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Synthesis of trifluoromethyl heterocyclic compounds [PDF]

open access: yesJournal of Chemical Research, 2003
The synthesis of trifluoromethyl pyrazoles, 1,5-benzodiazepines, and 1,5-benzothiazepines is described. The regiochemistry of the pyrazole synthesis was investigated using 2D NMR methods.
Emna Zouaoui, Mohamed Moncef El Gaied
openaire   +1 more source

Synthesis of α-amino amides via α-amino imidoylbenzotriazoles [PDF]

open access: yesJournal of the Serbian Chemical Society, 2005
Reactions of isonitriles 11a-c with N-(α-aminoalkyl)benzotriazoles 10a-k afford N-(α-aminoimidoyl)benzotriazoles 12a-q which on hydrolysis by dilute hydrochloric acid gave α-amino amides 14a-j.
Katritzky Alan R.   +4 more
doaj   +1 more source

Ultrasound-Promoted preparation and application of novel bifunctional core/shell Fe3O4@SiO2@PTS-APG as a robust catalyst in the expeditious synthesis of Hantzsch esters

open access: yesScientific Reports, 2023
In this work, D-(–)-α-phenylglycine (APG)-functionalized magnetic nanocatalyst (Fe3O4@SiO2@PTS-APG) was designed and successfully prepared in order to implement the principles of green chemistry for the synthesis of polyhydroquinoline (PHQ) and 1,4 ...
Peyman Shakib   +4 more
doaj   +1 more source

CuFe2O4@SiO2@L-arginine@Cu(I) as a new magnetically retrievable heterogeneous nanocatalyst with high efficiency for 1,4-disubstituted 1,2,3-triazoles synthesis

open access: yesScientific Reports, 2023
A novel magnetic heterogeneous catalyst was synthesized through the immobilization of copper ions onto the l-arginine functionalized CuFe2O4@SiO2. The prepared catalyst was characterized by Fourier Transform Infrared (FT-IR), X-ray diffraction (XRD ...
Fatemeh Salehzadeh   +4 more
doaj   +1 more source

Synthesis of (E)-2-(1H-tetrazole-5-yl)-3-phenylacrylenenitrile derivatives catalyzed by new ZnO nanoparticles embedded in a thermally stable magnetic periodic mesoporous organosilica under green conditions

open access: yesScientific Reports, 2022
ZnO nanoparticles embedded in a magnetic isocyanurate-based periodic mesoporous organosilica (Fe3O4@PMO–ICS–ZnO) were prepared through a modified environmentally-benign procedure for the first time and properly characterized by appropriate spectroscopic ...
Sajedeh Safapoor   +3 more
doaj   +1 more source

Sulfamic acid pyromellitic diamide-functionalized MCM-41 as a multifunctional hybrid catalyst for melting-assisted solvent-free synthesis of bioactive 3,4-dihydropyrimidin-2-(1H)-ones

open access: yesScientific Reports, 2021
This study introduces a practical approach to fabricate a novel hybrid acidic catalyst, namely sulfamic acid pyromellitic diamide-functionalized MCM-41 (MCM-41-APS-PMDA-NHSO3H).
Ehsan Valiey   +2 more
doaj   +1 more source

Dendrons containing boric acid and 1,3,5-tris(2-hydroxyethyl)isocyanurate covalently attached to silica-coated magnetite for the expeditious synthesis of Hantzsch esters

open access: yesScientific Reports, 2021
A new multifunctional dendritic nanocatalyst containing boric acid and 1,3,5-tris(2-hydroxyethyl)isocyanurate covalently attached to core–shell silica-coated magnetite (Fe3O4@SiO2@PTS-THEIC-(CH2)3OB(OH)2) was designed and properly characterized by ...
Mahsa Sam   +2 more
doaj   +1 more source

Catalytic Enantioselective Approaches to the oxa-Pictet–Spengler Cyclization and Other 3,6-Dihydropyran-Forming Reactions

open access: yesSynOpen, 2019
This Short Review provides an analysis of the state-of-the-art in catalytic enantioselective oxa-Pictet–Spengler cyclizations. Also discussed are other catalytic reactions providing access to enantio­enriched isochromans and tetrahydropyrano[3,4-b ...
Zhengbo Zhu   +3 more
doaj   +1 more source

Synthesis of nanocellulose aerogels and Cu-BTC/nanocellulose aerogel composites for adsorption of organic dyes and heavy metal ions

open access: yesScientific Reports, 2021
MOFs compounds with open metal sites, particularly Cu-BTC, have great potential for adsorption and catalysis applications. However, the powdery morphology limits their applications. One of the almost new ways to overcome this problem is to trap them in a
Nuhaa Shaheed   +4 more
doaj   +1 more source

Novel magnetic propylsulfonic acid-anchored isocyanurate-based periodic mesoporous organosilica (Iron oxide@PMO-ICS-PrSO3H) as a highly efficient and reusable nanoreactor for the sustainable synthesis of imidazopyrimidine derivatives

open access: yesScientific Reports, 2020
In this study, preparation and characterization of a new magnetic propylsulfonic acid-anchored isocyanurate bridging periodic mesoporous organosilica (Iron oxide@PMO-ICS-PrSO3H) is described. The iron oxide@PMO-ICS-PrSO3H nanomaterials were characterized
Arezoo Akbari   +3 more
doaj   +1 more source

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