Results 31 to 40 of about 8,848 (177)

Luminescence Vapochromism of a Cu(I)/Na Phosphane Iodide Assembly Based on a Secondary‐Sphere Sodium Response

Angewandte Chemie, EarlyView.
The luminescence of a heterometallic d‐s {Cu2I2Na2} phosphane‐phosphinate aggregate is regulated by an interplay of Na+–π/I– contacts and reversible coordination of oxygen‐containing organic molecules to Na ions. Structural variations caused by the incoming guest lead to a wide and selective variation of the emission color and illustrate a new approach
Henna Korhonen, Dorota Głosz, Mariia Beliaeva, Andrey Belyaev, Constance Lecourt, Adrien Schlachter, Karine Costuas, Guillaume Calvez, Robert Podgajny, Christophe Lescop, Igor O. Koshevoy   +10 more
wiley   +2 more sources

SYNTHESIS AND PHYSICO-CHEMICAL STUDIES OF HETEROMETALLIC NITRILOTRIACETATES OF CHROMIUM(III) WITH SOME 3d METALS [PDF]

Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, 2006
Heterometallic complexes of chromium (III) with some 3d metals have been synthesized based on nitrilotriacetic acid (H3nta), like M(bpy)2Cr2(OH)2(nta)2·nH2O, where M = Mn2+, Co2+, Ni2+ and Zn2+; bpy = α,α′- bipyridine; n = 8 or 9.
Victor Ciorne, Aurelian Gulea
doaj  

Orthogonal luminescence lifetime encoding by intermetallic energy transfer in heterometallic rare-earth MOFs

Nature Communications, 2023
Lifetime-encoded materials are attractive as optical markers. Here, the authors report a design strategy for true orthogonality in encoding based on heterometallic rare-earth MOFs with independently variable lifetime and composition.
Jacob I. Deneff, Lauren E. S. Rohwer, Kimberly S. Butler, Bryan Kaehr, Dayton J. Vogel, Ting S. Luk, Raphael A. Reyes, Alvaro A. Cruz-Cabrera, James E. Martin, Dorina F. Sava Gallis   +9 more
doaj   +1 more source

Dual d–p hybridization in Ternary PtGaGe Enables Concurrent Activity and Stability Enhancement for Alkaline Oxygen Reduction

Angewandte Chemie, EarlyView.
A unique dual d–p orbital hybridization strategy was established in a ternary PtGaGe alloy catalyst to overcome the longstanding activity–stability trade‐off in oxygen reduction reaction (ORR). Synergistic hybridization between Ga/Ge p orbitals and Pt d orbitals modulates the Pt electronic structure, optimizes oxygen intermediates adsorption, and ...
Qian Zhang, Jinting Wu, Yong‐Chao Zhang, Lijun Tang, Xingchun Shi, Jian Gao, Tiansheng Mu, Xiaoli Zhang, Xiao‐Dong Zhu   +8 more
wiley   +2 more sources

Controlled heterometallic composition in linear trinuclear [LnCeLn] lanthanide molecular assemblies [PDF]

, 2019
The combination of two different β-diketone ligands facilitates the size-controlled assembly of pure heterometallic [LnLn′Ln] linear compounds thanks to two different coordination sites present in the molecular scaffold.
Aromí, Guillem, Roubeau, Olivier, Verónica Velasco, Mike Schütze, Velasco, Verónica, Luis Vitalla, Fernando, Barrios, Leoní A., Leoní A. Barrios, David Aguilà, Aromí Bedmar, Guillem, Barrios, Leoní A, Aguilà Avilés, David, Teati, Simon J., Schütze, Mike, Barrios Moreno, Leoní Alejandra, Simon J. Teat, Schetze, Mike, Olivier Roubeau, Aguilà, David, Guillem Aromí, Velasco Amigó, Verónica, Teat, Simon J., Luis, Fernando, Teat, Simon J, Fernando Luis   +24 more
core   +1 more source

Pyrazine-bridged polymetallic copper–iridium clusters

Acta Crystallographica Section E: Crystallographic Communications
Single crystals of the molecular compound, {Cu20Ir6Cl8(C21H24N2)6(C4H4N2)3]·3.18CH3OH or [({Cu10Ir3}Cl4(IMes)3(pyrazine))2(pyrazine)]·3.18CH3OH [where IMes is 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene], with a unique heterometallic cluster have ...
Ben. J. Tickner, Richard Gammons, Adrian C. Whitwood, Simon B. Duckett   +3 more
doaj   +1 more source

Competing excitation paths in luminescent heterobimetallic Ln-Al complexes: Unraveling interactions via experimental and theoretical investigations

iScience, 2023
Summary: The interest for heterometallic lanthanide-d or-p metal (Ln-M) complexes is growing because of a potential cooperative or synergistic effect related to the proximity of two different metals in the same molecular architecture affording special ...
Luca Bellucci, Silvia Carlotto, Gregorio Bottaro, Luca Babetto, Luca Labella, Elisa Gallo, Fabio Marchetti, Simona Samaritani, Lidia Armelao   +8 more
doaj   +1 more source

Heterometallic Multinuclear Nodes Directing MOF Electronic Behavior [PDF]

, 2020
Metal node engineering in combination with modularity, topological diversity, and porosity of metal–organic frameworks (MOFs) could advance energy and optoelectronic sectors.
Shustova, Natalia B., Prof. Dr., Pandey, Shubham, Berseneva, Anna A., Klepov, Vladislav V., Mathur, Abhijai, Smith, Mark D., Phillpot, Simon R., Leith, Gabrielle A., Park, Kyoung Chul, Ejegbavwo, Otega A., Karakalos, Stavros G., Chandrashekhar, Mvs, Garashchuk, Sophya, Brandt, Amy J., Heiser, Brittany J., Martin, Corey R., Farzandh, Sharfa, Chen, Donna A.   +17 more
core   +1 more source

On-surface preparation of coordinated lanthanide-transition-metal clusters

Nature Communications, 2021
The preparation of lanthanide-transition metal clusters containing multiple lanthanide atoms remains challenging. Here, the authors present the controlled on-surface formation of ligand-stabilized heterometallic Ce/Au clusters containing two, three and ...
Jing Liu, Jie Li, Zhen Xu, Xiong Zhou, Qiang Xue, Tianhao Wu, Mingjun Zhong, Ruoning Li, Rong Sun, Ziyong Shen, Hao Tang, Song Gao, Bingwu Wang, Shimin Hou, Yongfeng Wang   +14 more
doaj   +1 more source

Novel Heterometallic Lanthanide Silsesquioxane

, 2016
Novel Heterometallic Lanthanide ...
Alexander Steiner (2234449), Judith Annand (2978898), Helen C. Aspinall (2145016)   +2 more
core   +1 more source