Results 181 to 190 of about 11,779 (265)

Disentangled autoencoding equivariant diffusion model for controlled generation of 3D molecules. [PDF]

Nat Commun
Li T, Liu H, Guo H, Gerstein M, Min MR.
europepmc   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

Angewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +1 more source

Water‐Dispersible Ruthenium Nanocatalyst for Carbonyl Reduction With D2 or T2 in Aqueous Media

Angewandte Chemie, EarlyView.
We report the synthesis and characterization of water‐dispersible ruthenium nanoparticles that catalyze the reductive deuteration and tritiation of carbonyl compounds in aqueous media, enabling efficient access to a broad range of isotopically labeled polar molecules, including cyclic peptides, antibody‐drug conjugate linkers, pegylated derivatives ...
Elisa Martinelli, Rafael Jiménez Rioboo, Remo Weck, Sophie Feuillastre, Luis M. Martínez‐Prieto, Grégory Pieters, Volker Derdau   +6 more
wiley   +1 more source

A Tiered Multi-Technique Decision-Support Framework for Contaminant Screening and Recycling-Route Assignment of Mixed Plastic Waste. [PDF]

Polymers (Basel)
Chen A, Saxena S, Samaras VG, Dally B.
europepmc   +1 more source

A Modular Synthesis of C5‐Sulfenyl Thiazoles via an Intermolecular Pummerer Rearrangement: An Underexplored Scaffold for Medicinal Chemistry

Angewandte Chemie, EarlyView.
Modular access to underexplored C5‐sulfenyl thiazoles via an intermolecular Pummerer rearrangement is reported. The methodology exhibits a broad functional group tolerance enabling the seamless design of trisubstituted thiazole cores bearing a sulfur handle for further elaboration.
Joe L. Smy, Theo C. Webb, Barnaby W. Greenland, S. Mark Roe, John Spencer, Storm Hassell‐Hart   +5 more
wiley   +1 more source

Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables Remote‐Markovnikov Hydroamination of Alkenes

Angewandte Chemie, EarlyView.
A cobalt‐catalyzed remote‐Markovnikov 1,3‐hydroamination of allyl carboxylates proceeds through MHAT, 1,2‐radical acyloxy migration (1,2‐RAM), and radical ligand transfer (RLT) from a Co‐N intermediate, providing protected amino alcohols. ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet ...
Arman Khosravi, Ho Martin Yuen, Seth Fremin, Nuwan A. Pannilawithana, Nol Supasueb, Yu Zhang, Peng Liu, Ming‐Yu Ngai   +7 more
wiley   +1 more source

Enantioselective α,α-Chlorofluorination of Sulfoxonium Ylides. [PDF]

Org Lett
Furniel LG, Capellaro KC, Câmara VS, Hayashi M, Echemendía R, Pinto CB, Salata ABAM, Filho JAL, Hantao LW, Ellena J, Burtoloso ACB.   +10 more
europepmc   +1 more source

Interaction Hierarchy and Polymorphic Structure–Property Dynamics in Luminescent Molecular Crystals

Angewandte Chemie, EarlyView.
Competing homotypic and heterotypic intermolecular interactions give rise to polymorphic structure–property dynamics in luminescent molecular crystals. Thermal and mechanical stimuli induce distinct phase‐transition pathways accompanied by pronounced photoluminescence changes.
Mahiro Nakabayashi, Shotaro Hayashi
wiley   +1 more source

Unveiling Clusterization-Triggered Emission Mechanism Through a Small-Molecule Clusteroluminogen with Color Tunable and White-Light Emission. [PDF]

J Phys Chem C Nanomater Interfaces
Abid K, Pillet S, Samet A, Abid Y.
europepmc   +1 more source

Adaptive Hydrogenation of Alkynes Using CO as a Molecular Trigger to Selectively Produce Alkanes or Z‐Alkenes

Angewandte Chemie, EarlyView.
One catalyst for two products: CO acts as a molecular trigger for adaptive alkyne hydrogenation using supported Pd nanoparticles. The catalyst reversibly switches between the formation of alkanes under H2 and Z‐alkenes under H2/CO for 37 structurally diverse alkynes.
Manisha Durai, Lachlan Sharp‐Bucknall, Tim Alexander Schubert, Jacob Johny, John‐Tommes Krzeslack, Walid Hetaba, Walter Leitner, Alexis Bordet   +7 more
wiley   +1 more source