Results 51 to 60 of about 173,680 (267)

Modular Generation of Alkyl Selenyl Radicals for the Synthesis of Alkyl Selenides via a Mechanochemical Approach

Advanced Science, EarlyView.
We present a mechanochemical, radical‐mediated hydroselenation of alkenes under ambient conditions. This method modularly generates alkyl selenyl radicals from elemental selenium and alkyl (pseudo)halides, utilizing PhSiH3 and H2O as hydrogen atom donors, with the water likely originating from the air and/or trace water present in the reagents ...
Xiaochun He, Yu Zhou, Fei Zhou, Zixi Ai, Peiyu Hu, Xuemei Zhang, Xiaofeng Wei, Gui‐Juan Cheng, Zhong Lian   +8 more
wiley   +1 more source

Preparation of heterocyclic block copolymer from perfluoroalkylene oxide alpha, omega-diamidoximes [PDF]

, 1979
Diamidoxime monomers are intermolecularly and thermally condensed to form a heat and chemical resistant polymer containing 1,2,4-oxadiazole linkages with identical bivalent organic radicals or any combination of bivalent organic radicals selected from ...
Iannone, M., Ross, L. O., Rosser, R. W.
core   +1 more source

Recent Advances in Homogeneous Metal-Catalyzed Aerobic C–H Oxidation of Benzylic Compounds [PDF]

, 2018
Csp(3)-H oxidation of benzylic methylene compounds is an established strategy for the synthesis of aromatic ketones, esters, and amides. The need for more sustainable oxidizers has encouraged researchers to explore the use of molecular oxygen.
Domínguez Pérez, Pilar Esther, Herrero Corral, María Teresa, San Martín Faces, Raúl, Urgoitia Gabikaetxebarria, Garazi   +3 more
core   +3 more sources

FeCoNiCuPt High‐Entropy Alloy Boosts Photocatalytic Hydrogen Production on Protonated Graphitic Carbon Nitride

Advanced Science, EarlyView.
In this study, FeCoNiCuPt high‐entropy alloy particles (HEA) are loaded onto protonated g‐C3N4 nanosheets (HCN NSs) to construct HEA/HCN composites through an electrostatic self‐assembly method. Protonation treatment enriches the surface of g‐C3N4 nanosheets with abundant active sites and enhances their interfacial charge separation capability ...
Yunzhu Zang, Jiali Ren, Yanjun Xue, Jian Tian   +3 more
wiley   +1 more source

In vitro assessment of antimicrobial, antioxidant, and cytotoxic properties of Saccharin-Tetrazolyl and-Thiadiazolyl derivatives: the simple dependence of the pH value on antimicrobial activity [PDF]

, 2019
The antimicrobial, antioxidant, and cytotoxic activities of a series of saccharin-tetrazolyl and -thiadiazolyl analogs were examined. The assessment of the antimicrobial properties of the referred-to molecules was completed through an evaluation of ...
Andrade, Joana M., Cabral, Lília, Cristiano, Maria de Lurdes, Frija, Luís M. T., Ntungwe, Epole, Pombeiro, Armando J. L., Rijo, Patrícia, Sitarek, Przemysław, Toma, Monika, Śliwiński, Tomasz   +9 more
core   +1 more source

Stabilizing Atomically Dispersed Au With Adjacent Pt for Spatially Precise Molecule Recognition

Advanced Science, EarlyView.
A strategy to stabilize atomically dispersed Au catalysts by introducing Pt atoms into CeO2 supports is presented. Pt incorporation prevents Au aggregation, enhances Au‐O orbital coupling, and enables precise recognition of multi‐functionalized molecules, improving catalytic performance and the structural stability of Au‐based catalysts in ...
Rui Tang, Xiangyu Xiao, Jingyi Yao, Qing Wang, Qijing Gao, Nan Zhou, Fanyi Kong, Dingguan Liang, Kangning Dong, Liang Xiong, Yuwei Cao, Zhendong Lei, Liang Tang   +12 more
wiley   +1 more source

Fused Ring Engineering Induced Topology Control in Covalent Organic Frameworks: Unlocking Promoted Photocatalytic H2O2 Production and Selective Methane Oxidation

Angewandte Chemie, EarlyView.
By modulating the topological structures of two N‐heterocycle‐based covalent organic frameworks, Phen‐TTA with a kgd‐v topology exhibits narrower optical bandgap, lower exciton binding energy, and faster charge‐carrier kinetics compared to O‐TTA with an hcb topology.
Lei Wang, Zhipeng Xie, Xinyi Zeng, Hetao Xu, Mingyue Wang, Jie Yang, Chao Lin, Wandong Xing, Zhengxiao Guo, Xiong Chen   +9 more
wiley   +2 more sources

Dirhenium Carbonyl Complexes Bearing 2-Vinylpyridine, Morpholine and 1-Methylimidazole Ligands [PDF]

, 2008
Treatment of the labile compound [Re2(CO)8(MeCN)2] with 2-vinylpyridine in refluxing benzene affords exclusively the new compound [Re2(CO)8(μ-η1:η2-NC5H4CHCH2)] (1) in 39% yield in which the μ-η1:η2-vinylpyridine ligand is coordinated to one Re atom ...
Ahmed, Faruque, Bennett, Dennis W., Das, Anamika, Hassan, Mohammad R., Haworth, Daniel T., Kabir, Shariff E., Lindeman, Sergey V., Siddiquee, Tasneem   +7 more
core   +1 more source

Synthesis of novel azo compounds containing 5(4H)-oxazolone ring as potent tyrosinase inhibitors [PDF]

, 2013
Six new azo dyes containing of 5(4H)-oxazolone ring were prepared by diazotization of 4-aminohippuric acid and coupling with N,N-dimethylaniline, 1-naphthol and 2-naphthol and condensation with 4-fluoro benzaldehyde or 4-trifluoromethoxy benzaldehyde ...
Abbasalipour, V., Fozooni, S., Hamidian, H., Namjou, M., Tagizadeh, R., Taheri, A.   +5 more
core   +1 more source

Precise Tailoring 3D Printed In Situ Toughening Low‐k Microwave Transparent Structure via Thiol‐acrylate Chain Transfer Behavior

Advanced Science, EarlyView.
An in situ thiol–acrylate chain transfer‐mediated toughening strategy is introduced for Digital Light Processing (DLP) printing. Benefiting from its excellent printability, a printed gyroid lattice‐filled plate (100 µm wall thickness) achieves 92% transmittance at 10 GHz under a 50° incidence angle following structural optimization. ABSTRACT The unique
Ce Bian, Kai Zheng, Ruoyu Chen, Wansong Gu, Guanxiang Zhong, Difei Liang, Longjiang Deng, Hetao Chu   +7 more
wiley   +1 more source