Nucleofugality and Nucleophilicity of Fluoride in Protic Solvents [PDF]
, 2016 A series of p-substituted benzhydryl fluorides (diarylfluoromethanes) were prepared and subjected to solvolysis reactions, which were followed conductometrically.
Johannes Ammer (1353501) +2 more
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Chemosensors, 2022 Twisting intramolecular charge transfer (TICT) is a common nonradiative relaxation pathway for a molecule with a flexible substituent, effectively reducing the fluorescence quantum yield (FQY) by swift twisting motions.
Jiawei Liu, Cheng Chen, Chong Fang
doaj +1 more source
Functionalized Oxatriquinanes and Their Structural Equilibrium in Protic Solvent
Chemical and Pharmaceutical Bulletin, 2014 We synthesized oxatriquinane hexafluorophosphate bearing an ethoxycarbonylmethyl group 7 or a 2-oxopropyl group 11. Both of these organic oxonium cation compounds were obtained as stable solids. However, (1)H-NMR analysis showed that oxatriquinane 7 was present as the oxonium cation in aprotic solvent CD₃CN, but was in rapid equilibrium with ring ...
Suzuki, Hideyuki, Muratake, Hideaki
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Journal of Natural Fibers, 2022 Cellulose swelling using different protic, aprotic and alkaline solvents, which are capable of penetrating crystalline parts of cellulose is one of the important methods to enhance the accessibility and, as a result, the reactivity of cellulose in ...
Fereshteh Fadavi +3 more
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Dissociation constants of some substituted cinnamic acids in protic solvents: measurements by hyper-Rayleigh scattering and potentiometric techniques [PDF]
, 1996 Recently, we have demonstrated [J. Phys. Chem. 99 (1995) 17891] that dissociation constants of weak organic acids in protic solvents can be measured by the recently revived hyper-Rayleigh scattering technique.
Munichandraiah, N. +2 more
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Assisted dipeptide bond formation: glycine as a case study
Heliyon, 2021 Peptide bond formation is a crucial chemical process that dominates most biological mechanisms and is claimed to be a governing factor in the origin of life.
Sofiene Achour +3 more
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Ultrafast Excited-State Dynamics of Hydrogen-Bonded Cytosine Microsolvated Clusters with Protic and Aprotic Polar Solvents [PDF]
, 2018 Microsolvation effects on the ultrafast excited-state deactivation dynamics of cytosine (Cy) were studied in hydrogen-bonded Cy clusters with protic and aprotic solvents using mass-resolved femtosecond pump–probe ionization spectroscopy.
Hung-Chien Yen +17 more
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Journal of Saudi Chemical Society, 2019 Solubility of active pharmaceutical ingredient (API) in solvents is very important for drug development and manufacturing. Solubility data may provide further information such as thermochemical properties and intermolecular interactions that may lead to ...
S. Hassan +3 more
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Utilization of the dye N-methyl-6-oxyquinolone as an optical acidometer in molecular solvents and protic ionic liquids [PDF]
, 2017 We developed a procedure to use the highly sensitive dyeN-methyl-6-oxyquinolone as an acidity probe in molecular solvents and protic ionic liquids.
Stella Schmode, Ralf Ludwig
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Dissociation constants of weak organic acids in protic solvents obtained from their first hyperpolarizabilities in solution [PDF]
, 1995 The first hyperpolarizabilities (beta) of some weak aromatic organic acids have been measured in protic solvents by the hyper-Rayleigh scattering (HRS) technique at low concentrations.
Ray, Paresh Chandra, Das, Puspendu Kumar
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