Results 211 to 220 of about 18,040 (292)

(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications

Angewandte Chemie, EarlyView.
In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh, Nicole Hanania, Pinaki Nad, Tipu Alam, Tamir Kish, Ahmad Masarwa   +5 more
wiley   +2 more sources

Multidentate Iodoalkyne Receptors as Halogen Bond Donors

, 2015
Harumi Takasaki
openalex   +1 more source

Bidentate Chiral Bis(imidazolium)-Based Halogen Bond Donors: Synthesis and First Applications in Enantioselective Recognition and Catalysis

, 2019
Revannath L. Sutar, Elric Engelage, Raphael Stoll, Stefan Huber   +3 more
openalex   +1 more source

Halide Bond Assisted Double Desymmetrization of Meso‐Dicarboxylic Acids with Symmetrical Olefins via Asymmetric Halogenation

Angewandte Chemie, EarlyView.
This work demonstrates a double desymmetrization of meso‐dicarboxylic acids with symmetrical olefins, constructing complex chiral lactones with six stereocenters in one step. Unexpectedly, the halide bond was found to be crucial in achieving high stereoselectivity.
Qingyu Zhang, Haihui Wang, Ying‐Lung Steve Tse, Ying‐Yeung Yeung   +3 more
wiley   +2 more sources

Hyperuniform Mesoporous Gold Films Coated with Halogen-Bonding Metal-Organic Frameworks for Selective Raman Sensing of Chlorinated Hydrocarbons. [PDF]

ACS Nano
Khairunnisa SZ, Guselnikova O, Kang Y, Postnikov PS, Valiev RR, Hill JP, Nugraha N, Yuliarto B, Yamauchi Y, Henzie J.   +9 more
europepmc   +1 more source

Unnatural Amino Acid and Emerging Chemistry Approaches to Map RNA–Protein Interactions

Angewandte Chemie, EarlyView.
This review highlights emerging chemistries for mapping RNA–protein interactions, including genetically encoded unnatural amino acids, novel photocrosslinkers, and non‐photoactivatable crosslinking systems. We compare their mechanisms, reactivity and applications, outlining how these next‐generation tools enable higher‐resolution, site‐specific ...
Eryn Lundrigan, Parrish Evers, Elexa Scott, John Paul Pezacki   +3 more
wiley   +1 more source

Publisher Correction: Amphoteric chalcogen-bonding and halogen-bonding rotaxanes for anion or cation recognition. [PDF]

Nat Chem
Tse YC, Docker A, Marques I, Félix V, Beer PD.   +4 more
europepmc   +1 more source

Interfacial halogen bonding with charge-transport layers for operational stability of hybrid perovskite solar cells.

Energy Adv
Lukić JN, Luo W, Kim S, Ferrer L, Ortiz J, Molina D, Kim J, Venegas JA, Zimmermann P, Nguyen TD, Hinderhofer A, Schreiber F, Sastre-Santos Á, Seo JY, Radmilović VV, Milić JV.   +15 more
europepmc   +1 more source

Polarization Upends Convention: Halogen Bonding Propensities of Main Group Halides. [PDF]

J Phys Chem A
Robinson N, Pham N, Donald KJ.
europepmc   +1 more source

Photothermal Conversion Promotes Challenging SNAr for Facile C─N Bond Formation

Angewandte Chemie, EarlyView.
Photothermal conversion enables facile aromatic C─N bond formation via red light irradiation. A variety of inter‐ and intramolecular SNAr transformations are achieved under mild, schematically simple conditions. Additionally, a thermally promoted halogen exchange mechanism provides access to aryl bromides, chlorides, and fluorides – making this ...
Megan E. Matter, Rory C. Devin, Erin E. Stache   +2 more
wiley   +2 more sources