Results 91 to 100 of about 1,056,868 (306)

Heterogeneous catalysis: Catch me if you can! [PDF]

open access: yes, 2009
Chemists are like detectives: they like to know 'whodunit' during a catalytic reaction. Combining advanced electron microscopy with intelligent molecular design has now provided strong evidence for the presence of a highly active site within a complex ...
Inorganic Chemistry and Catalysis   +2 more
core  

Nationwide Survey of Association Between Fever and Epileptic Seizure in CDKL5 Deficiency Disorder Revealed Therapeutic Implications

open access: yesAnnals of Clinical and Translational Neurology, EarlyView.
ABSTRACT Objective CDKL5 deficiency disorder (CDD) is a rare, severe developmental and epileptic encephalopathy. There is a pressing need to develop effective and sustainable therapeutic strategies. We aimed to investigate the causal association between febrile episodes and epileptic seizures for therapeutic implications in CDD patients.
Siyi Wang   +13 more
wiley   +1 more source

Ligand-functionalized nanoparticles for chemo- and stereoselective, heterogeneous catalysis [PDF]

open access: yes, 2017
Asymmetric catalysis is an important topic for establishing sustainable chemical preparation routes. Mainly homogeneous catalysts consisting of single metal atoms with chiral organic ligands have been developed within the past decades, but their ...
Schrader, Imke
core  

Theoretical study of crystal phase effect in heterogeneous catalysis

open access: yes, 2016
Density functional theory (DFT) is a powerful tool to study heterogeneous catalysis nowadays. In past decades, numerous DFT calculations have been conducted to investigate the mechanism of catalytic reaction from which the rationale of catalyst design ...
Liu, J Jinxun   +5 more
core   +1 more source

Tandem reductive amination and deuteration over a phosphorus-modified iron center

open access: yesNature Communications
Deuterated amines are key building blocks for drug synthesis and the identification of metabolites of new pharmaceuticals, which drives the search for general, efficient, and widely applicable methods for the selective synthesis of such compounds.
Haifeng Qi   +11 more
doaj   +1 more source

High‐Resolution Corrosion Fingerprinting of Alloy Libraries via Microdroplet Spectroelectrochemistry

open access: yesAdvanced Engineering Materials, EarlyView.
Ionic‐liquid microdroplet spectroelectrochemistry enables stable, localized electrochemical measurements over extended timescales. By coupling impedance spectroscopy, wetting analysis, finite‐element simulations, and operando Raman spectroscopy, it disentangles geometrical and electrochemical effects, opening new opportunities for rapid corrosion ...
Ekaterina Kurchavova   +3 more
wiley   +1 more source

Radical-constructed intergrown titanosilicalite interfaces for efficient direct propene epoxidation with H2 and O2

open access: yesNature Communications
The development of titianosilicates is considered a major milestone in oxidative catalysis due to the ability of framework Ti sites to co-ordinate hydrogen peroxide/peroxy species.
Dong Lin   +13 more
doaj   +1 more source

FastNano Liquid: An Automated Platform for Small‐Angle X‐ray Scattering‐Based Materials Discovery

open access: yesAdvanced Engineering Materials, EarlyView.
We present FastNano Liquid, an automated small‐ and wide‐angle X‐ray scattering platform for the combined synthesis and characterization of (nano)materials. The platform is coupled to varied reactor workflows for both in situ studies of reaction kinetics and ex situ screening of synthesis conditions to support machine learning‐guided exploration ...
Pierre‐Baptiste Flandrin   +16 more
wiley   +1 more source

Laser‐Induced Graphene from Waste Almond Shells

open access: yesAdvanced Functional Materials, EarlyView.
Almond shells, an abundant agricultural by‐product, are repurposed to create a fully bioderived almond shell/chitosan composite (ASC) degradable in soil. ASC is converted into laser‐induced graphene (LIG) by laser scribing and proposed as a substrate for transient electronics.
Yulia Steksova   +9 more
wiley   +1 more source

Bio‐Inspired Synthesis of Macroporous Single Crystal Particles as Scattering Agents

open access: yesAdvanced Functional Materials, EarlyView.
A general strategy is presented that delivers unique, single‐crystal microparticles that combine submicron macroporosity and uniform particle shapes. A bioinspired approach is used to occlude three distinct types of additives – polystyrene microspheres, polymer vesicles and amino acids – within calcite single crystals, and subsequent thermal annealing ...
Stephanie E. Foster   +11 more
wiley   +1 more source

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