[CrIII8NiII6]n+ Heterometallic Coordination Cubes [PDF]
, 2021 Three new heterometallic [CrIII8NiII6] coordination cubes of formulae [CrIII8NiII6L24(H2O)12](NO3)12 (1), [CrIII8NiII6L24(MeCN)7(H2O)5](ClO4)12 (2) and [CrIII8NiII6L24Cl12] (3) (where HL = 1-(4-pyridyl)butane-1,3-dione), were synthesised using the ...
Helen, O\u27Connor +11 more
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Heterometallic Titanium–Organic Frameworks by Metal-Induced Dynamic Topological Transformations [PDF]
, 2020 Reticular chemistry has boosted the design of thousands of metal and covalent organic frameworks for unlimited chemical compositions, structures, and sizable porosities.
Marı́a de la Mata (2627263) +21 more
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Injectable and photocurable macromonomers synthesized using a heterometallic magnesium-titanium metal-organic catalyst for elastomeric polymer networks [PDF]
, 2023 Injectable and in situ photocurable biomaterials are receiving a lot of attention due to their ease of application via syringe or dedicated applicator and ability to be used in laparoscopic and robotic minimally invasive procedures.
Gokhan, Demirci +5 more
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Photochemical H2 Activation by an Zn–Fe Heterometallic: A Mechanistic Investigation [PDF]
, 2023 Addition of H2 to a Zn–Fe heterometallic complex was observed to occur under photochemical conditions (390 or 428 nm LED) and leads to the formation of the corresponding metal dihydride.
Mark, Crimmin, Marina, Perez-Jimenez
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Homo- and Heterometallic planes, chains and cubanes. [PDF]
, 2013 Journal article (post-print)The synthesis, structural and magnetic characterisation of a family of homo- and heterometallic complexes constructed with the Schiff base ligands 2-iminomethyl-6-methoxy-phenol (L1H) and 2-imino-6-methoxy-phenol (L2H), are ...
Jones, Leigh F., Meally, Sean T.
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Kinetic Versus Thermodynamic Metalation Enables Synthesis of Isostructural Homo- and Heterometallic Trinuclear Clusters [PDF]
, 2020 Temperature-dependent metalation of the new hexadentate ligand (tris(5-(pyridin-2-yl)-1H-pyrrol-2-yl)methane; H3TPM) enables the selective synthesis of both mononuclear (i.e. Na(THF)4[Fe(TPM)], kinetic product) and trinuclear (i.e.
Siyoung, Sung +8 more
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Heterodimers of heterometallic rings [PDF]
, 2016 Nine new complexes are reported involving linked heterometallic rings; one ring is designed as a ligand for the second, and the compounds produced can be regarded as molecular prototypes for implementing quantum gates featuring two subtly different ...
Mcinnes, Eric +18 more
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Heterobimetallic Janus Catalysts for the One-Pot Synthesis of Polar-Apolar Block Copolymers. [PDF]
Angew Chem Int Ed EnglHeterobimetallic Janus catalysts act as bifunctional initiators, combining two distinct polymerisation mechanisms in one pot to deliver well‐defined apolar‐polar block copolymers. Combining Earth abundant Ti and Al catalysts for respective α‐olefin and lactone polymerisation, the orthogonal activity is enabled by unprecedented initiation from a Ti ...
Chambenahalli R, Nichol GS, Garden JA.
europepmc +3 more sources
Inorganics, 2021 The synthesis of new porous materials with desired properties is a challenging task. It becomes especially difficult if you need to combine several metals in one framework to obtain a heterometallic node. The use of presynthesized complexes for obtaining
Marina Barsukova +6 more
doaj +1 more source
Hidden Heterometallic Interaction Emerges from Resonant Inelastic X-ray Scattering in Luminescent Tb–Pt Molecules [PDF]
, 2022 Theoretical calculations are typically utilized for examining intermetallic interactions. However, to validate theory, experimental confirmation of the existence of these interactions is necessary. We synthesized new heterometallic Ln–Pt complexes, NEt4{[
Miki , Hasegawa +15 more
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