Results 71 to 80 of about 96,191 (265)

Substrate‐Affinitive P‐Type Azapolycyclic Photosensitizer for Chemoselective Nitrilization Under Mild Conditions

open access: yesAdvanced Science, EarlyView.
We developed a series of quinoxalinoquinoxaline (QQ) photosensitizers featuring high and tunable excited‐state reduction potentials (E(PC•+/PC*) = –1.76 to –2.05 V vs. SCE). Their hydrogen‐bonding interaction with carbonyl substrates enables selective single‐electron transfer events for selective nitrilization of 1° amides, offering a tunable ...
Seongwoo Bae, Dongwook Kim, Jinwoo Kim
wiley   +1 more source

Crystal structures of N-[(4-phenylthiazol-2-yl)carbamothioyl]benzamide and N-{[4-(4-bromophenyl)thiazol-2-yl]carbamothioyl}benzamide from synchrotron X-ray diffraction

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2016
The title compounds, C17H13N3OS2, (I), and C17H12BrN3OS2, (II), are potential active pharmaceutical ingredients. Compound (I) comprises two almost planar fragments. The first is the central (carbamothioyl)amide (r.m.s.
Ekaterina S. Gantimurova   +6 more
doaj   +1 more source

Janus‐Type Electrostatic Potential Gradient‐Activated Dynamic Zn2+‐Coordinating Nitrogen Sites in Molecularly Locked Nanocellulose Separators for Stable Zinc‐Ion Batteries

open access: yesAdvanced Science, EarlyView.
A multifunctional benzimidazole‐terminated CNF separator is constructed via a PEI‐mediated covalent locking strategy, generating dense zincophilic sites that accelerate Zn2+ transport and desolvation while enabling uniform Zn (002) deposition and suppressing side reactions.
Jie Liang   +17 more
wiley   +1 more source

Novel heterocyclic construction via dipolar cycloadditions to 1,2-dicarbonyl compounds

open access: yes, 2000
The reactivity of o-quinones and other 1,2-diones towards a variety of dipolar species viz-, nitrile oxides, carbonyl ylides, betaines and mesoionic compounds has been investigated. In most cases, these reactions occur with the participation of C=O group
Somarajan Nair, J.   +6 more
core   +1 more source

Decoupling Intrinsic Molecular Efficacy From Platform Effects: An Interpretable Machine Learning Framework for Unbiased Perovskite Passivator Discovery

open access: yesAdvanced Science, EarlyView.
This study establishes an interpretable machine learning framework that disentangles the intrinsic molecular efficacy of passivators from experimental platform effects—enabling unbiased, high‐throughput discovery of effective perovskite surface modifiers.
Jing Zhang   +5 more
wiley   +1 more source

Synthesis and Characterization of a Graphene Oxide Hydrogel Nanocomposite for Efficient Lithium Ion Adsorption from Aqueous Solutions

open access: yesChemistry Proceedings
In this study, a PVA/graphene oxide (GO) hydrogel nanocomposite was synthesized as a adsorbent for Li+ removal from aqueous solutions. The composite was characterized by FTIR, XRD, and SEM/EDS to verify interfacial interactions and porous morphology ...
Amir Ali Hadiyanjazi   +2 more
doaj   +1 more source

Direct Electrochemistry of Glucose Oxidase on a GrapheneGraphene Oxide Nanocomposite-Modified Electrode for a Glucose Biosensor

open access: yesInternational Journal of Electrochemical Science, 2019
Direct electrochemistry of glucose oxidase (GOD) was conducted on the surface of a novel graphenegraphene oxide (GR-GO) nanocomposite. GR-GO possesses the virtues of excellent biocompatibility and conductivity, and high sensitivity to local perturbations,
Bo Wang   +4 more
doaj   +1 more source

Atroposelective Construction of Axially Chiral Tetraarylethenes Via NHC‐Catalyzed Desymmetrization

open access: yesAdvanced Science, EarlyView.
We report the first NHC‐catalyzed atroposelective synthesis of axially chiral TAEs via oxidative desymmetrization of prochiral TAE dialdehydes. This catalytic strategy operates under mild conditions and accommodates a broad range of phenolic and nitrogen nucleophiles, delivering diverse axially chiral TAEs in good yields and up to 99% ee.
Yang‐Ze Zheng   +6 more
wiley   +1 more source

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