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Sandwich d/f Heterometallic Complexes [(Ln(hfac)3)2M(acac)3] (Ln = La, Pr, Sm, Dy and M = Co; Ln = La and M = Ru) [PDF]

open access: yesMolecules
Sandwich d/f heterometallic complexes [(Ln(hfac)3)2M(acac)3] (Ln = La, Pr, Sm, Dy and M = Co; Ln = La and M = Ru) were prepared in strictly anhydrous conditions reacting the formally unsaturated fragment [Ln(hfac)3] and [M(acac)3] in a 2-to-1 molar ratio.
Cristian Grechi   +5 more
doaj   +2 more sources

Heterometallic Multinuclear Ruthenium Complexes as Cytotoxic Agents [PDF]

open access: yesBiomedicines
The design of multitargeted drug candidates has recently emerged as a highly attractive area of research. Numerous heterometallic compounds have been developed to enhance both the biological efficacy and physicochemical properties of monometallic ...
Irena Kostova
doaj   +2 more sources

Heterobimetallic Janus Catalysts for the One-Pot Synthesis of Polar-Apolar Block Copolymers. [PDF]

open access: yesAngew Chem Int Ed Engl
Heterobimetallic Janus catalysts act as bifunctional initiators, combining two distinct polymerisation mechanisms in one pot to deliver well‐defined apolar‐polar block copolymers. Combining Earth abundant Ti and Al catalysts for respective α‐olefin and lactone polymerisation, the orthogonal activity is enabled by unprecedented initiation from a Ti ...
Chambenahalli R, Nichol GS, Garden JA.
europepmc   +3 more sources

Directed Synthesis of {Mn18Cu6} Heterometallic Complexes† [PDF]

open access: yesAngewandte Chemie - International Edition, 2013
Mark Murrie   +2 more
exaly   +2 more sources

Structure and Properties of Heterometallics Based on Lanthanides and Transition Metals with Methoxy-β-Diketonates

open access: yesMolecules, 2022
The possibility of obtaining volatile polynuclear heterometallic complexes containing lanthanides and transition metals bound by methoxy-β-diketonates was studied.
Vladislav V. Krisyuk   +5 more
doaj   +1 more source

Heterometallic Molecular Architectures Based on Fluorinated β-Diketone Ligands

open access: yesMolecules, 2022
This review summarizes the data on the synthesis of coordination compounds containing two or more different metal ions based on fluorinated β-diketonates.
Viktor I. Saloutin   +4 more
doaj   +1 more source

Competing excitation paths in luminescent heterobimetallic Ln-Al complexes: Unraveling interactions via experimental and theoretical investigations

open access: yesiScience, 2023
Summary: The interest for heterometallic lanthanide-d or-p metal (Ln-M) complexes is growing because of a potential cooperative or synergistic effect related to the proximity of two different metals in the same molecular architecture affording special ...
Luca Bellucci   +8 more
doaj   +1 more source

Syntheses and structural characterization of heterometallic trinuclear {Cu(I), Ag(I)}-Ir(III) hydride complexes bridged by Ir metalloligands

open access: yesResults in Chemistry, 2022
The reactions of [Ir(H)2(PPh3)2(tptz)]PF6 (1) (tptz = 2,4,6-tris(2-pyridyl)-s-triazine) with {Cu(I), Ag(I)} salts under Ar afforded heterometallic trinuclear {Cu(I), Ag(I)}-Ir(III)-tptz hydride complexes [CuIr2(H)4(PPh3)4(tptz)2](PF6)3·2Me2CO (2), [AgIr2(
Masahiko Maekawa   +4 more
doaj   +1 more source

Influence of Substituents in Terephthalate Linker on the Structure of MOFs Obtained from Presynthesized Heterometallic Complex

open access: yesInorganics, 2021
The synthesis of new porous materials with desired properties is a challenging task. It becomes especially difficult if you need to combine several metals in one framework to obtain a heterometallic node. The use of presynthesized complexes for obtaining
Marina Barsukova   +6 more
doaj   +1 more source

Synthesis and Characterisation of New {Fe2CrO} Heterotrinuclear Iron-chromium Clusters

open access: yesChemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 2021
Two new μ3-oxo trinuclear heterometallic Fe2IIICrIII complexes with furan-2-carboxylic and salicylic acids with the composition: [Fe2CrO(C4H3OCOO)6(CH3OH)3]NO3·0.5CH3OH and [Fe2CrO(C6H4(OH)COO)7(CH3OH)2]·2DMA were synthesized starting from iron(III) and ...
Viorina Gorinchoy   +4 more
doaj   +1 more source

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