Results 161 to 170 of about 173,680 (267)

XXIV.—The formation of heterocyclic compounds

open access: green, 1900
Siegfried Ruhemann, H. E. Stapleton
openalex   +1 more source

Hydrogen Isotope Exchange in Pyridine Catalyzed by an Iron(II) Imido Complex: Counterion‐Directed Regioselectivity

open access: yesAngewandte Chemie International Edition, EarlyView.
Anionic high‐spin iron(II) imido complexes are catalysts for the hydrogen isotope exchange (HIE) reaction with pyridine as the substrate. The alkali metal counter‐cation plays critical roles in activating the substrate and facilitating deuteration. These complexes catalyze site‐selective α‐, α,β,γ‐, and β,γ‐deuteration of pyridine, where the counter ...
Bin Feng   +6 more
wiley   +1 more source

From [NHC─H]• to Persistent σ‐Complex Radicals: Photoinduced Radical Chemistry of Imidazolium Salts

open access: yesAngewandte Chemie International Edition, EarlyView.
Visible‐light excitation of electron donor–acceptor (EDA) complexes between imidazolium salts and triarylamines enables controlled single‐electron transfer (SET) and reveals a family of carbene‐centered σ‐complex radical cations. Cryogenic electron paramagnetic resonance (EPR) captures the elusive [NHC─H]• intermediate and its thermal evolution into ...
Filipp M. Kolomeychuk   +4 more
wiley   +1 more source

1-Indol-1-yl-propan-2-ones and related heterocyclic compounds as dual inhibitors of cytosolic phospholipase A2α and fatty acid amide hydrolase

open access: green, 2009
Laura Forster   +6 more
openalex   +1 more source

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