Results 71 to 80 of about 379,037 (236)
Can Elastomers Combine Stiffness, Toughness and Fatigue Resistance?
Advanced Materials, EarlyView.This review studies how the molecular and macroscopic architecture of elastomers influence their mechanical properties including: stiffness, stretchability, toughness, fatigue resistance, and damping behavior. By linking the structure to performance, it proposes design principles for advanced elastomeric systems that combine mechanical properties ...
Eva Baur, Esther Amstad
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Advanced Materials, EarlyView.Our work introduces a new framework that fundamentally changes how orientation in bismuth oxyhalide systems is approached. Comprehensive experiments, backed by theoretical models, reveal the pivotal role of halide anions to modify the van der Waals stacking energies required to direct orientation. Our method enables the fabrication of near perfect (001)
Gabriel Aygur +10 more
wiley +1 more source
Hydrogen Bonding versus Halogen Bonding in Host–Guest Compounds
, 2016 The similarity and differences of the three host compounds H1 = 9,9′-(biphenyl-2,2′-diyl)difluoren-9-ol, H2 = 2,2′,7,7′-tetrabromo-9,9′-(biphenyl-2,2′-diyl)difluoren-9-ol, and H3 = 2,2′,7,7′-tetra-tert-butyl-9,9′-(1,4-phenylene)difluoren-9-ol which ...
Susan A. Bourne (1576081) +4 more
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Advanced Materials, EarlyView.Environmental Synthesis Radar (ESR) evaluates the environmental impact of (early‐stage) multi‐step chemical syntheses, providing a holistic view by using 18 midpoint impact categories. Unlike conventional life‐cycle assessment (LCA) approaches, ESR reveals three complementary metrics: overall impact Vtotal, environmental hotspots VEF, and critical ...
Laura Plein +8 more
wiley +1 more source
, 2022 Six novel halogen-bonded cocrystals of 1,3,5-triiodo-2,4,6-trifluorobenzene with three structural isomers of benzoylpyridine have been synthesized mechanochemically and by crystallization from solution, five of which were structurally characterized.
Nea Baus Topić (12557492) +4 more
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Advanced Materials, EarlyView.Molecular doping redistributes the internal electric field in organic photodetectors, providing a new degree of freedom to spatially control carrier transport and collection. Simulations and experiments reveal distinct transport pathways for injected and photogenerated carriers, enabling low dark current under reverse bias and wavelength‐selective ...
Jingwei Yi +15 more
wiley +1 more source
Halogen Bonding: A Halogen-Centered Noncovalent Interaction Yet to Be Understood
Inorganics, 2019 In addition to the underlying basic concepts and early recognition of halogen bonding, this paper reviews the conflicting views that consistently appear in the area of noncovalent interactions and the ability of covalently bonded halogen atoms in ...
Pradeep R. Varadwaj +2 more
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Advanced Materials, EarlyView.Stepwise dual‐side functionalization creates covalent Janus graphene with chemically and electrostatically asymmetric interfaces. The resulting nonadditive surface‐potential response and pronounced charge‐transport modulation demonstrate a versatile route for tailoring the electronic properties of graphene.
Shishi Liu +14 more
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Atom transfer radical addition (ATRA) reactions are crucial for the dual functionalization of unsaturated hydrocarbons. Radical generation, pivotal in ATRA, has seen advancements from thermal to photochemical methods.
Eiji Yamaguchi (1447486) +2 more
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Descriptor‐Informed Screening of Interface‐Active Molecules for Efficient Magnesium Metal Anodes
Advanced Materials, EarlyView.A descriptor‐informed molecular screening strategy identifies 4‐bromo‐N, N‐dimethylaniline (BrNNA) as an interface‐active electrolyte component that enables fast Mg stripping/plating in Mg(TFSI)2‐based electrolytes. By simultaneously regulating Mg2+ solvation and interphase formation, the BrNNA‐containing electrolyte delivers activation‐free Mg ...
Hao Xu +16 more
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