Results 31 to 40 of about 209,291 (274)

1,2-bis-(ditertbutylphosphinomethyl)benzene in catalysis [PDF]

open access: yes, 2012
Different diphosphine ligands having the structure shown below have been studied for carbonylation and hydroformylation reactions. Depending on the substituent on the phosphorus atoms the electronic and steric properties can be tuned to direct the ...
Jiménez, Cristina
core   +2 more sources

Influence of Swelling Media on the Crystallinity and Accessibility of Lyocell Fibers: An FTIR and 13C NMR Analysis

open access: yesJournal of Natural Fibers, 2022
Cellulose swelling using different protic, aprotic and alkaline solvents, which are capable of penetrating crystalline parts of cellulose is one of the important methods to enhance the accessibility and, as a result, the reactivity of cellulose in ...
Fereshteh Fadavi   +3 more
doaj   +1 more source

Hydrogen-Bonded Encapsulation Complexes in Protic Solvents

open access: yes, 2016
We describe here the behavior of the hydrogen-bonded capsule 1·1 and its complexes in protic solvents. The kinetics and thermodynamics of the encapsulation process were determined through conventional 1H NMR methods.
Toru Amaya (1552171)   +1 more
core   +1 more source

Etching and coating mechanisms evaluation of gold nanoparticles-coated surface plasmon resonance sensors in protic solvents [PDF]

open access: yes, 2022
In recent years, the demand for high-quality sensors for various industrial, medical and environmental applications has been exponentially growing.
Elshikeri, Nada Badreldin Ibrhim
core  

Unprecedented high fluorescence anisotropy in protic solvents: hydrogen bond induced solvent caging?

open access: yes, 2016
Atypical high fluorescence anisotropy has been revealed in protic solvents for excited state intramolecular proton transfer (ESIPT) prone 3-hydroxyflavone and some of its hydroxy derivatives. In non-protic solvents, however, the anisotropy values are low.
Das, Sinjan   +2 more
core   +1 more source

Assisted dipeptide bond formation: glycine as a case study

open access: yesHeliyon, 2021
Peptide bond formation is a crucial chemical process that dominates most biological mechanisms and is claimed to be a governing factor in the origin of life.
Sofiene Achour   +3 more
doaj   +1 more source

Evaluation of solvents’ effect on solubility, intermolecular interaction energies and habit of ascorbic acid crystals

open access: yesJournal of Saudi Chemical Society, 2019
Solubility of active pharmaceutical ingredient (API) in solvents is very important for drug development and manufacturing. Solubility data may provide further information such as thermochemical properties and intermolecular interactions that may lead to ...
S. Hassan   +3 more
doaj   +1 more source

Epimerization of ergot alkaloids in feed

open access: yesHeliyon, 2020
Chronic intake of cereals contaminated with ergot alkaloids can cause ergotism and result in the loss of toes and fingers or even death. Today, due to common risk management practices, ergotism is rare as a human disease but remains a problem in ...
Claude Schummer   +3 more
doaj   +1 more source

Programmable Functional Silicification of DNA Origami Nanostructures

open access: yesAdvanced Materials, EarlyView.
This work introduces additional functionality into silica‐coated DNA origami nanostructures using non‐standard silica precursors. A fluorescent precursor enables enhanced intracellular tracking, while a disulfide‐containing reagent yields redox‐responsive, degradable silica coatings.
Anna V. Baptist   +4 more
wiley   +1 more source

Directional Second Sphere Effect on CO2 Activation and Reduction by Iron Porphyrin in Aprotic and Protic Media

open access: yesAngewandte Chemie, EarlyView.
Directional control within the secondary coordination sphere redefines CO2 reduction by iron porphyrins. Simply rearranging identical urea hydrogen‐bond donors modulates reactivity, revealing that optimal catalysis does not only arise from maximal intermediate stabilization, but also from directional, adaptive non‐covalent interactions that balance ...
Ashutosh Vishwakarma   +7 more
wiley   +2 more sources

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