Results 251 to 260 of about 66,822 (374)

Synthesis of Polysubstituted Naphthalenes via Metal‐Free Borylative Cyclization of o‐Alkynylstyrenes

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract A selective, metal‐free method for the synthesis of boron‐functionalized polysubstituted naphthalenes via BCl3‐mediated cyclization of α‐substituted o‐alkynylstyrenes is described. The reaction exhibits broad substrate scope, tolerating various groups such as ethers, sulfides and halogens, and delivers high yields under mild conditions, even ...
Marcos Humanes   +2 more
wiley   +1 more source

Regio‐, Stereoselective, Aerobic and Metal‐Free Synthesis of Z‐Vinyl Sulfides: One‐Pot Hydroiodination of Internal Alkynes and in situ Sulfenylations

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract A novel, metal‐free, air‐ and moisture‐compatible one‐pot tandem protocol for the regio‐ and stereoselective synthesis of Z‐vinyl sulfides (achieving yields up to 99%), is reported. This straightforward and efficient process combines the selective hydroiodination of internal alkynes, promoted by the eutectic mixture choline iodide (ChI)/p‐TsOH
Gloria Morís‐Menéndez   +5 more
wiley   +1 more source

Synthesis and conformational analysis of pyran inter-halide analogues of ᴅ-talose. [PDF]

open access: yesBeilstein J Org Chem
Lessard O   +3 more
europepmc   +1 more source

Sustainable Flame‐Retardant Poly Lactic Acid Biocomposites Reinforced with Polyphosphate‐Enriched Microalgae: Unlocking the Potential of Hyper‐Compensation

open access: yesAdvanced Sustainable Systems, EarlyView.
This study explores microalgae cultivation for wastewater treatment and enhancement of poly lactic acid (PLA)‐based biocomposites. It achieves up to 99.9% nutrient removal, increases biomass productivity by 322%, and demonstrates a triphasic luxury phosphorus uptake system. Incorporation into PLA improves fire‐retardant properties, suggesting potential
Rohit Dey   +9 more
wiley   +1 more source

Key role of short-lived halogens on global atmospheric oxidation during historical periods.

open access: yesEnviron Sci Atmos
Bossolasco A   +10 more
europepmc   +1 more source

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