Results 11 to 20 of about 2,396 (173)
Dynamics of cetyltrimethylammonium bromide mediated reaction of phenylsulfinylacetic acid with Cr(VI): Treatment of pseudo-phase models [PDF]
Journal of the Serbian Chemical Society, 2015 micellar effect % Hammett correlation % Piszkiewicz cooperative model KR nema The influence of cetyltrimethylammonium bromide, CTon the oxidative decarboxylation of phenylsulfinylacetic acid, PSAA and several meta- and para-substituted PSAAs by Cr ...
Subramaniam Perumal +1 more
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Synthesis of some substituted pyrazole-1- carbothioamides and spectral correlations in 3-(2,4-dibromophenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1- carbothioamides [PDF]
QScience Connect, 2013 Background: This study aims to synthesise a series of 1-thiocarbomyl pyrazolines, including 3-(2,4-dibromophenyl)-5-(substituted phenyl)-4,5-dihydro-1H-pyrazole-1-carbothioamides, using solvent-free fly-ash:PTS catalyzed cyclization between chalcones and
G. Thirunarayanan, K. G.Sekar
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Molecules, 2020 The attribution of 1H and 13C NMR signals of a library of 5-, 6- and 7-substituted 2,2-dimethylchroman-4-one derivatives is reported. Substituent effects were interpreted in terms of the Hammett equation, showing a good correlation for carbons para- to ...
Daniela Iguchi +3 more
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Compounds, 2023 The ability for density functional theory with the B3LYP functional with the lanl2dz basis set to predict the 1st (Wave 1) and 2nd (Wave 2) reductions of the diazine ring in a series of thirty-seven (37) 1,4-di-N-oxide quinoxaline-2-carboxamide ...
Faranak Pooladian +4 more
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Hammett Correlations in the Chemistry of 3-Phenylpropyl Radicals
The Journal of Physical Chemistry A, 2011 The energetics and kinetics of the reaction of variously substituted benzyl radicals with a model alkene were calculated at the G3(MP2)-RAD//B3-LYP/6-31G(d) level of theory to determine whether such reactions are amenable to Hammett analysis. The reactions were studied both in the gas phase and in toluene solution in the temperature range 298-353 K ...
Modglin, James D. +4 more
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Hammett Spectral Correlations in Benzofuranyl Flavonols
International Letters of Chemistry, Physics and Astronomy, 2014 A series containing eleven benzofuranyl flavonols have been prepared by cyclization of 3-hydroxybenzofuranyl chalcones with 30% hydrogen peroxide in the presence of sodium bicarbonate. The synthesized flavonols were characterized by their physical constants, analytical and spectroscopic data. The infrared spectral
Ganesamoorthy Thirunarayanan, K.G. Sekar
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A spectrophotometric study of the protonation processes of some N-[1-(benzimidazol)-1-yl]methylbenzamide derivatives [PDF]
Journal of the Serbian Chemical Society, 2000 The protonation of N-[1-(benzimidazol)-1-yl]methylbenzamide derivatives in aqueous acids (H2SO4) media was investigated, using a spectrophotometric method. The investigated compounds have two protonation processes. The first protonation process occurs in
NADA U. PERISIC-JANJIC +2 more
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The substituent effects on the 13c chemical shifts of the azomethine carbon atom of n-(phenyl substituted) salycilaldimines [PDF]
Journal of the Serbian Chemical Society, 2012 The Hammett correlations between 13C-NMR chemical shifts of the azomethine carbon atom and the corresponding substituent constants for thirtheen Schiff bases were established.
Drmanić Saša Ž. +3 more
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Acta Chimica Slovenica, 2017 Iodine-catalyzed transformations of alcohols under solvent-free reaction conditions (SFRC) and under highly concentrated reaction conditions (HCRC) in the presence of various solvents were studied in order to gain insight into the behavior of the ...
Marjan Jereb, Dejan Vražič
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Mechanistic studies of the solvolysis of alkanesulfonyl and arenesulfonyl halides
Beilstein Journal of Organic Chemistry, 2022 There have been several studies on the solvolysis mechanisms for alkanesulfonyl chlorides (RSO2Cl) and arenesulfonyl chlorides (ArSO2Cl). The earlier of these studies were reviewed a little over thirty years ago by Gordon, Maskill and Ruasse (Chem.
Malcolm J. D’Souza, Dennis N. Kevill
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