Results 51 to 60 of about 379,037 (236)

Exploring Orthogonality between Halogen and Hydrogen Bonding Involving Benzene

open access: yesMolecules, 2021
The concept of orthogonality between halogen and hydrogen bonding, brought out by Ho and coworkers some years ago, has become a widely accepted idea within the chemists’ community. While the original work was based on a common carbonyl oxygen as acceptor
Alessandra Forni   +4 more
doaj   +1 more source

Realizing Two-Dimensional Spin Arrays on Surfaces via Halogen-Bonding Molecular Self-Assembly [PDF]

open access: yes, 2021
Well-ordered spin arrays are highly desirable for next-generation molecule-based magnetic devices, and yet its synthetic method remains a challenging task.
Dingguan, Wang   +8 more
core   +2 more sources

Fluorination: A strategy to tune the interactions of molecules and nanoscale systems with biological matter

open access: yesFEBS Open Bio, EarlyView.
This minireview explores fluorination as a key strategy to optimize therapeutic molecules and nanocarriers. By incorporating different fluorinated motifs—from single atoms to linear and branched chains—drug delivery, cellular uptake, and colloidal stability can be improved and fine‐tuned.
Martina Beccalli   +2 more
wiley   +1 more source

Graded Metallopolymer Structures with Shape‐Memory Abilities via DLP‐Based 3D‐Printing

open access: yesAdvanced Functional Materials, EarlyView.
This study presents the digital light processing (DLP) based 3D printing of graded metallopolymers featuring shape‐memory abilities. The permanent shape can be recovered in two distinct steps with excellent rates. The obtained graded prints range from simple rod‐like structures to complex hollow materials.
Michael Klein   +6 more
wiley   +1 more source

Halogen Bonding beyond Crystals in Materials Science [PDF]

open access: yes, 2019
Halogen bonding has recently gained well deserved attention in present-day research for its importance in many fields of supramolecular science and crystal engineering.
Marco Saccone   +5 more
core   +1 more source

Nitride MXenes Beyond Carbides: Bridging the Gap Between Computational Prediction and Experimental Realization

open access: yesAdvanced Functional Materials, EarlyView.
Nitride MXenes remain constrained by a persistent gap between computational prediction and experimental realization. This Review identifies the thermodynamic, kinetic, and chemical barriers limiting their synthesis, critically evaluates emerging fabrication routes, and proposes a multidimensional computational‐experimental framework to accelerate the ...
Naresh Varnakavi, Masoud Soroush
wiley   +1 more source

Correction to Halogen-Bonding-Induced Hydrogen Transfer to CN Bond with Hantzsch Ester

open access: yes, 2019
Correction to Halogen-Bonding-Induced Hydrogen Transfer to CN Bond with Hantzsch ...
Choon-Hong Tan   +5 more
core   +1 more source

Lone‐Pair‐Induced Lattice Distortion in Lead‐Free Hybrid Perovskites for High‐Performance Nanogenerators

open access: yesAdvanced Functional Materials, EarlyView.
A lead‐free tin‐based hybrid perovskite is designed in which stereochemically active lone‐pair electrons on tin distort the crystal lattice and break its symmetry. Blended into a flexible polymer, the material converts pressure into electricity at milliwatt‐scale power density and continues working far below freezing, powering a commercial wristwatch ...
Majid Haji Bagheri   +12 more
wiley   +1 more source

Editorial: Advanced Research in Halogen Bonding

open access: yesCrystals, 2022
The Special Issue on “Advanced Research in Halogen Bonding” is a collection of 17 original articles reporting the results of theoretical and experimental studies that provide new insights into this fascinating intermolecular interaction [...]
Sergiy V. Rosokha, Atash V. Gurbanov
doaj   +1 more source

Halogen bonding between an Isoindoline Nitroxide and 1,4-Diiodotetrafluorobenzene: New tools and tectons for self-assembling organic spin systems

open access: yes, 2009
Radical assembly: Halogen bonding has been observed for the first time between an isoindoline nitroxide and an iodoperfluorocarbon (see figure), which cocrystallize to form a discrete 2:1 supramolecular compound in which NO.I halogen bonding is the ...
Aaron S. Micallef   +11 more
core   +1 more source

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