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Asymmetric bifurcated halogen bonds
Physical Chemistry Chemical Physics, 2015Depending on the relative orientation of the halogen-bond donor and acceptor, this bifurcated interaction may be classified as ‘σ-hole – lone pair’ or ‘σ-hole – π’ bonding.
Novák, Martin +2 more
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A direct look at halogen bonds
Science, 2017High-resolution images of halogen-containing molecules reveal unusual bonding ...
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Halogen bonding anion recognition
Chemical Communications, 2016The development of solution-based anion receptor molecules which exploit halogen bonding interactions is an emerging area of research. ThisFeature Articlereviews recent advances which have been made in this rapidly developing field, surveying the use of iodoperfluoroarene, haloimidazolium and halotriazole/triazolium halogen-bond-donor motifs in anion ...
Asha, Brown, Paul D, Beer
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The halogen bond: an interim perspective
Physical Chemistry Chemical Physics, 2010There has been an upsurge of interest in the halogen bond during the last decade. This non-covalent interaction is less familiar than the hydrogen bond, but is similar to it in several respects. In this article, we first discuss the nature of the halogen bond in the gas phase, as established by systematic investigations of the rotational spectra of ...
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Chalcogen Bond: A Sister Noncovalent Bond to Halogen Bond
The Journal of Physical Chemistry A, 2009A sister noncovalent bond to halogen bond, termed chalcogen bond, is defined in this article. By selecting the complexes H(2)CS...Cl(-), F(2)CS...Cl(-), OCS...Cl(-), and SCS...Cl(-) as models, the bond-length change, interaction energy, topological property of the electron charge density and its Laplacian, and the charge transfer of the chalcogen bond ...
Weizhou, Wang, Baoming, Ji, Yu, Zhang
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Halogen bonding: Recent advances
Current Opinion in Solid State and Materials Science, 2009Halogen bonding (XB), as a directional interaction between covalently bound halogen atoms (XB donor) and Lewis bases (A, XB acceptor), has been recently intensively investigated as a powerful tool in crystal engineering. After a short review on the origin and general features of halogen bonding, current developments towards (i) the elaboration of three-
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Faraday Discuss., 2017
The models behind simple bonding theory and the origins of some components often proposed to be involved in weak intermolecular bonds are described with special reference to σ-hole bonding, of which halogen bonds are a subset. A protocol for the analysis of weak intermolecular interactions is proposed on the basis of sound physical principles.
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The models behind simple bonding theory and the origins of some components often proposed to be involved in weak intermolecular bonds are described with special reference to σ-hole bonding, of which halogen bonds are a subset. A protocol for the analysis of weak intermolecular interactions is proposed on the basis of sound physical principles.
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Studies in halogen-halogen bonding
Theoretica Chimica Acta, 1970G. H. Cheesman +2 more
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Halogen bonding in room-temperature phosphorescent materials
Coordination Chemistry Reviews, 2020Weizhou Wang, Wei Jun Jin
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