Results 71 to 80 of about 54,172 (278)

Editorial: Advanced Research in Halogen Bonding

Crystals, 2022
The Special Issue on “Advanced Research in Halogen Bonding” is a collection of 17 original articles reporting the results of theoretical and experimental studies that provide new insights into this fascinating intermolecular interaction [...]
Sergiy V. Rosokha, Atash V. Gurbanov
doaj   +1 more source

Coordination networks incorporating halogen-bond donor sites and azobenzene groups [PDF]

, 2016
Two Zn coordination networks, [Zn(1)(Py)2]2(2-propanol)n (3) and [Zn(1)2(Bipy)2](DMF)2n (4), incorporating halogen-bond (XB) donor sites and azobenzene groups have been synthesized and fully characterized.
Fernandez-Palacio F., Metrangolo P., Pilati T., Priimagi A., Resnati G., Saccone M., Terraneo G.   +6 more
core   +1 more source

Halogen Bond Asymmetry in Solution [PDF]

Journal of the American Chemical Society, 2018
Halogen bonding is the noncovalent interaction of halogen atoms in which they act as electron acceptors. Whereas three-center hydrogen bond complexes, [D···H···D]+ where D is an electron donor, exist in solution as rapidly equilibrating asymmetric species, the analogous halogen bonds, [D···X···D]+, have been observed so far only to adopt static and ...
Sofia Lindblad, Krenare Mehmeti, Alberte X. Veiga, Bijan Nekoueishahraki, Jürgen Gräfenstein, Máté Erdélyi   +5 more
openaire   +4 more sources

Halide‐Dependent Photoluminescence and Heavy‐Atom Effects in Low‐Melting Organic–Inorganic Manganese Halides

Advanced Functional Materials, EarlyView.
Two pyridinium‐based ionic liquid templated hybrid manganese halides, (C4Py)2[MnCl4] and (C4Py)2[MnBr4], display similar bulk structures but show significantly different photoluminescence behaviors due to the bromine heavy‐atom effect. Their stable local Mn environments remain intact even in the molten state, allowing applications such as luminescence ...
Biswajit Bhattacharyya, Christian Balischewski, Jiyong Kim, Tiago Duarte, Lianshe Fu, Rute A.S. Ferreira, Alkit Beqiraj, Iuliia Mikulska, Diego Gianolio, Eric Sperlich, Felix Stete, Wouter Koopman, Christina Günter, Katlen Brennenstuhl, Daniel Van Opdenbosch, Cordt Zollfrank, Armin Wedel, Beth J. Murray, Małgorzata Swadźba‐Kwaśny, Tillmann Klamroth, Michael U. Kumke, Verónica de Zea Bermudez, Andreas Taubert   +22 more
wiley   +1 more source

Thermodynamics and Spectroscopy of Halogen- and Hydrogen-Bonded Complexes of Haloforms with Aromatic and Aliphatic Amines

Molecules, 2022
Similarities and differences of halogen and hydrogen bonding were explored via UV–Vis and 1H NMR measurements, X-ray crystallography and computational analysis of the associations of CHX3 (X=I, Br, Cl) with aromatic (tetramethyl-p-phenylenediamine) and ...
Emmanuel Adeniyi, Olivia Grounds, Zachary Stephens, Matthias Zeller, Sergiy V. Rosokha   +4 more
doaj   +1 more source

Rational design of super-alkalis and their role in CO2 activation [PDF]

, 2017
Super-alkalis are clusters of atoms. With ionization potentials smaller than those of the alkali atoms, they are playing an increasing role in chemistry as highlighted by recent applications in solar cells as well as in Li-ion batteries.
Jena, Puru, Wang, Qian, Zhao, Tianshan
core   +3 more sources

Halogen-Bonded Photoresponsive Materials

, 2014
The aim of the present review is to illustrate to the reader the state of the art on the construction of supramolecular azobenzene-containing materials formed by halogen bonding. These materials include several examples of polymeric, liquid crystalline or crystalline species whose performances are either superior to the corresponding performances of ...
Saccone, Marco, Cavallo, Gabriella, Metrangolo, Pierangelo, Resnati, Giuseppe, Priimagi, Arri   +5 more
openaire   +7 more sources

Evidence for Interfacial Halogen Bonding

Angewandte Chemie International Edition, 2016
AbstractA homologous series of donor–π–acceptor dyes was synthesized, differing only in the identity of the halogen substituents about the triphenylamine (TPA; donor) portion of each molecule. Each Dye‐X (X=F, Cl, Br, and I) was immobilized on a TiO2 surface to investigate how the halogen substituents affect the reaction between the light‐induced ...
Wesley B, Swords, Sarah J C, Simon, Fraser G L, Parlane, Rebecca K, Dean, Cameron W, Kellett, Ke, Hu, Gerald J, Meyer, Curtis P, Berlinguette   +7 more
openaire   +4 more sources

Electrolyte Design Strategies for Static Shuttle‐Free and Long‐Life Aqueous Zinc‐Iodine Batteries

Advanced Functional Materials, EarlyView.
This review systematically summarizes recent advances in electrolyte design for static aqueous Zn‐I2 batteries, highlighting solvation regulation and interfacial engineering strategies to control reaction kinetics, suppress iodine shuttling, enhance energy density, and stabilize multi‐electron iodine redox chemistry for durable, high‐performance energy
Qianqin Zhou, Fan Zhang, Ting Liao, Ziqi Sun   +3 more
wiley   +1 more source

Anion Recognition by Neutral and Cationic Iodotriazole Halogen Bonding Scaffolds

Molecules, 2020
A computational study of the iodide discrimination by different neutral and cationic iodotriazole halogen bonding hosts was carried out by means of Density Functional Theory.
Iñigo Iribarren, Goar Sánchez-Sanz, Cristina Trujillo   +2 more
doaj   +1 more source