Strategic applications of heterocyclic compounds in pharmaceutical innovation: a business perspective. [PDF]
Dong Y +6 more
europepmc +1 more source
Remote Desaturation of Unprotected Amines and C─H Amination of Alkanes by Polarity-Matched N-Radical Cations. [PDF]
Laohapaisan P +6 more
europepmc +1 more source
Asymmetric Reductive Three-Component Annulation Reaction for Constructing Fused N-Heterocycles With Contiguous Stereogenic Centers. [PDF]
Lu GP +4 more
europepmc +1 more source
DiploPhos: A Hemilabile Bisphosphine for Sterically Hindered Ni-Catalyzed Suzuki-Miyaura Couplings. [PDF]
Raab TJ +7 more
europepmc +1 more source
A manganese single‐atom photocatalyst on functionalised carbon nitride enables selective visible‐light‐driven C(sp2)─H chlorination. DFT‐supported mechanistic studies indicate that photoinduced charge separation activates NCS, while isolated Mn sites stabilize Mn─Cl intermediates at the catalyst interface.
Jaro Vanderghinste +16 more
wiley +1 more source
Catalyst-Free Photoinduced Deaminative Functionalization of Amino Acids and Glutarimide Precursors. [PDF]
Chong TG +6 more
europepmc +1 more source
Cobalt-Catalyzed Cyclohydrocarbonylations: Syntheses of Saturated Heterocycles Promoted by Light. [PDF]
Rodriguez MR +5 more
europepmc +1 more source
Dual‐Function Cosubstrates Enable Threonine Dehydrogenase‐Driven Chemoenzymatic Pyrrole Synthesis
Classical Knorr chemistry meets contemporary biocatalysis. Threonine dehydrogenase generates aminoacetone from l‐threonine, which is directly intercepted in a chemoenzymatic Knorr pyrrole synthesis. A dual‐function β‐dicarbonyl substrate serves as both pyrrole precursor and hydride acceptor for integrated NAD+ recycling, affording substituted pyrroles ...
Valentina Jurkaš +8 more
wiley +1 more source
Catalytic Stereoselective Intermolecular Fluoroacylation of Unactivated Alkynes via C-F Bond Reconstruction. [PDF]
Kanji T +6 more
europepmc +1 more source

