On the Roles of Protic Solvents in Imidazolidinone‐Catalyzed Transformations
Angewandte Chemie International Edition, 2011 Step by step: The effect of protic solvents on the rate and stereochemical outcome of the imidazolidinone-catalyzed Diels–Alder cycloaddition was rationalized. The following picture emerges: the solvent accelerates iminium ion formation (step 1), the Diels–Alder cycloaddition is reversible (step 2), and the solvent intercepts the iminium ion adduct ...
Brazier, John B. +3 more
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FA Polymerization Disruption by Protic Polar Solvents [PDF]
Polymers, 2018 Furfuryl alcohol (FA) is a biobased monomer derived from lignocellulosic biomass. The present work describes its polymerization in the presence of protic polar solvents, i.e., water or isopropyl alcohol (IPA), using maleic anhydride (MA) as an acidic initiator.
Falco, Guillaume +3 more
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Solvatochromic effects on the fluorescence and triplet–triplet absorption of phenosafranine in protic and aprotic solvents [PDF]
Journal of Photochemistry and Photobiology A: Chemistry, 2006 Photophysical and spectroscopic properties of phenosafranine were investigated in 21 solvents, including pure aprotic solvents and pure and binary protic solvent mixtures.
Sonia G Bertolotti +2 more
exaly +2 more sources
Characterization and Reactivity of Triperoxo Vanadium Complexes In Protic Solvents
European Journal of Inorganic Chemistry, 2001 ESI-MS and 51V NMR techniques have been used to detect the formation of vanadium triperoxo complexes in protic solvents. RHF/6-311++G(d,p) ab initio calculations were also carried out to address the structure and the energy requirements of vanadium peroxo species formed from vanadates and hydrogen peroxide.
M. Bonchio +3 more
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Dynamical behavior of the azide ion in protic solvents
Chemical Physics Letters, 1993 Abstract Molecular dynamics calculations based on rigid molecules have been used to study the solvation structure and dynamics of an azide ion in methanol and water. The ion is found to have either five to six methanols or six to seven waters in its solvation cage.
FERRARIO, Mauro +2 more
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Structure–property relationships in protic ionic liquids: a study of solvent–solvent and solvent–solute interactions [PDF]
Phys. Chem. Chem. Phys., 2017 Ionicity of protic ionic liquids are significantly affected by additional functionality, thereby influencing solvation properties.
Joshua E. S. J. Reid +6 more
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Protic Ionic Liquids: Solvents with Tunable Phase Behavior and Physicochemical Properties
, 2016 The phase behavior, including glass, devitrification, solid crystal melting, and liquid boiling transitions, and physicochemical properties, including density, refractive index, viscosity, conductivity, and air−liquid surface tension, of a series of 25 ...
Irena Krodkiewska (2223880) +4 more
core +2 more sources
Etching and coating mechanisms evaluation of gold nanoparticles-coated surface plasmon resonance sensors in protic solvents [PDF]
, 2022 In recent years, the demand for high-quality sensors for various industrial, medical and environmental applications has been exponentially growing.
Elshikeri, Nada Badreldin Ibrhim
core
, 2021 The polarizable CL&Pol force field presented in our previous study, Transferable, Polarizable Force Field for Ionic Liquids (J. Chem. Theory Comput. 2019, 15, 5858, DOI: 10.1021/acs.jctc.9b00689), is extended to electrolytes, protic ionic liquids, deep ...
Agilio, Padua +3 more
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Functionalized Oxatriquinanes and Their Structural Equilibrium in Protic Solvent
Chemical and Pharmaceutical Bulletin, 2014 We synthesized oxatriquinane hexafluorophosphate bearing an ethoxycarbonylmethyl group 7 or a 2-oxopropyl group 11. Both of these organic oxonium cation compounds were obtained as stable solids. However, (1)H-NMR analysis showed that oxatriquinane 7 was present as the oxonium cation in aprotic solvent CD₃CN, but was in rapid equilibrium with ring ...
Suzuki, Hideyuki, Muratake, Hideaki
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