Results 181 to 190 of about 379,037 (236)

NHC‐Copper(I)‐Mediated Functionalization of White Phosphorus

Angewandte Chemie, EarlyView.
White phosphorus is functionalized by N‐heterocyclic carbene supported copper(I) complexes through redox‐neutral steps. Treatment of the resulting complexes with electrophiles releases the ligands from the metal center as asymmetrically substituted organophosphorus butterfly compounds.
Thomas M. Horsley Downie, Sophia A. Vogler, Gábor Balázs, Francesco Cirigliano, Robert Wolf   +4 more
wiley   +2 more sources

Chloride Selective, Nonprotonophoric Ion Transport with Macrocyclic Halogen Bonding Anionophores. [PDF]

Chemistry
Flerin M, Duarte F, Langton MJ.
europepmc   +1 more source

Cobalt‐Catalyzed [2σ+2π] Cycloaddition via Site‐Selective Capture of Bicyclobutane Diradical

Angewandte Chemie, EarlyView.
We report a Co(II)‐catalyzed strategy that combines thermal activation of bicyclo[1.1.0]butane (BCBs) with site‐selective radical capture to furnish head‐to‐head fused bicyclo[2.1.1]hexanes via [2σ+2π] cycloaddition with indoles. Detailed mechanistic studies (31P NMR, EPR, CV, and DFT) support the catalytic pathway, while phosphine‐oxide trapping and X‐
Tanmayee Nanda, Alexander Umanzor, Julia Gartzke, Jeremy T. Maddigan‐Wyatt, Philipp Thielert, Stefan Weber, Sabine Richert, Shuming Chen, Daniel B. Werz   +8 more
wiley   +2 more sources

Halogen bonding-guided growth of heteroatom-rich polycarbazole wires on Au(111). [PDF]

Nanoscale Adv
Palmino F, Luzet V, Jeannoutot J, Rochefort A, Chérioux F.   +4 more
europepmc   +1 more source

Chalcogen‐Bond‐Driven Electrochemical Bromide Sequestration in Benzothiazole‐Functionalized Covalent Organic Frameworks

Angewandte Chemie, EarlyView.
To address the unresolved challenge of selective bromide removal from reverse‐osmosis permeate, we developed benzothiazole‐functionalized COF/rGO electrodes that exploit directional chalcogen bonding to preferentially capture Br− over Cl−. The mesoporous BTzTp@rGO electrode achieved a maximum Br− uptake of 36.7 mg g−1, a Br−/Cl− selectivity factor of ...
Najat Maher Aldaqqa, Rajesh Dhanushkotti, Sara Vaca‐Chacon, Sushil Kumar, Thibault Terencio, Kyriaki Polychronopoulou, Gisha Elizabeth Luckachan, Dinesh Shetty   +7 more
wiley   +2 more sources

Halogen Bonding and Rearrangements in Complexes of N-Chlorosuccinimide with Halides. [PDF]

Molecules
Hardin M, Zeller M, Rosokha SV.
europepmc   +1 more source

Dual Semiconductor-Photoredox/Halogen-Bonding Organocatalyzed Cascade Sulfonylation/Cyclization of Alkynes and Alkenes with RSO₂Cl. [PDF]

Adv Sci (Weinh)
Wang YH, He LH, Tan YY, Zhang ZT, Xu YD, Ding R, Jiang J, He WM.   +7 more
europepmc   +1 more source

Synthesis, Structure, and Reactivity of Hypervalent Iodine Reagents Stabilized by Internal Out-of-Plane Halogen Bonding: <i>ortho-</i>Bromo and <i>ortho-</i>Chloro-Substituted [Hydroxy(tosyloxy)iodo]arenes and Iodonium Ylides. [PDF]

J Org Chem
Zarrabi N, Hughes G, Herrmann B, Krystosek S, Tyson DR, Funk Y, Rohde GT, Zhdankin VV.   +7 more
europepmc   +1 more source

Isoelectronic Push-Pull Fluorescent Difluoroborates: Halogen Bonding and Photophysical Properties. [PDF]

J Org Chem
Iglesias-Reguant A, Barańska I, Plażuk D, Zaleśny R, Luis JM, Ośmiałowski B.   +5 more
europepmc   +1 more source

Metal-Involving Bifurcated Halogen Bonding with Iodide and Platinum(II) Center. [PDF]

Int J Mol Sci
Kryukova MA, Kostareva MB, Cheranyova AM, Khazanova MA, Rozhkov AV, Ivanov DM.   +5 more
europepmc   +1 more source