Results 171 to 180 of about 11,779 (265)

Tailoring Photochromism Beyond Human Eye Visibility: On/Off Switchable NIR Absorption in an Aluminosilicate

open access: yesAngewandte Chemie, EarlyView.
A new photochromic material was developed. Its on/off‐switchable absorption band is situated completely outside the human eye's visibility, in the near‐infrared (NIR) region, a feature never reported before. The photochromism mechanism in this aluminosilicate is elucidated by combining experimental as well as computational results, and the material's ...
Bettiina Muurinen   +15 more
wiley   +1 more source

Surface-ligand-triggered synthetic control of defects in nanocrystals toward high-efficiency blue electroluminescence. [PDF]

open access: yesInnovation (Camb)
Cao Q   +11 more
europepmc   +1 more source

One Molecular Platform, Three Distinct Narrowband Organoboron TADF Emitters: A Divergent One‐Pot Strategy From Green to Red

open access: yesAngewandte Chemie, EarlyView.
One platform–three emitters: Divergent one‐pot borylation of a single indolocarbazole platform exploits competing mono‐ and double‐borylation pathways to generate three spectrally distinct organoboron MR‐TADF emitters spanning green to red, enabling color‐tunable narrowband OLEDs with external quantum efficiencies over 30%.
Jun Hyeon Lee   +2 more
wiley   +1 more source

Supersolidophobic Pt catalyst for long-term natural seawater electrolysis with hydrogen production and magnesium extraction. [PDF]

open access: yesNat Commun
Yi L   +13 more
europepmc   +1 more source

Chlorine‐Free Depolymerization of Commercial PMMA via Oxygen‐Centered Radicals

open access: yesAngewandte Chemie, EarlyView.
A new chlorine‐free photothermal method enables sustainable recycling of plastics with C–C backbones under mild conditions. Driven by an oxygen‐centered radical pathway with ppm levels of anthraquinone catalyst, it eliminates hazardous chlorinated solvents, achieving an impressive 97% depolymerization conversion.
Chih‐Yin Lin   +5 more
wiley   +1 more source

London Dispersion Favors <i>Cis</i> Selectivity in the Johnson-Corey-Chaykovsky Epoxidation. [PDF]

open access: yesJ Org Chem
Domanski MHJ   +5 more
europepmc   +1 more source

N‐Alkoxysulfurdiimide Reagents for the One‐Step Modular Synthesis of Primary Sulfonimidamides

open access: yesAngewandte Chemie, EarlyView.
N‐Alkoxysulfurdiimide reagents when combined with organometallic reagents lead directly to primary sulfonimidamide products. The reactions are broad in scope, encompassing aryl, heteroaryl, and alkyl carbon substituents. The reactivity of the N‐alkoxysulfurdiimide reagents can be correlated with the electron‐withdrawing ability of the N‐substituent ...
Suzanne E. Davison   +6 more
wiley   +1 more source

Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons

open access: yesAngewandte Chemie, EarlyView.
1,2‐Aryl migration involving in situ‐generated alkyl iodine(III) species proceeds through a previously unrecognized 1,2‐C/I(III) dyotropic rearrangement. Migratory aryl fluorination, acetoxylation, and alkoxylation of 2‐alkyl‐2‐aryl‐3‐iodopropanoates provide α‐heterofunctionalized products, accompanied by aryl migration from the α‐ to the β‐position ...
Chen‐Xu Liu   +3 more
wiley   +1 more source

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