Results 21 to 30 of about 17,342 (289)
Intramolecular halogen–halogen bonds?
Physical Chemistry Chemical Physics, 2013 By analysing the properties of the electron density in the structurally simple perhalogenated ethanes, X3C-CY3 (X, Y = F, Cl), a previously overlooked non-covalent attraction between halogens attached to opposite carbon atoms is found. Quantum chemical calculations extrapolated towards the full solution of the Schrödinger equation reveal the complex ...
Johansson, Mikael P., Swart, Marcel
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Molecules, 2020 New D-π-A configured organic sensitizers featuring halogen-substituted oxindole-bridged acceptor units have been synthesized for dye-sensitized solar cells applications.
Yogesh S. Tingare +5 more
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Volcanica, 2019 We investigate sulphur, chlorine and fluorine release during explosive, effusive and intrusive phases the 2011 Cordón Caulle eruption, with a focus on halogen devolatilization. Petrological analysis shows halogen release to have been promoted by isobaric
C Ian Schipper +8 more
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Halogens in the atmosphere [PDF]
, 1981 Extant data from measurements of halogens in the atmosphere are reviewed in the following categories: gaseous chlorine compounds (inorganic and organic), particulate chloride and chloride in precipitation, gaseous bromine compounds (inorganic and organic)
Cicerone, Ralph J, Ralph J. Cicerone
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Effects of halogens on European air-quality. [PDF]
, 2017 Halogens (Cl, Br) have a profound influence on stratospheric ozone (O3). They (Cl, Br and I) have recently also been shown to impact the troposphere, notably by reducing the mixing ratios of O3 and OH.
P. S. Monks (7603757) +12 more
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Chemical Reviews, 2016 The halogen bond occurs when there is evidence of a net attractive interaction between an electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic region in another, or the same, molecular entity. In this fairly extensive review, after a brief history of the interaction, we will provide the reader with a snapshot of ...
Cavallo, Gabriella +7 more
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Application of Satellite‐Based Detections of Arctic Bromine Explosion Events Within GEOS‐Chem
Journal of Advances in Modeling Earth Systems, 2023 During polar spring, periods of elevated tropospheric bromine drive near complete removal of surface ozone. These events impact the tropospheric oxidative capacity and are an area of active research with multiple approaches for representing the ...
P. A. Wales +9 more
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Halogen⋯halogen contra C–H⋯halogen interactions
CrystEngComm, 2014 Pressure affects the competition between C–H⋯X hydrogen bonds and X⋯X halogen⋯halogen interactions. In bromomethane, CH3Br, pressure changes the molecular arrangement of the two solid-state phases of this compound: low-pressure phase α is dominated by halogen⋯halogen interactions, whereas above 1.5 GPa the β phase is governed by C–H⋯halogen bonds.
Marcin Podsiadło +2 more
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Atmosphere, 2020 In this paper, we compare model calculations of ozone profiles and their variability for the period 1998 to 2016 with satellite and lidar profiles at five ground-based stations.
Kostas Eleftheratos +15 more
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Natural halogens buffer tropospheric ozone in a changing climate [PDF]
, 2020 Reactive atmospheric halogens destroy tropospheric ozone (O3), an air pollutant and greenhouse gas. The primary source of natural halogens is emissions from marine phytoplankton and algae, as well as abiotic sources from ocean and tropospheric chemistry,
Kinnison, Douglas E. +27 more
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