-Fluoroazobenzenes are a remarkable example of bistable photoswitches, addressable by visible light. Symmetrical, highly fluorinated azobenzenes bearing an iodine substituent in para-position were shown to be suitable supramolecular building blocks ...
Esther Nieland +2 more
doaj +1 more source
Advanced Materials Technologies, EarlyView.Extrusion‐based bioprinting (EBB) has emerged as a versatile biofabrication platform capable of precisely depositing bioinks composed of biomaterials, cells, and bioactive agents to generate patient‐specific, biomimetic skin constructs. This paper presents a state‐of‐the‐art and forward‐looking overview of EBB for wound healing, encompassing printing ...
Hien‐Phuong Le +4 more
wiley +1 more source
Characterization of halogen-bonded complexes in systems with competing hydorgen-bonding or electron transfer [PDF]
, 2023 Halogen bonding (HaB) is an intermolecular attraction between covalently bonded electron-poor halogen atoms and electron-rich species, similar to hydrogen bonding (HyB).
Adeniyl, Emmanuel
core
Halogen-Bond-Induced Consecutive Csp3–H Aminations via Hydrogen Atom Transfer Relay Strategy [PDF]
, 2020 The utilization of a halogen bond in a number of chemical fields is well-known. Surprisingly, the incorporation of this useful noncovalent interaction in chemical reaction engineering is rare. We disclose here an uncommon use of halogen bonding to induce
Nur-E Alom +13 more
core +1 more source