Results 1 to 10 of about 8,848 (177)

Advances in heterometallic ring-opening (co)polymerisation catalysis [PDF]

open access: yesNature Communications, 2021
Improving catalyst performance for ring-opening (co)polymerisation (RO(CO)P) reactions by using heterometallic cooperativity is a promising yet underexplored strategy.
Weronika Gruszka, Jennifer A. Garden
doaj   +2 more sources

Heterometallic Multinuclear Ruthenium Complexes as Cytotoxic Agents [PDF]

open access: yesBiomedicines
The design of multitargeted drug candidates has recently emerged as a highly attractive area of research. Numerous heterometallic compounds have been developed to enhance both the biological efficacy and physicochemical properties of monometallic ...
Irena Kostova
doaj   +2 more sources

Heterometallic Molecular Architectures Based on Fluorinated β-Diketone Ligands

open access: yesMolecules, 2022
This review summarizes the data on the synthesis of coordination compounds containing two or more different metal ions based on fluorinated β-diketonates.
Viktor I. Saloutin   +4 more
doaj   +2 more sources

Homometallic Intervalence Charge Transfer Band of Co(II/III) Induced by Phase Transitions in a Heterometallic Co–W Charge Transfer Photomagnet [PDF]

open access: yesSmall Science
A photomagnet, Co8[W(CN)8]5Cl·(pyrazine)11·21H2O, exhibiting Class II mixed valency due to homometallic intervalence charge transfer (IVCT) between CoII and CoIII centers, is synthesized.
Kazuki Nakamura   +5 more
doaj   +2 more sources

Metal Rich Metallaboranes: Synthesis, Structure and Bonding of pileo-[(Cp*Ru)2M(CO)3(µ-H)(µ-E)(µ3-BH)B2H5] (M = Mo, W, E = CO, and M = Mn, E = H) Clusters

open access: yesInorganics, 2023
The synthesis and structural characterization of a series of heterotrimetallic ruthenaborane clusters are reported. The photolytic reaction of nido-[(Cp*Ru)2(µ-H)2B3H7] (nido-1) (Cp* = 1,2,3,4,5-pentamethylcyclopentadienyl) with [M(CO)5·THF] (THF ...
Alaka Nanda Pradhan   +4 more
doaj   +1 more source

Structure and Properties of Heterometallics Based on Lanthanides and Transition Metals with Methoxy-β-Diketonates

open access: yesMolecules, 2022
The possibility of obtaining volatile polynuclear heterometallic complexes containing lanthanides and transition metals bound by methoxy-β-diketonates was studied.
Vladislav V. Krisyuk   +5 more
doaj   +1 more source

From K6[Re6−xMoxS8(CN)5] Solid Solution to Individual Cluster Complexes: Separation and Investigation of [Re4Mo2S8(CN)6]n− and [Re3Mo3S8(CN)6]n− Heterometallic Clusters

open access: yesMolecules, 2023
A series of new cluster compounds with {Re4Mo2S8} and {Re3Mo3S8} cores has been obtained and investigated. The clusters with different Re/Mo ratios were isolated as individual compounds, which made it possible to study their spectroscopic and ...
Tatiana I. Lappi   +8 more
doaj   +1 more source

Tetrameric cubane Al9Ln7 (Ln = Ce, Pr, Nd) clusters as aldol addition catalysts

open access: yesPolyoxometalates, 2023
Studies on the preparation, structures, and properties of heterometallic complexes are currently of great interest because of their emergent synergistic properties.
Xiao-Yu Liu   +4 more
doaj   +1 more source

A binuclear CuII/CaII thiocyanate complex with a Schiff base ligand derived from o-vanillin and ammonia

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2020
The new heterometallic complex, aqua-1κO-bis(μ2-2-iminomethyl-6-methoxyphenolato-1κ2O1,O6:2κ2O1,N)bis(thiocyanato-1κN)calcium(II)copper(II), [CaCu(C8H8NO2)2(NCS)2(H2O)], has been synthesized using a one-pot reaction of copper powder, calcium oxide, o ...
Nataliya Plyuta   +4 more
doaj   +1 more source

Development of Ferromagnetic Materials Containing Co2P, Fe2P Phases from Organometallic Dendrimers Precursors

open access: yesMolecules, 2021
The development of synthesis methods to access advanced materials, such as magnetic materials that combine multimetallic phosphide phases, remains a worthy research challenge. The most widely used strategies for the synthesis of magnetic transition metal
Alaa S. Abd-El-Aziz   +7 more
doaj   +1 more source

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