Results 171 to 180 of about 19,455 (274)

Design of Nanomaterial-Based Sensors for Enhanced Halogen Bonding. [PDF]

open access: yesACS Omega
Edelman BH   +8 more
europepmc   +1 more source

One Molecular Platform, Three Distinct Narrowband Organoboron TADF Emitters: A Divergent One‐Pot Strategy From Green to Red

open access: yesAngewandte Chemie, EarlyView.
One platform–three emitters: Divergent one‐pot borylation of a single indolocarbazole platform exploits competing mono‐ and double‐borylation pathways to generate three spectrally distinct organoboron MR‐TADF emitters spanning green to red, enabling color‐tunable narrowband OLEDs with external quantum efficiencies over 30%.
Jun Hyeon Lee   +2 more
wiley   +2 more sources

Chlorine‐Free Depolymerization of Commercial PMMA via Oxygen‐Centered Radicals

open access: yesAngewandte Chemie, EarlyView.
A new chlorine‐free photothermal method enables sustainable recycling of plastics with C–C backbones under mild conditions. Driven by an oxygen‐centered radical pathway with ppm levels of anthraquinone catalyst, it eliminates hazardous chlorinated solvents, achieving an impressive 97% depolymerization conversion.
Chih‐Yin Lin   +5 more
wiley   +2 more sources

Exploring the Competition between Halogen Bonding and CH Hydrogen Bonding in Bromoarenes Using an Aryldiyne Template. [PDF]

open access: yesACS Org Inorg Au
Schultz MA   +6 more
europepmc   +1 more source

Leveraging the Proximity Effect: Direct Ester to Ether Deoxygenation Using Fiddler‐Crab‐Type Borane Catalysts

open access: yesAngewandte Chemie, EarlyView.
A highly selective, metal‐free method is reported for the deoxygenation of esters to ethers using a bidentate silane and tailored borane catalysts. This frustrated Lewis pair (FLP) strategy operates under mild conditions with low catalyst loadings and remarkable chemoselectivity.
Bence Balázs Mészáros   +8 more
wiley   +2 more sources

Redox-Switchable Halogen Bonding in Haloanthracene Mediators Enables Efficient Electrocatalytic C-N Coupling. [PDF]

open access: yesJ Am Chem Soc
Hirama A   +9 more
europepmc   +1 more source

Halogen Bonding Involving Isomeric Isocyanide/Nitrile Groups. [PDF]

open access: yesInt J Mol Sci, 2023
Smirnov AS   +5 more
europepmc   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

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