Investigations of the reactivity of pyridine carboxylic acids with diazodiphenylmethane in protic and aprotic solvents. [PDF]
Rate constants for the reaction of diazodiphenylmethane with isomeric pyridine carboxylic acids were determined in chosen protic and aprotic solvents at 30 °C, using the well known UV spectrophotometric method.
ALEKSANDAR D. MARINKOVIC +3 more
doaj +1 more source
A Mechanical Planar Chiral Rotaxane Induces Single-Handed Helicity in a Twisted Perylene Diimide. [PDF]
A mechanical planar chiral rotaxane (Rmp) is used to induce single‐handed helical chirality (M) in a perylene diimide chromophore, resulting in persistent circular dichroism (CD) and circularly polarised luminescence (CPL). ABSTRACT The twisting of chromophores such as perylene diimides (PDIs) into helical structures affords chiroptical properties from
Lawson TE +5 more
europepmc +3 more sources
The Role of Solvent on the Kinetics and Mechanism of the Hydrolysis of Salicylidene Benzoyl Hydrazone [PDF]
The effect of various solvents on the kinetics and mechanism of the hydrolysis of Salicylidene Benzoyl hydrazone (SBH) has been studied at five different temperatures (17-45 C) using U.V. and visible spectrophotometry. In both protic and aprotic solvents,
Maher Abu-Eid
doaj +1 more source
A series of poly(pyridinium salt)s-fluorene main-chain ionic polymers with various organic counterions were synthesized by using ring-transmutation polymerization and metathesis reactions. Their chemical structures were characterized by Fourier Transform
Pradip K. Bhowmik +8 more
doaj +1 more source
Structure–property relationships in protic ionic liquids: a study of solvent–solvent and solvent–solute interactions [PDF]
Ionicity of protic ionic liquids are significantly affected by additional functionality, thereby influencing solvation properties.
Joshua E. S. J. Reid +6 more
openaire +5 more sources
Extension of the CL&Pol Polarizable Force Field to Electrolytes, Protic Ionic Liquids and Deep Eutectic Solvents [PDF]
The polarizable CL&Pol force field presented in our previous study, Transferable, Polarizable Force Field for Ionic Liquids (J. Chem. Theory Comput. 2019, 15, 5858, DOI: 10.1021/acs.jctc.9b00689), is extended to electrolytes, protic ionic liquids, deep ...
Agilio, Padua +3 more
core +1 more source
In this paper, we investigate the solvatochromatic behaviors of fluorenone and benzofluorenone derivatives in both protic and aprotic solvents. While the effects of aprotic solvents on these dyes have been extensively studied in silico, little has been ...
Colley, Kiser Z., Dunn, Timothy
core +1 more source
Theoretical Investigation of Solvation Effects on the Tautomerism of Maleic Hydrazide
A DFT study is used to calculate structural data of tautomers of maleic hydrazide (MH) in the gas phase and selected solvents such as benzene (non-polar solvent), tetrahydrofuran (polar aprotic solvent) and methanol (protic solvent), dimethyl sulfoxide ...
Meisam Shabanian +3 more
doaj +1 more source
The synthesis of new 6-Bromoquinolin-4-ol derivatives (3a–3h) by Chan–Lam coupling utilizing different types of solvents (protic, aprotic, and mixed solvents) and bases was studied in the present manuscript.
Mahwish Arshad +4 more
doaj +1 more source
Protic Ionic Liquids: Solvents with Tunable Phase Behavior and Physicochemical Properties
The phase behavior, including glass, devitrification, solid crystal melting, and liquid boiling transitions, and physicochemical properties, including density, refractive index, viscosity, conductivity, and air−liquid surface tension, of a series of 25 ...
Irena Krodkiewska (2223880) +4 more
core +2 more sources

