Results 111 to 120 of about 12,869 (241)

Palladium catalyzed ortho-halogenation of 2-arylbenzothiazole and 2,3-diarylquinoxaline

open access: yes, 2015
A palladium catalysed ortho-halogenation strategy has been developed using benzothiazoles and quinoxalines as the directing substrates. This method provides mono-o-halogenated product at the other available ortho site of a mono-ortho substituted 2 ...
Khatun, Nilufa   +4 more
core   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, Volume 138, Issue 37, 7 September 2026.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +2 more sources

Direct conversion of various phosphate sources to a versatile P-X reagent [TBA][PO2X2] via redox-neutral halogenation

open access: yesNature Communications
Inorganic phosphates hold significant potential as ideal natural building blocks, forming a fundamental basis for organic and biochemical synthesis.
Yaling Tian   +7 more
doaj   +1 more source

Novel Pyrazole‐4‐Carbaldehyde Derivatives Having Potent COX‐2 Inhibition and Anti‐Tubercular Activity: Microwave‐Assisted Green Synthesis and Molecular Docking

open access: yesJournal of Biochemical and Molecular Toxicology, Volume 40, Issue 10, October 2026.
ABSTRACT A series of 1‐(4‐Chorophenyl)‐3Aryl‐1‐H‐pyrazole‐4‐carbaldehyde derivatives were synthesized under the microwave irradiation (MW) technique. IR, 1H‐NMR, 13C‐NMR, and mass spectroscopic techniques were used to confirm the structure of the synthesized compounds.
Megha Kokane   +6 more
wiley   +1 more source

Rechargeable N ‐Halamine Functionalized Ultra‐Thin PES Ultrafiltration Membranes

open access: yesJournal of Polymer Science, Volume 64, Issue 18, Page 3986-4000, 15 September 2026.
An automated 3D printer‐assisted casting platform is utilized to fabricate ultra‐thin polyethersulfone membranes with precise structural control. The integration of a custom‐synthesized, regenerable N‐halamine homopolymer imparts superior, cyclic antifouling resistance and rapid, broad‐spectrum antibacterial efficacy.
Ahmet Aydın   +2 more
wiley   +1 more source

Anion Transfer Reactions from Chiral Hypervalent Iodine Macrocycles

open access: yesOrganics
The direct chlorination, bromination and azidation of beta keto esters, 2-acetyl-1-tetralone and methyl 1-oxo-2,3-dihydro-1H-indene-2-carboxylate is achieved utilizing anion-coordinated hypervalent iodine benziodazoles derived from hypervalent iodine ...
Mina Dumre Pandey   +5 more
doaj   +1 more source

Light on the sustainable preparation of aryl-cored dibromides

open access: yesBeilstein Journal of Organic Chemistry
Both aryl and benzyl polybromides have gained significant importance as reactive building blocks in polymer and materials chemistry. Their preparation primarily relies on established synthetic methods using molecular bromine or N-bromosuccinimide, known ...
Fabrizio Roncaglia   +5 more
doaj   +1 more source

Halogenation through Deoxygenation of Alcohols and Aldehydes

open access: yes, 2018
An efficient reagent system, Ph3P/XCH2CH2X (X = Cl, Br, or I), was very effective for the deoxygenative halogenation (including fluorination) of alcohols (including tertiary alcohols) and aldehydes. The easily available 1,2-dihaloethanes were used as key
Ji-Chang Xiao (1457842)   +2 more
core   +1 more source

Regioselective Halogenation of 1,4-Benzodiazepinones via CH Activation

open access: yes, 2015
International audienceThis article reports an efficient CH activation process for regioselective halogenation of 1,4-benzodiazepinones. Direct halogenation with NXS (X = Br, I) affords halogenated benzodiazepinones on the central aromatic ring whereas ...
Cintrat, Jean-Christophe   +1 more
core   +1 more source

Tuning of electronic, optical and lipophilic behaviours of adamantane through various substitutions

open access: yesMaterials Research Express
Successive tuning of electronic, optical and lipophilic characteristics of adamantane molecules are obtained by various halogen substitutions at bridgehead and bridge positions of adamantane.
Aravindhan R   +2 more
doaj   +1 more source

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