Results 211 to 220 of about 68,348 (275)

In Situ X-Ray Techniques Unraveling Charge Distribution Induced by Halogen Bonds in Solvates of an Iodo-Substituted Squaraine Dye. [PDF]

Adv Sci (Weinh)
Ye X, Gutenthaler-Tietze J, Wu R, Xia G, Xu S, Liu B, Chen YH, Karaghiosoff K.   +7 more
europepmc   +1 more source

Strength of the [Z-I···Hal]^- and [Z-Hal···I]^- Halogen Bonds: Electron Density Properties and Halogen Bond Length as Estimators of Interaction Energy. [PDF]

Molecules, 2021
Kuznetsov ML.
europepmc   +1 more source

Nickel‐Catalyzed Enantioconvergent Arylation of Unactivated Cyclic Electrophiles: Asymmetric Synthesis of 3‐Substituted Pyrrolidines

Angewandte Chemie, EarlyView.
Metal‐catalyzed enantioconvergent substitutions of unactivated cyclic electrophiles by organometallic nucleophiles have not previously been reported. Herein, a chiral nickel catalyst is described that achieves this objective, coupling 3‐iodopyrrolidine derivatives with arylzinc nucleophiles.
Ting Hei Matthew Wong, Xiaoyu Tong, Gregory C. Fu   +2 more
wiley   +2 more sources

Formation of Planar π-Conjugated Sheets in Cocrystals of Bis(iodoethynyl)pyridines and Bipyrimidylalkynes: Cooperative C-H···N Hydrogen Bonds and sp-C-I···N Halogen Bonds. [PDF]

Cryst Growth Des
Lang LB, Bowling NP, Bosch E.
europepmc   +1 more source

Comparison between Chlorine-Shared and π-Halogen Bonds Involving Substituted Phosphabenzene and ClF Molecules. [PDF]

ACS Omega, 2020
Sutradhar D, Bhattarai S, Parveen S, Chandra AK.   +3 more
europepmc   +1 more source

Photocatalytic Transfer Hydrogenation Using Plastic Hydrolysates as Hydrogen Donor

Angewandte Chemie, EarlyView.
Plastic waste is transformed into functional amines via solar‐driven transfer hydrogenation. Soluble monomers from acid hydrolysis of waste polymers serve as a hydrogen (electron/proton)donors in the selective reduction of nitroarenes using a visible light active photocatalyst consisting of cobalt promoted molybdenum disulfide integrated in cyanamide ...
Papa K. Kwarteng, Afreen H. Naceruddin, Erwin Reisner   +2 more
wiley   +2 more sources

Comparison of N···I and N···O Halogen Bonds in Organoiodine Cocrystals of Heterocyclic Aromatic Diazine Mono-N-oxides. [PDF]

Cryst Growth Des
Padgett CW, Dean R, Cobb A, Miller A, Goetz A, Bailey S, Hillis K, McMillen C, Toney S, Guillet GL, Lynch W, Pennington WT.   +11 more
europepmc   +1 more source

Halogen Bonds in Ligand-Protein Systems: Molecular Orbital Theory for Drug Design. [PDF]

J Chem Inf Model, 2020
Margiotta E, van der Lubbe SCC, de Azevedo Santos L, Paragi G, Moro S, Bickelhaupt FM, Fonseca Guerra C.   +6 more
europepmc   +1 more source

Sulfur‐Directed Construction of Vinyl Cyclopropanes from 1,3‐Dienes

Angewandte Chemie, EarlyView.
Sulfur takes control. A pending thioether acts as a molecular compass, directing carbene addition to the 1,3‐diene scaffold with exceptional regio‑ and diastereocontrol to forge sulfur‐substituted vinyl cyclopropanes (S‐VCPs) — molecular architectures inaccessible via conventional cyclopropanation strategies.
Anna Keimer, Jonas Rettig, Tim‐Niclas Streit, Bob Barthel, Mélissa Calmels, Moritz Malischewski, Franz‐Lucas Haut   +6 more
wiley   +2 more sources

Strategies Toward Accessing Enantioenriched (Hetero)Benzo‐Fused 5‐ and 6‐ Membered Rings via Intermolecular Carbometalation

Angewandte Chemie, EarlyView.
The use of transition‐metal catalysts and design of chiral ligands have allowed chemists to access highly functionalized benzofused 5‐ and 6‐ membered rings in high yield and enantioselectivity. A common strategy used relies on an intermolecular carbometalation across alkynes and olefins, usually followed by a subsequent intramolecular carbometalation.
Clara Jans, Armaan Grewal, Xavier Abel‐Snape, Mark Lautens   +3 more
wiley   +2 more sources