Investigations of the reactivity of pyridine carboxylic acids with diazodiphenylmethane in protic and aprotic solvents. [PDF]
Rate constants for the reaction of diazodiphenylmethane with isomeric pyridine carboxylic acids were determined in chosen protic and aprotic solvents at 30 °C, using the well known UV spectrophotometric method.
ALEKSANDAR D. MARINKOVIC +3 more
doaj +2 more sources
Protic Ionic Liquids: Solvents with Tunable Phase Behavior and Physicochemical Properties [PDF]
The phase behavior, including glass, devitrification, solid crystal melting, and liquid boiling transitions, and physicochemical properties, including density, refractive index, viscosity, conductivity, and air−liquid surface tension, of a series of 25 ...
Irena Krodkiewska (2223880) +4 more
core +3 more sources
Extension of the CL&Pol Polarizable Force Field to Electrolytes, Protic Ionic Liquids and Deep Eutectic Solvents [PDF]
The polarizable CL&Pol force field presented in our previous study, Transferable, Polarizable Force Field for Ionic Liquids (J. Chem. Theory Comput. 2019, 15, 5858, DOI: 10.1021/acs.jctc.9b00689), is extended to electrolytes, protic ionic liquids, deep ...
Agilio, Padua +3 more
core +1 more source
The Role of Solvent on the Kinetics and Mechanism of the Hydrolysis of Salicylidene Benzoyl Hydrazone [PDF]
The effect of various solvents on the kinetics and mechanism of the hydrolysis of Salicylidene Benzoyl hydrazone (SBH) has been studied at five different temperatures (17-45 C) using U.V. and visible spectrophotometry. In both protic and aprotic solvents,
Maher Abu-Eid
doaj +1 more source
Hydrogen-Bonded Encapsulation Complexes in Protic Solvents [PDF]
We describe here the behavior of the hydrogen-bonded capsule 1·1 and its complexes in protic solvents. The kinetics and thermodynamics of the encapsulation process were determined through conventional 1H NMR methods.
Toru Amaya (1552171) +1 more
core +1 more source
Unprecedented high fluorescence anisotropy in protic solvents: hydrogen bond induced solvent caging? [PDF]
Atypical high fluorescence anisotropy has been revealed in protic solvents for excited state intramolecular proton transfer (ESIPT) prone 3-hydroxyflavone and some of its hydroxy derivatives. In non-protic solvents, however, the anisotropy values are low.
Das, Sinjan +2 more
core +1 more source
Towards Understanding the Solvatochromatic Behavior of Fluorenone and Benzofluorenone Derivatives in Protic Solvents [PDF]
In this paper, we investigate the solvatochromatic behaviors of fluorenone and benzofluorenone derivatives in both protic and aprotic solvents. While the effects of aprotic solvents on these dyes have been extensively studied in silico, little has been ...
Colley, Kiser Z., Dunn, Timothy
core
A series of poly(pyridinium salt)s-fluorene main-chain ionic polymers with various organic counterions were synthesized by using ring-transmutation polymerization and metathesis reactions. Their chemical structures were characterized by Fourier Transform
Pradip K. Bhowmik +8 more
doaj +1 more source
Structure–property relationships in protic ionic liquids: a study of solvent–solvent and solvent–solute interactions [PDF]
Ionicity of protic ionic liquids are significantly affected by additional functionality, thereby influencing solvation properties.
Joshua E. S. J. Reid +6 more
openaire +5 more sources
Optical basicity scales in protic solvents: water, hydrogen fluoride, ammonia and their mixtures. [PDF]
In an inorganic material, a measure of the Lewis basicity of a solvent is commonly provided by the optical basicity, i.e. the ability of the solvent molecules to donate their electrons to an acidic species.
Christian Simon +5 more
core +1 more source

