Cyclic diaryliodonium salts engage aryl Grignard reagents to trigger a self‐propagating aryne–arylation cycle. Transient cyclic triaryliodanes serve as aryne precursors and dynamic aryl reservoirs, delivering iodine‐capped teraryls with predominant meta‐selectivity. The preserved C─I bond enables outward π‐extension or inward recyclization.
Daichi Ikeshita +2 more
wiley +2 more sources
Alcohol‐Directed Carboamination of Conjugated Enynes
The first general three‐component intermolecular Pd‐catalyzed carboamination of conjugated enynes enables the coupling of anilines and aryl triflates to produce functionalized allenic amines, utilizing a native alcohol directing group to control regioselectivity.
Helena Solé‐Àvila +3 more
wiley +2 more sources
Charge Displacement Analysis-A Tool to Theoretically Characterize the Charge Transfer Contribution of Halogen Bonds. [PDF]
Ciancaleoni G, Nunzi F, Belpassi L.
europepmc +1 more source
Tris(diethyldithiocarbamato)(4-methoxyphenyl)tellurium(IV), \u3cem\u3ep\u3c/em\u3e-MeOC\u3csub\u3e6\u3c/sub\u3eH\u3csub\u3e4\u3c/sub\u3eTe(S\u3csub\u3e2\u3c/sub\u3eCNEt\u3csub\u3e2\u3c/sub\u3e)\u3csub\u3e3\u3c/sub\u3e, and the Triclinic Modification of Tris(diethyldithiocarbamato)phenyltellurium(IV), PhTe(S\u3csub\u3e2\u3c/sub\u3eCNEt\u3csub\u3e2\u3c/sub\u3e)\u3csub\u3e3\u3c/sub\u3e [PDF]
Husebye, Steinar, Lindeman, Sergey V.
core +1 more source
Hydrogen Bond Enhanced Halogen Bonds: A Synergistic Interaction in Chemistry and Biochemistry. [PDF]
Riel AMS +6 more
europepmc +1 more source
Halogen Bonds in 2,5-Dihalopyridine-Copper(I) Halide Coordination Polymers. [PDF]
von Essen C, Rissanen K, Puttreddy R.
europepmc +1 more source
The many flavours of halogen bonds - message from experimental electron density and Raman spectroscopy. [PDF]
Wang R +5 more
europepmc +1 more source
Exploring Halogen Bonds in 5-Hydroxytryptamine 2B Receptor-Ligand Interactions. [PDF]
Zhou Y +6 more
europepmc +1 more source
ABSTRACT Four benzothiophenes, thianaphthene (BT‐1), 3‐bromothianaphthene (BT‐2), benzo[b]thiophene‐2‐carboxaldehyde (BT‐3), and benzo[b]thiophene‐2‐carbonitrile (BT‐4), were tested as mild steel corrosion inhibitors in 1‐M HCl. The compounds have the similar benzothiophene core but differ in the substituents bound to the ring.
Nhlanhla G. Chirwa +3 more
wiley +1 more source
The impact of alloy fluctuations on the spin dynamics of mixed‐cation MAxFA1‐xPbI3 perovskite single crystals is studied experimentally by means of polarized time‐resolved photoluminescence. The high optical orientation degree, reaching 80% for x = 0.1 and 0.8, displays a minimum of 60% for x = 0.4.
Boris F. Gribakin +7 more
wiley +1 more source

