Results 31 to 40 of about 5,186,208 (171)

Controlled preparation of a heterometallic lanthanide complex containing different lanthanides in symmetrical binding pockets.

, 2009
A heterometallic lanthanide complex has been prepared by sequential deprotection and complexation of an orthogonally protected ligand: luminescence and NMR spectroscopy have been used to probe the integrity of the ...
Villaraza, AJ, Faulkner, Stephen, Kenwright, Alan M., Natrajan, LS, Natrajan, Louise S.; id_orcid, Faulkner, S, Villaraza, Aaron Joseph L, Kenwright, AM   +7 more
core   +1 more source

Highly Porous Cyanometallic Spin-Crossover Frameworks Employing Pyridazino[4,5-d]pyridazine Bridge

Inorganics, 2022
Single crystals of two spin-crossover (SCO) cyanometallic coordination polymers based on the pyridazino[4,5-d]pyridazine ligand (pp) of the composition [Fe(pp)M(CN)4]∙G (where M = Pd, Pt; G = guest molecules) were obtained by a slow diffusion technique ...
Volodymyr M. Hiiuk, Sergiu Shova, Kostiantyn V. Domasevitch, Il’ya A. Gural’skiy   +3 more
doaj   +1 more source

Elucidating the role of seed structure in the heterometallic seeded growth of copper-based nanocrystals

Frontiers in Nanotechnology, 2023
Seed-mediated synthesis is a versatile method to prepare multimetallic nanocrystals for diverse applications. However, many fundamental questions remain on how the structural and chemical properties of nanocrystal seeds control the reaction pathways ...
Soojin Jeong, Rebecca X. Skalla, Yi Wang, Baixu Zhu, Xingchen Ye   +4 more
doaj   +1 more source

Three 1D cyanide-bridged M(Ni, Pd, Pt)-Mn(II) coordination polymer: synthesis, crystal structure and magnetic properties

Acta Chimica Slovenica, 2017
Three tetracyanide-containing building blocks K2[M(CN)4] (M = Ni, Pd, Pt) and one semi-closed macrocycle seven-coordinated manganese(II) compound have been employed to assemble cyanide-bridged heterometallic complexes, resulting in three cyanide-bridged ...
Jingwen Shi, Chongchong Xue, Lingqian Kong, Daopeng Zhang   +3 more
doaj   +1 more source

Physical Parameters of the Synthesized Complex Compound of Cobalt (II) with N, N'-Bis(salicylidene)semicarbazide

Фізика і хімія твердого тіла, 2020
A new material of strontium tetraaquad[N, N'-bis(salicylidene)semicarbazidatocobalt(II)] dihydrate (I) with the following composition: Sr[CoL'(Н2О)2]22Н2О, where H3L = N,N'-bis(salicylidene)semicarbazide was synthesized.
O.V. Osadchuk, V.V. Martyniuk, T.I. Sydoruk, O.O. Semenova   +3 more
doaj   +1 more source

Probing Electrocatalyst Design for Product Selectivity in CO2 Reduction

Advanced Science, EarlyView.
Selective CO2 electroreduction is controlled by catalyst structure, dynamic surface reconstruction, adsorbate interactions, and reaction microenvironment. This review summarizes Cu‐ and non‐Cu‐based catalysts, single‐atom and molecular systems, degradation pathways, and operando/computational strategies for steering CO2RR toward hydrocarbons ...
Suvodeep Sen, Bapan Biswas, Apinya Ngoipala, Julia Wiktor, Ujjwal Pal, Shalini Singh   +5 more
wiley   +1 more source

Injectable and photocurable macromonomers synthesized using a heterometallic magnesium-titanium metal-organic catalyst for elastomeric polymer networks [PDF]

, 2023
Injectable and in situ photocurable biomaterials are receiving a lot of attention due to their ease of application via syringe or dedicated applicator and ability to be used in laparoscopic and robotic minimally invasive procedures.
Gokhan, Demirci, Miroslawa, El Fray, Wojciech, Ignaczak, Peter, Sobolewski, Malwina, Niedzwiedz, Agata, Goszczyńska   +5 more
core   +2 more sources

Rapid Electrochemical Synthesis and Solvatochromic Emission Behavior of Single Crystals of a Heteronuclear Platinum(II)‐Copper(I) Complex

Aggregate
In this study, we present a novel multicomponent self‐assembly approach that offers good potential for crafting heterometallic complexes with exceptional constitutional control.
Yijia Liu, Limin Zhang, Yun Ma, Pengfei She, Wei Tang, Wai‐Yeung Wong   +5 more
doaj   +1 more source

Halogen-Dependent Diversity and Weak Interactions in the Heterometallic Ni/Cd Complex Solids: Structural and Theoretical Investigation

Molecules, 2023
Three novel heterometallic Ni/Cd coordination compounds [Ni(en)3][CdCl4]∙3dmso (1), [Ni(en)2(dmf)2][CdBr4] (2), and [Ni(en)3]2[CdI4](I)2 (3) have been synthesized through the self-assembly process in a one-pot reaction of cadmium oxide, nickel salt (or ...
Oksana V. Nesterova, Svitlana R. Petrusenko, Brian W. Skelton, Dmytro S. Nesterov   +3 more
doaj   +1 more source

Strong Metal‐Support Interaction Driven Janus Reconstruction in PtRu Alloys for Low‐Temperature Hydrogen Storage

Advanced Science, EarlyView.
Strong metal‐support interactions (SMSI) drive the spontaneous segregation of RuPt alloy into Janus nanoparticles on CeO2, spatially partitioning Pt‐rich domains for H2 dissociation and Ru‐rich domains for toluene adsorption. This Janus nanocatalysts yield a turnover frequency of 10 906 h−1 for toluene hydrogenation at 50 °C, which is 6.7 times that of
Xingyu Zhang, Haiqiang Bai, Wenbin Li, You Wang, Yunhua Xu, Sai Zhang   +5 more
wiley   +1 more source