Results 51 to 60 of about 92,883 (234)

Bio‐Inspired Molecular Events in Poly(Ionic Liquids)

open access: yesAdvanced Functional Materials, EarlyView.
Originating from dipolar and polar inter‐ and intra‐chain interactions of the building blocks, the topologies and morphologies of poly(ionic liquids) (PIL) govern their nano‐ and micro‐processibility. Modulating the interactions of cation‐anion pairs with aliphatic dipolar components enables the tunability of properties, facilitated by “bottom‐up ...
Jiahui Liu, Marek W. Urban
wiley   +1 more source

Synthesis and Characterization of a New Series of [1, 3]-Oxazepine Compounds from Heterocyclic Schiff Bases

open access: yesZanco Journal of Pure and Applied Sciences, 2023
      In this study a new Series of aromatic heterocyclic [1, 3]-oxazepine have been synthesized by two steps. The first-step included synthesis of imine derivatives (1–7) using glacial acetic acid as a catalyst in the condensation reaction of 4-(6 ...
Roshna B. Nadr, Bana S. Abdulrahman
doaj   +1 more source

Selective C(sp2)−H Halogenation of "click" 4-Aryl-1,2,3-triazoles [PDF]

open access: yes, 2017
Selective bromination reactions of “click compounds” are described. Electron-neutral and electron-deficient arenes selectively undergo unprecedented Pd-catalyzed C–H ortho-halogenations assisted by simple triazoles as modular directing groups, whereas ...
Correa Navarro, Arkaitz   +2 more
core   +2 more sources

Electrocatalytic Reduction of CO2 to Ethylene: Catalyst Design and Synchrotron‐Based Characterizations

open access: yesAdvanced Functional Materials, EarlyView.
This review evaluates strategies for electrochemical CO2 reduction to ethylene, focusing on copper‐based catalyst design and microenvironment modulation to achieve industrial‐grade performance. By leveraging operando synchrotron‐based characterizations, we provide a multiscale understanding of dynamic structural transformations and key reaction ...
Meng Zhang, Zuolong Chen, Yimin A. Wu
wiley   +1 more source

In vitro assessment of antimicrobial, antioxidant, and cytotoxic properties of Saccharin-Tetrazolyl and-Thiadiazolyl derivatives: the simple dependence of the pH value on antimicrobial activity [PDF]

open access: yes, 2019
The antimicrobial, antioxidant, and cytotoxic activities of a series of saccharin-tetrazolyl and -thiadiazolyl analogs were examined. The assessment of the antimicrobial properties of the referred-to molecules was completed through an evaluation of ...
Andrade, Joana M.   +9 more
core   +1 more source

NH3‐Guided Low‐Temperature Nanostructural Refinement Boosts Visible‐Light‐Driven H2O2 Synthesis in Ionic Carbon Nitrides

open access: yesAdvanced Materials, EarlyView.
A nanostructural refinement strategy is reported for KPHI photocatalysts using NH4Cl in a molten salt environment to induce coherent domain fragmentation and controlled cyano defect formation. This dual modification promotes n→π* transitions, enhances charge separation, and accelerates ORR kinetics, yielding exceptional AQY values of 49% (410 nm) and 5%
Jaya Bharti   +9 more
wiley   +1 more source

Synthesis of Fluorine Heterocyclic Nitrogen Systems Derived From Sulfa Drugs as PhotochemicalProbe Agents for Inhibition of Vitiligo Disease-Part II

open access: yesE-Journal of Chemistry, 2010
Some more new bioactive fluorine heterocyclic systems containing sulfur and nitrogen as six-membered rings such as; N,Nʼ-disubstituted-thiobarbituric acid, 3-thioxo-1,2,4-triazino[5,6-b]indole, 3-sulfanilamido-1,2,4-triazino[5,6-b]indole and 2 ...
Reda M. Abdel-Rahman   +2 more
doaj   +1 more source

3-{5-Bromo-2-[(triphenylphosphanylidene)amino]phenyl}-4,5-dihydro-1,2,3-oxadiazol-3-ylium-5-olate

open access: yesActa Crystallographica Section E, 2013
In general, sydnone compounds are synthesized with an aromatic substituent at the N-3 position and this feature adds to the stability of the mesoionic five-membered heterocyclic ring.
Kenneth Turnbull   +2 more
doaj   +1 more source

Synthesis and Influence of 3-Amino Benzoxaboroles Structure on Their Activity against Candida albicans

open access: yesMolecules, 2020
Benzoxaboroles emerged recently as molecules of high medicinal potential with Kerydin® (Tavaborole) and Eucrisa® (Crisaborole) currently in clinical practice as antifungal and anti-inflammatory drugs, respectively. Over a dozen of 3-amino benzoxaboroles,
Dorota Wieczorek   +6 more
doaj   +1 more source

Simple oxidation of pyrimidinylhydrazones to triazolopyrimidines and their inhibition of Shiga toxin trafficking [PDF]

open access: yes, 2010
The oxidative cyclisation of a range of benzothieno[2,3-d]pyrimidine hydrazones (7a–j) to the 1,2,4-triazolo[4,3-c]pyrimidines (8a–j) catalysed by lithium iodide or to the 1,2,4-triazolo[1,5-c]pyrimidines (10a–j) with sodium carbonate is presented.
Ahmed   +46 more
core   +1 more source

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