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Nitrate Reduction for Deaminative Suzuki–Miyaura Coupling of Anilines

open access: yesAngewandte Chemie, EarlyView.
We present a one‐step deaminative Suzuki–Miyaura‐type coupling of anilines via fleeting diazonium intermediate with nitrate and bisulfite as the reagents. This represents the first application of the nitrate reduction strategy in transition metal catalysis of diazonium chemistry.
Chen‐Chen Li   +6 more
wiley   +2 more sources

Manganese‐Catalyzed Enantioselective Dearomative Epoxidation of Naphthalenes with Aqueous Hydrogen Peroxide

open access: yesAngewandte Chemie, EarlyView.
The enantioselective epoxidation of naphthalenes into their corresponding arene oxides with aqueous hydrogen peroxide is described. The reaction combines dearomatization with installation of chemically versatile functionality in an enantioselective manner.
Najoua Choukairi Afailal   +2 more
wiley   +2 more sources

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