Results 211 to 220 of about 1,415,920 (286)

Intramolecular N···F Pnictogen Bond Mitigates the Explosive Behavior of Azido‐L‐Phenylalanines

ChemistryEurope, EarlyView.
An intramolecular N···F pnictogen bond is the key for the chemical stabilization of the fluorinated azido‐L‐phenylalanines, mitigating the risk of explosion and thus facilitating the handling and storage of these materials. Organic azides are versatile intermediates but are plagued by intrinsic instability and potential explosiveness. Here, it is shown
Andrea Pizzi, Eleonora Veronese, Nicola Demitri, Marco Saccone, Pierangelo Metrangolo, Giancarlo Terraneo   +5 more
wiley   +1 more source

Illuminating the Performance of Electron Withdrawing Groups in Halogen Bonding. [PDF]

Chemphyschem
Devore DP, Ellington TL, Shuford KL.
europepmc   +1 more source

Organophotoredox/Cobalt‐Catalyzed Retro‐Hydroformylation of Aldehydes

ChemistryEurope, EarlyView.
A new photoredox/cobalt retro‐hydroformylation is developed. This one‐pot two‐step process involves the in situ formation of the corresponding 1,4‐dihydropyridine as key intermediate. Under mild reaction conditions, alkenes are efficiently produced from a wide range of aliphatic α‐monosubstituted aldehydes, with high functional‐group tolerance.
Augustin Nouaille, Emmanuel Magnier, Corinne Gosmini, Guillaume Dagousset   +3 more
wiley   +1 more source

Polarization Upends Convention: Halogen Bonding Propensities of Main Group Halides. [PDF]

J Phys Chem A
Robinson N, Pham N, Donald KJ.
europepmc   +1 more source

Skeletal Editing from Pyridine to Aniline via C‐Insertion and N‐Isomerization

ChemistryEurope, EarlyView.
A concise protocol is presented that converts pyridines into anilines by externalizing the original pyridine nitrogen at either the "ipso" or "ortho" position, which results in para or meta‐primary aniline products. A key carbene‐insertion step precedes nitrogen migration, preserving both ring size and overall structure.
Yun Luo, Jing Dai, Yongchang Wei, Chang Min   +3 more
wiley   +1 more source

Non-Symmetrical Tetradentate Mixed Halogen Bonding-Hydrogen Bonding Macrocycles for Anion Recognition in Aqueous-Organic Media. [PDF]

Chem Asian J
Opascharoenboon S, Vigromsitdet S, Cheevathanomsak N, Atirojwanich I, Tantirungrotechai J, Sukwattanasinitt M, Surawatanawong P, Beer PD, Bunchuay T.   +8 more
europepmc   +1 more source

From Two‐Electron to Four‐Electron System: Electrolyte Regulation for Advanced Aqueous Zn–I2 Batteries

Carbon Energy, EarlyView.
This review systematically summarizes recent progress in electrolyte‐regulated aqueous Zn–I2 batteries (AZIBs). It outlines the fundamentals of AZIBs along with their main challenges, and then analyzes electrolyte‐engineering strategies that improve both two‐ and four‐electron reactions.
Yucong Wang, Ruifeng Huang, Zhangchi Yang, Shaojian Zhang, Lijing Yan, Weijie Chen, Xiaolong Lin, Yongjun Li, Shuxing Wu, Zhan Lin, Jun Lu   +10 more
wiley   +1 more source

Evaluating the halogen bonding strength of a iodoloisoxazolium(III) salt. [PDF]

Beilstein J Org Chem
Reinhard DL, Schmidt A, Sons M, Wolf J, Engelage E, Huber SM.   +5 more
europepmc   +1 more source

Recent Strategies Toward Durable and Ion‐Tolerant Transition Metal‐Based Electrocatalysts in Seawater Electrolysis

Carbon Energy, EarlyView.
Recent strategies address these challenges through ion‐specific regulation, encompassing chloride‐tolerant and chloride‐regulating anodes together with cathode designs that suppress OH− accumulation and Mg2+/Ca2+ coupling. This ion‐management‐oriented framework provides general guidelines for achieving stable, selective, and scalable seawater ...
Lina Li, Wenda Zhang, Xinti Yu, Ning Han, Zhangxing Chen, Heng Zhao   +5 more
wiley   +1 more source