Results 171 to 180 of about 379,037 (236)

Halogen Bonding-Sustained Accumulation of Polyiodide in Hierarchically Open Micellar Film for Shuttle-Free Long-Duration Zn-I₂ Battery. [PDF]

Angew Chem Int Ed Engl
Li Z, Wang J, Yang N, Chen R, Feng Z, Sun Y, Shen C, Qiu H.   +7 more
europepmc   +1 more source

Syntheses, X‐ray Crystal Structures, and Raman Spectra of Self‐Assembled XeO3 Chain and Network Complexes of Polytopic sp2‐ and sp3‐Nitrogen Bases

Angewandte Chemie, EarlyView.
Supramolecular 1‐D, 2‐D, and 3‐D networks comprised of ‐(‐O═Xe(O2)‐‐)‐∞ and ‐(‐Xe(O2)O‐‐‐HO(H)‐‐)‐∞ chains coordinated to polytopic N‐base ligands were synthesized and structurally characterized by X‐ray crystallography. Their Xe‐‐‐N and Xe‐‐‐O bonds are characteristic of σ–hole bonds in which the nucleophilic Lewis base sites of the N‐ligands, H2O ...
James T. Goettel, Hélène P. A. Mercier, Gary J. Schrobilgen   +2 more
wiley   +2 more sources

Control of Conical Intersection Dynamics in CF₃I Photodissociation via Halogen Bonding. [PDF]

JACS Au
Yan D, Zhang H, Li F, Yang M, Liu J, Ma Y, Xu A, Zhou T, Yang M, Zhou M, Wang F.   +10 more
europepmc   +1 more source

Cocrystallization of Antifungal Compounds Mediated by Halogen Bonding. [PDF]

Cryst Growth Des, 2023
Benito M, Frontera A, Molins E.
europepmc   +1 more source

S = 3/2 Iron(I)‐Bisphosphine‐Ate Complexes: Synthesis, Characterization, and Reactivity for Electrophile Activation

Angewandte Chemie, EarlyView.
In this work, we present a new class of unusual charged Fe(I)‐bisphosphine‐ates, along with full characterization of their structure and bonding, utilizing low‐temperature synthetic and spectroscopic and techniques. These complexes are highly reactive toward catalytically relevant electrophiles, and can serve as valuable synthons providing access to ...
Egor Kokin, Shih‐Chieh Kao, Matthew J. Kania, Michael L. Neidig   +3 more
wiley   +2 more sources

Enhanced Selectivity of Chalcogen Bonding over Halogen Bonding Catalyzed C-glycosylation Through Differentiated Intermediate Activation. [PDF]

Angew Chem Int Ed Engl
Guo H, Loh CCJ.
europepmc   +1 more source

Asymmetric Counteranion-Directed Halogen Bonding Catalysis. [PDF]

J Am Chem Soc
Reinhard DL, Iniutina A, Reese S, Shaw T, Merten C, List B, Huber SM.   +6 more
europepmc   +1 more source

Halogen Bonding in Sulphonamide Co-Crystals: X···π Preferred over X···O/N? [PDF]

Molecules, 2023
Heinen T, Merzenich S, Kwill A, Vasylyeva V.   +3 more
europepmc   +1 more source

Radical, Not Ionic: The Mechanochemical Zincke Nitration of Phenols

Angewandte Chemie, EarlyView.
Mechanochemistry recasts the classical Zincke nitration as an open‐shell process. Liquid‐assisted vibrational milling of phenols with in situ HNO2 delivers direct and ipso nitration across 50 substrates, while atmosphere, NOx‐transfer, EPR and DFT evidence expose a phenoxyl‐radical/NO2 manifold underlying this historically ionic transformation ...
Roberto Scipione, Francesco Basoccu, Pietro Caboni, Francesca Sardu, Enrico Podda, Marco Lucarini, Massimiliano Arca, Andrea Porcheddu   +7 more
wiley   +2 more sources

Halogen bonding-induced 1,3-carbohydroxylation of allyl carboxylates <i>via</i> 1,2-cationic acyloxy migration (1,2-CAM). [PDF]

Chem Sci
Sharma S, Zhao G, Bedda L, Khosravi A, Musaev DG, Ngai MY.   +5 more
europepmc   +1 more source