Carbene‐stabilized dithiolene zwitterion, as a redox‐active frustrated Lewis pair, can mediate the B─H bond activation of catecholborane via hydride‐coupled reverse electron transfer processes. This discovery represents the first experimental evidence of the FLP‐mediated B─H activation via net proton transfer.
Yuzhong Wang +5 more
wiley +1 more source
Synthesis and <i>In Vitro</i> Evaluation of Anticancer Activity of Fluorophenyl Derivatives of 1,3,4-Thiadiazole Against Estrogen-Dependent Breast Cancer. [PDF]
Janowska S +4 more
europepmc +1 more source
Research Progress of Polyoxometalate‐Integrated Frameworks: Syntheses, Properties, and Applications
This review systematically summarizes the integration of polyoxometalates with covalent organic frameworks, metal‐organic frameworks, hydrogen‐bonded organic frameworks, and emerging porous hosts. It highlights synergistic effects, synthesis strategies, and applications in catalysis, energy storage, sensing, and biomedicine, while addressing current ...
De‐Yin Wang +6 more
wiley +1 more source
Unlocking the potential of mandelic acid derivatives: chemical and biological applications - a comprehensive review. [PDF]
Banerjee A, Mitra AK.
europepmc +1 more source
Hyperpolarization by parahydrogen‐induced polarization enhances the sensitivity of nuclear magnetic resonance spectroscopy of amino acids, peptides, mini‐proteins, and biopolymers using nonnatural amino acids with unsaturated side chains up to three orders of magnitude.
Gerd Buntkowsky
wiley +1 more source
Antioxidant Activity of Maillard Reaction Products in Dairy Products: Formation, Influencing Factors, and Applications. [PDF]
Lan H +7 more
europepmc +1 more source
Gold(I)‐Catalyzed Domino Cyclization for the Construction of Trispirocyclic Cyclohexanes
We describe herein a series of intricate trispirocyclic architectures that have been synthesized from readily available substrates through an operationally simple one‐pot transformation under mild conditions. An unprecedented gold(I)‐catalyzed domino cyclization involving 2‐ethynylbenzyl alcohol derivatives and heterocyclic α,β‐unsaturated imines ...
Manon Genet +3 more
wiley +1 more source
Design, Synthesis, Antimicrobial Activity and Molecular Docking of New 1,2,4-Triazepine, 1,3,4,6-Oxatriazepine and Pyridazino[1,2-<i>a</i>] Pyrimidine Derivatives. [PDF]
Amri N, Abu-Hashem AA.
europepmc +1 more source
Intramolecular N···F Pnictogen Bond Mitigates the Explosive Behavior of Azido‐L‐Phenylalanines
An intramolecular N···F pnictogen bond is the key for the chemical stabilization of the fluorinated azido‐L‐phenylalanines, mitigating the risk of explosion and thus facilitating the handling and storage of these materials. Organic azides are versatile intermediates but are plagued by intrinsic instability and potential explosiveness. Here, it is shown
Andrea Pizzi +5 more
wiley +1 more source
Tetrahydropyridines: a recent update for their multicomponent synthesis. [PDF]
Khan MM, Faiz FA, Khan MS.
europepmc +1 more source

