Unveiling the molecular basis of selective fluorination of SAM-dependent fluorinases. [PDF]
Verma RK+6 more
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Divergent role of PIDA and PIFA in the AlX3 (X = Cl, Br) halogenation of 2-naphthol: a mechanistic study. [PDF]
Juárez-Ornelas KA+4 more
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Dual ligand-enabled iron and halogen-containing carboxylate-based photocatalysis for chloro/fluoro-polyhaloalkylation of alkenes. [PDF]
Han W+9 more
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200 Years of The Haloform Reaction: Methods and Applications. [PDF]
Rowett AC+5 more
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Benchmark Ab Initio Mapping of the F- + CH2ClI SN2 and Proton-Abstraction Reactions. [PDF]
Tasi DA, Orján EM, Czakó G.
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Revealing the nature of covalently tethered distonic radical anions in the generation of heteroatom-centered radicals: evidence for the polarity-matching PCET pathway. [PDF]
Fu K, Yang X, Yu Z, Song L, Shi L.
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The halogens are reactive elements that consist of diatomic molecules. All are oxidizing agents with fluorine being extremely strong. The elements are found in nature with salt, NaCl, being the most abundant compound of chlorine. Fluorine occurs in fluorite, CaF2, and other minerals. Bromine and iodine are found in seawater and as minor constituents in
James E. House, Kathleen A. House
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Halogen−Halogen Interactions in Halomethanes
The Journal of Organic Chemistry, 2002We report the study of the electronic structure of CHFI(2), CHBrI(2), CHBr(2)I, CHClI(2), and CHCl(2)I using VUV photoelectron spectroscopy (UPS). The lone pair orbital interactions are discussed on the basis of experimental results and comparisons with other halomethanes.
Novak, I.+4 more
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Halogen–halogen interactions and halogen bonding in thiacalixarene systems
CrystEngComm, 20145,11,17,23-tetraiodo-25,26,27,28-tetrapropoxythiacalix[4]arene exhibited I⋯I interactions which are ca. 2% shorter than the sum of their respective van der Waals atomic radii. 5,11,17,23-tetraiodo-25,26,27,28-tetrabutoxythiacalix[4]arene were identified to have S⋯I interactions that are ca.
Fumio Hamada+2 more
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