Results 121 to 130 of about 11,578 (241)
Quasi T‐shaped three‐way benzo[b]thiophene scaffolds, containing iodine atom(s) at the 4‐ and/or 7‐position, were prepared by several methods such as silica gel‐assisted cyclization. The iodobenzo[b]thiophenes thus prepared were subjected to Sonogashira cross couplings to give various ethynylbenzo[b]thiophenes.
Kozo Toyota +9 more
wiley +1 more source
Emerging MBenes for Energy Technologies
ABSTRACT The escalating global demand for sustainable energy is driving the search for transformative materials that transcend the limitations of conventional systems. Two‐dimensional (2D) transition metal borides (MBenes) have recently emerged as a compelling class, distinguished by unique electronic structures, tunable surface chemistry, and ...
Yingrui Ding +5 more
wiley +1 more source
Intermediates in halogenation of 2-amino-thiazoles
Halogenation of 2-amino-thiazoles in various solvents to 2-amino-5-halogenated-thiazoles is ...
MEDICI, Alessandro, L. FORLANI
core
Competition in atomic halogenation reactions
IT has been shown recently 1 that it is useful to consider a general mechanism for atomic halogenation reactions, which, in the case of the photochlorination of C 2Cl 4 and C 2HCl 5, is given by: © 1957 Nature Publishing Group.SCOPUS: le.jinfo:eu-repo ...
Vander Auwera, D. +5 more
core +1 more source
C4 Functionalization of the Isoquinoline Core via Oxidative Radical Substitution
The isoquinoline ring can be easily functionalized at C‐4 through a radical‐oxidative substitution process. The resulting products can be readily cyclized under basic conditions, facilitating the construction of pyranones fused to the isoquinoline scaffold. ABSTRACTIn this work, we report a straightforward synthetic procedure that enables the selective
Oscar Coral +2 more
wiley +1 more source
A practical SnCl4‐mediated Friedel–Crafts acylation of N‐tosylindoles provides regioselective access to diverse 3‐acylindoles with substrate scope across substituted indoles. The utility of this method is demonstrated in a concise total synthesis of the halogen‐rich marine natural product Breitfussin B.
Yu‐Tung Tsai +3 more
wiley +1 more source
Selective C–H halogenation over hydroxylation by non-heme iron(IV)-oxo
International audienceNon-heme iron based halogenase enzymes promote selective halogenation of the sp3-C–H bond through iron(IV)-oxo-halide active species.
CLEMANCEY, M +15 more
core +1 more source
Advances in the Different Synthetic Routes of Fluorinated Hydrazines
This review highlights the various routes to the preparation of fluorinated hydrazines, thereby promoting the exploration of innovative methods for the synthesis of new N‐fluorinated hydrazines. Their synthesis mainly involves synthetic routes such as organometallic, organocatalytic, and photocatalytic.
Dimitra Kyrko, Benoît Crousse
wiley +1 more source
Metal-free C5-selective halogenation of quinolines under aqueous conditions
An efficient and convenient method of C5-selective halogenation of quinoline derivatives was developed.
Aijun Lin +6 more
core +1 more source
N-halossacarinas: reagentes úteis (e alternativos) em síntese orgânica
N-halosaccharins proved to be useful and alternative reagents for diverse organic transformations, such as halogenation of aromatic compounds, benzylic and alpha-carbonylic positions, cohalogenation of alkenes, oxidation of secondary alcohols, etc. Their
Souza Soraia P. L. de +2 more
doaj

