Results 41 to 50 of about 1,896 (172)

Titanium‐Catalyzed Diastereoselective Keto‐ and Iminonitrile Cyclizations

Chemistry – A European Journal, EarlyView.
The titanium(III)‐catalyzed diastereoselective cyclization of readily‐available substituted ketonitriles gives cyclopentanones in good yield and stereoselectivity. Subsequent 1,2‐addition allows the preparation of cyclopentyls with three consecutive stereocenters.
Christoph Kern, Ritu Singh, Michael A. Unkrig‐Bau, Lukas Jakob, Jan Streuff   +4 more
wiley   +1 more source

Cross‐Dehydrogenative Coupling Reactions With Redox‐Active Guanidine Reagents

Chemistry – A European Journal, EarlyView.
ABSTRACT Cross‐dehydrogenative coupling (CDC) reactions are attractive and environmentally friendly ways to form new C‐C and other element‐element bonds. Here, we report the first CDC reactions triggered by a redox‐active guanidine reagent. N‐phenyltetrahydroisoquinoline and derivatives with electron‐donating and withdrawing substituents at the N ...
Petra Walter, Olaf Hübner, Hans‐Jörg Himmel   +2 more
wiley   +1 more source

Modular One‐Pot Access to π‐Expanded Tetrakis(Phenothiazinyl)‐Silanes With Broadly Tunable Redox and Emission Properties

Chemistry – A European Journal, EarlyView.
A library of 21 tetrakis(phenothiazinyl)‐substituted silanes with broadly variable substituent decoration, which are fully reversible multistage redox systems with intense tunable emission from deep blue to yellow–green (441–533 nm), was rapidly synthesized by bromine–lithium exchange/borylation–Suzuki coupling of tetrakis(4‐bromophenyl)silane or by ...
Thomas P. M. Merke, Lysander Presser, Leonard Karl, Christian Ganter, Thomas J. J. Müller   +4 more
wiley   +1 more source

Introduction of the Difluoro(methoxy)methyl Group into the Aromatic Ring and the Study of Its Electronic Properties

Журнал органічної та фармацевтичної хімії
A simple and efficient method for synthesizing aromatic compounds with a difluoro(methoxy)methyl fragment (CF2OCH3) by the fluorodesulfurization of thionoesters has been developed.
Mykhailo O. Pashko, Yurii L. Yagupolskii
doaj   +1 more source

Linear and Two‐Dimensional Infrared Spectroscopy of the Multifunctional Vibrational Probe, 3‐(4‐Azidophenyl) Propiolonitrile. Deperturbing a Fermi Triad by Isotopic Substitution

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Linear infrared spectroscopy combined with isotope labeling and density functional theory unravels the origin of a Fermi triad in a multifunctional vibrational chromophore. Ultrafast 2DIR‐spectroscopy reports directly on the dynamics and the intramolecular vibrational energy flow pathways in the isotopically deperturbed system. Abstract Infrared probes
Claudia Gräve, Jörg Lindner, Stefan Flesch, Luis I. Domenianni, Peter Vöhringer   +4 more
wiley   +1 more source

Computational design of poly(p‐phenylene vinylene)‐based gas sensors: tunable reactivity and selectivity via side‐group functionalization

Polymer International, EarlyView.
Side‐group functionalization enhances the reactivity and optoelectronic properties of poly(p‐phenylene vinylene) (PPV) derivatives for chemical sensing. PPV‐CN and PPV‐NO2 display strong interactions and pronounced responses, providing molecular‐level insights for designing high‐performance polymer‐based sensors.
Bruno Hori Barboza, Rosangela A Maia, João Paulo Cachaneski‐Lopes, Augusto Batagin‐Neto   +3 more
wiley   +1 more source

A modification of the Hammett equation for predicting ionisation constants of p-vinyl phenols

European Journal of Pharmaceutical Sciences, 2005
Currently there are several compounds used as drugs or studied as new chemical entities, which have an electron withdrawing group connected to a vinylic double bond in a phenolic or catecholic core structure. These compounds share a common feature--current computational methods utilizing the Hammett type equation for the prediction of ionisation ...
Julius, Sipilä, Harri, Nurmi, Ann Marie, Kaukonen, Jouni, Hirvonen, Jyrki, Taskinen, Jari, Yli-Kauhaluoma   +5 more
openaire   +2 more sources

Outer‐Sphere Tuning of Synthetic Iron–Sulfur Clusters Within Nanoscale Cage Frameworks

Small, EarlyView.
Noncovalent encapsulation of a synthetic iron–sulfur cluster within hydrophobic, naphthalenediimide (NDI)‐paneled cages is shown to lead to dramatic changes in the electronic structure and covalency of the Fe─S core. ABSTRACT As atomic‐scale archetypes for multi‐electron transfer, iron–sulfur clusters are compelling candidates for the design of redox ...
Rupal Baliyan, Shelby T. Davis, Jan‐Niklas Boyn, Gwendolyn A. Bailey   +3 more
wiley   +1 more source

Determination of acid dissociation constants of some hydroxy schiff bases by pH-metric titration. application of the Hammett equation

MATEC Web of Conferences, 2013
Ten compounds hydroxybases Schiff were synthesized from salicylaldehyde and the substituted aniline in the ortho, meta and para methyl groups, chloro and nitro.
Hadjeb R., Bara A., Barkat D.
doaj   +1 more source

1177. Streptocarpus aylae T.J.Edwards

Curtis's Botanical Magazine, EarlyView.
Summary Streptocarpus aylae T.J.Edwards, a spectacular, rosette forming herbaceous perennial from cliffs of the Msikaba River in Pondoland, Eastern Cape Province, South Africa is illustrated and discussed. The species is known from only two sites and is highly localised, growing in humus rich cracks and crevices on sandstone cliffs.
Paul Rees, Adam Harrower, Ernst J. Van Jaarsveld, Thomas E.M. Pickering, Carel J. Fourie, Dirk U. Bellstedt, Christabel King   +6 more
wiley   +1 more source